Online citations, reference lists, and bibliographies.
← Back to Search

Concerning CH/sub 2/=C/sup -/ And Its Reaction With /sup 14/N/sup 15/NO

J. H. Dawson, N. Nibbering
Published 1978 · Chemistry

Save to my Library
Download PDF
Analyze on Scholarcy
Share
Evidence is presented that stable C/sub 2/H/sub 2/./sup -/ (m/e 26) has the structure CH/sub 2/ = C./sup -/ . In the reaction of CH/sub 2/ = C./sup -/ with /sup 14/N /sup 15/NO, there is no incorporation of the /sup 15/N label into the CH/sub 2/CN/sup -/ product ions, and thus the reaction takes place at the terminal nitrogen. (DLC)



This paper is referenced by
10.1016/B978-0-12-174402-1.50011-1
Electron affinities of atoms, molecules and radicals
A. A. Christodoulides (1982)
10.1016/S0040-4020(01)91411-5
Carbon-carbon bond formation employing organoiron reagents : Syntheses of lavandulol and red scale pheromone
J. Celebuski (1985)
10.1016/S0040-4020(01)81303-X
Generation, thermochemistry, and chemistry of carbene anion radicals and related species
R. Mcdonald (1989)
10.1021/BI00531A012
Folate pentaglutamate and folate hexaglutamate mediated one-carbon metabolism.
T. Brody (1982)
10.1016/0020-7381(80)80030-1
The gas-phase anionic chemistry of saturated and unsaturated aliphatic nitriles
J. Dawson (1980)
10.1016/0040-4039(93)89003-9
Diastereoselective [2,3] Wittig rearrangement of carbohydrate-derived tertiary allylic ethers. 2. Synthesis of an advanced rapamycin intermediate from D-glucose.
Ny Sin (1993)
10.1016/0168-1176(84)85094-6
Low energy electron impact on benzene and the fluorobenzenes. Formation and dissociation of negative ions
Heinz-Peter Fenzlaff (1984)
10.1002/9780470682531.PAT0533
Energetics of Organomanganese Compounds
J. F. Liebman (2011)
10.1016/0009-2614(89)87115-5
The generation and identification of triplet vinylidene, [H2CC]:, by neutralization-reionization mass spectrometry
D. Sülzle (1989)
10.1016/S0040-4020(99)00386-5
THE CHEMISTRY OF THIOCYANIC ESTERS
A. W. Erian (1999)
10.1002/QUA.20382
Theoretical study of unimolecular rearrangements of vinylidenes to acetylenes
R. Kakkar (2005)
10.1039/A905870B
Synthesis, properties and reactivity of the phenylcarbene anion in the gas phase†
R. Seburg (1999)
10.1002/ANIE.197905633
Stereochemistry of [2,3]Sigmatropic Rearrangements
R. Hoffmann (1979)
10.1016/0168-1176(87)80010-1
Formation of carbene radical anions: gas-phase reaction of the atomic oxygen anion with organic neutrals
J. Grabowski (1987)
10.1007/978-1-4613-2931-2_10
Mechanistic Aspects of Ion-Molecule Reactions
N. Nibbering (1979)
10.1063/1.457415
A study of the singlet and triplet states of vinylidene by photoelectron spectroscopy of H2C=C−, D2C=C−, and HDC=C−. Vinylidene–acetylene isomerization
K. M. Ervin (1989)
10.1002/(SICI)1098-2787(1997)16:4<181::AID-MAS2>3.0.CO;2-D
Formation and chemistry of radical anions in the gas phase
Monique Born (1997)
10.1002/RCM.1290081108
Gas-phase reactions of transition metal carbonyl anions and atomic metal anions with nitrous oxide and dioxygen: oxygen atom transfer and ligand exchange in reactions with nitrous oxide
J. BergvandenK. (1994)
10.1016/0009-2614(83)87413-2
The neutral and ionic vinylidene—acetylene rearrangement
G. Frenking (1983)
10.1063/1.472491
Is acetylene radical anion with a trans–bent form observed in matrix experiment? An ab initio study
T. Ha (1996)
10.1016/0009-2614(82)80343-6
The preferred structure of C2H−2
J. Chandrasekhar (1982)
10.1016/0168-1176(92)80105-A
Chemistry of C−2 and HC−2 with nitrogen, oxygen and nitrogen oxides
J. V. Doren (1992)
10.1002/mrc.2230
119Sn NMR chemical shift tensors in anhydrous and hydrated Si8O20(SnMe3)8 crystals
J. Jiao (2008)
10.1002/ANGE.19790910806
Stereochemie [2, 3]sigmatroper Umlagerungen
R. Hoffmann (1979)
10.1016/0168-1176(89)83049-6
Theory and experiment in accord: the vinylidene radical cation
G. Frenking (1989)
10.1002/CHIN.197827049
CONCERNING CH2‐C‐.CNTDOT.AND ITS REACTION WITH 14N15NO
J. H. Dawson (2002)
10.1016/0020-7381(79)80034-0
The gas phase allyl anion
J. Dawson (1979)
10.1016/S0065-3160(08)60157-4
Gas-phase Reactions of Organic Anions
N. Nibbering (1988)
10.1007/978-94-009-7248-3_13
Determinations of Gas-Phase Organic Ion Structures
G. Groenewold (1984)
10.1016/1044-0305(93)85045-Y
Gas-phase reactions between O−. and C6H5F: On the acidity of fluorobenzene and 1,4-difluorobenzene
H. E. Matimba (1993)
10.1063/1.457855
Reactions of O−+ N2O at 300 K: The totally labeled experiments
S. E. Barlow (1990)
10.1016/J.IJMS.2008.07.007
Gas-phase reactions of halogenated radical carbene anions with sulfur and oxygen containing species
Stephanie M. Villano (2009)
See more
Semantic Scholar Logo Some data provided by SemanticScholar