Online citations, reference lists, and bibliographies.
← Back to Search

Molecular Adsorption And Resonance Coupling At The Colloidal Gold Nanoparticle Interface

Tony E Karam, L. H. Haber
Published 2014 · Chemistry

Cite This
Download PDF
Analyze on Scholarcy
Share
Second harmonic generation is used to investigate the adsorption properties of malachite green, brilliant green, and methyl green to the surface of 80 nm colloidal gold nanoparticles capped with mercaptosuccinic acid in water. The experimental results are fit using the modified Langmuir model to obtain the free energies of adsorption and the adsorbate site densities for each cationic triphenylmethane molecular dye. Malachite green is observed to bind more strongly than brilliant green or methyl green to the nanoparticle surface but has a lower adsorbate site density, indicating differences in image-charge effects, adsorbate–adsorbate repulsions, and adsorption tilt angles. Complementary measurements from extinction spectroscopy show plasmonic and molecular resonance coupling leading to the formation of new polaritonic states and Fano-type resonances with corresponding plasmon and molecular spectral depletions as the adsorbate concentration is increased. The changes in the resonance coupling spectra are co...
This paper references
10.1021/nn900012r
Tunability of subradiant dipolar and fano-type plasmon resonances in metallic ring/disk cavities: implications for nanoscale optical sensing.
F. Hao (2009)
10.1146/annurev.anchem.1.031207.112814
Surface-enhanced Raman spectroscopy.
P. L. Stiles (2008)
10.1080/01442350050034180
Shape and size dependence of radiative, non-radiative and photothermal properties of gold nanocrystals
S. Link (2000)
10.1021/CR030698+
Gold nanoparticles: assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology.
M. Daniel (2004)
10.1103/PHYSREVLETT.105.077401
Interference between selected dipoles and octupoles in the optical second-harmonic generation from spherical gold nanoparticles.
J. Butet (2010)
10.1016/J.AB.2004.11.026
Radiative decay engineering 5: metal-enhanced fluorescence and plasmon emission.
J. Lakowicz (2005)
10.1126/SCIENCE.2321027
Two-photon laser scanning fluorescence microscopy.
W. Denk (1990)
10.1103/PhysRevB.79.241404
Strong coupling of localized plasmons and molecular excitons in nanostructured silver films
N. I. Cade (2009)
10.1021/JA0537169
Correlating second harmonic optical responses of single Ag nanoparticles with morphology.
R. Jin (2005)
10.1021/JP051066P
Catalysis with transition metal nanoparticles in colloidal solution: nanoparticle shape dependence and stability.
R. Narayanan (2005)
10.1103/PHYSREVB.84.121402
Determination of adsorption geometry on spherical particles from nonlinear Mie theory analysis of surface second harmonic generation
G. Gonella (2011)
10.1021/CM980065P
Seeding of Colloidal Au Nanoparticle Solutions. 2. Improved Control of Particle Size and Shape
K. Brown (2000)
10.1021/JP8095264
Excited-State Lifetime Assay for Protein Detection on Gold Colloids-Fluorophore Complexes
S. Freddi (2009)
10.1021/jp806690z
Second harmonic studies of ions crossing liposome membranes in real time.
J. Liu (2008)
10.1002/adma.201203682
Tuning the work-function via strong coupling.
James A. Hutchison (2013)
10.1021/ja104859j
Tailoring DNA structure to increase target hybridization kinetics on surfaces.
Andrew E. Prigodich (2010)
10.1021/JP8047168
Protonation at the Aqueous Interface of Polymer Nanoparticles with Second Harmonic Generation
M. Subir (2008)
10.1021/JP066952U
Meeting the Clean Energy Demand: Nanostructure Architectures for Solar Energy Conversion
P. Kamat (2007)
10.1103/PHYSREVB.75.245438
ANYL 279-Vibrational sum frequency generation scattering from the interface of an isotropic particle: Geometrical and chiral effects
D. Beer (2007)
10.1063/1.2796162
Curve crossing and negative refraction in simulations of near-field coupled metallic nanoparticle arrays.
K. Lopata (2007)
10.1039/b712170a
Biological applications of gold nanoparticles.
Ralph A. Sperling (2008)
10.1103/PHYSREVLETT.83.4045
