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One-carbon Homologation Of Carboxylic Acids Via BtCH(2)TMS: A Safe Alternative To The Arndt--Eistert Reaction.

A. Katritzky, S. Zhang, A. Hussein, Y. Fang, P. Steel
Published 2001 · Medicine, Chemistry

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Carboxylic acids are converted into the corresponding homologated acids or esters, using easily available 1-(trimethylsilylmethyl)benzotriazole (1) as a one-carbon synthon. The effectiveness of the reaction has been investigated on six aryl and seven alkyl carboxylic acids.
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