Second-Harmonic Rayleigh Scattering from a Sphere of Centrosymmetric Material
J. Dadap (1999)
10.1021/ja910239b
Effects of dyes, gold nanocrystals, pH, and metal ions on plasmonic and molecular resonance coupling.
W. Ni (2010)
10.1063/1.1641517
The electric double layer at a metal electrode in pure water
P. Brüesch (2004)
10.1021/NL062901X
Plasmonic enhancement of molecular fluorescence.
F. Tam (2007)
10.1039/c2cp43271d
Nanoparticle surface electromagnetic fields studied by single-particle nonlinear optical spectroscopy.
M. Chandra (2013)
10.1021/JP034486S
Ultrafast Relaxation Dynamics from the S2 State of Malachite Green Studied with Femtosecond Upconversion Spectroscopy
A. C. Bhasikuttan (2003)
10.1063/1.2790436
Molecular nanopolaritonics: cross manipulation of near-field plasmons and molecules. I. Theory and application to junction control.
D. Neuhauser (2007)
10.1063/1.1290024
Surface enhanced sum frequency generation of carbon monoxide adsorbed on platinum nanoparticle arrays
S. Baldelli (2000)
10.1021/NL050074E
Surface plasmon resonance scattering and absorption of anti-EGFR antibody conjugated gold nanoparticles in cancer diagnostics: applications in oral cancer.
I. El-Sayed (2005)
10.1021/ar800121r
Noble metal nanocrystals: plasmon electron transfer photochemistry and single-molecule Raman spectroscopy.
L. Brus (2008)
10.1021/CM000662N
Evidence for Seed-Mediated Nucleation in the Chemical Reduction of Gold Salts to Gold Nanoparticles
N. R. Jana (2001)
10.1021/JP0209289
Photophysical, photochemical and photocatalytic aspects of metal nanoparticles
P. Kamat (2002)
10.1021/JP984044U
Enormous Hyper-Rayleigh Scattering from Nanocrystalline Gold Particle Suspensions
Fredrick W. Vance (1998)
10.1038/nmat2810
The Fano resonance in plasmonic nanostructures and metamaterials.
B. Luk'yanchuk (2010)
10.1021/JP066873I
Adsorption at a Carbon Black Microparticle Surface in Aqueous Colloids Probed by Optical Second-Harmonic Generation †
H. Wang (2007)
10.1023/B:JOFL.0000031824.48401.5c
Advances in Surface-Enhanced Fluorescence
J. Lakowicz (2004)
10.1021/ja106910x
Controlled plasmon resonance properties of hollow gold nanosphere aggregates.
M. Chandra (2010)
10.1021/JP981335U
New Method for Determination of Surface Potential of Microscopic Particles by Second Harmonic Generation
Elsa C. Y. Yan (1998)
10.1016/J.CPLETT.2011.03.042
Probing the colloidal gold nanoparticle/aqueous interface with second harmonic generation
L. H. Haber (2011)
10.1021/jp304242c
Molecular excited-state relaxation dynamics at the colloidal microparticle interface monitored with pump-probe second harmonic generation.
L. H. Haber (2013)
10.1021/ar900233v
The spectral signatures of Frenkel polarons in H- and J-aggregates.
F. Spano (2010)
10.1103/PHYSREV.124.1866
Effects of Configuration Interaction on Intensities and Phase Shifts
U. Fano (1961)
10.1021/CR0403685
Second harmonic spectroscopy of aqueous nano- and microparticle interfaces.
K. Eisenthal (2006)
10.1063/1.1510439
Hyper-Rayleigh scattering from silver nanoparticles
E. Hao (2002)
10.1021/nn2050533
Plasmonic systems unveiled by Fano resonances.
Y. Francescato (2012)
10.1016/J.CANLET.2005.07.035
Selective laser photo-thermal therapy of epithelial carcinoma using anti-EGFR antibody conjugated gold nanoparticles.
I. El-Sayed (2006)
10.1021/ja907069u
Synthesis and surface modification of highly monodispersed, spherical gold nanoparticles of 50-200 nm.
Steven D. Perrault (2009)
10.1063/1.3082245
Multiscale Maxwell-Schrodinger modeling: A split field finite-difference time-domain approach to molecular nanopolaritonics.
K. Lopata (2009)
10.1103/PHYSREVLETT.97.266808
Strong coupling between localized plasmons and organic excitons in metal nanovoids.
Y. Sugawara (2006)
10.1021/JP069062N
Vibrational sum frequency generation spectroscopy of dodecanethiol on metal nanoparticles
A. Bordenyuk (2007)
10.1021/JP0675025
Multipolar Contributions of the Second Harmonic Generation from Silver and Gold Nanoparticles
I. Russier-Antoine (2007)
10.1021/JP980491Y
Energetics and Population of Molecules at Microscopic Liquid and Solid Surfaces
H. Wang (1998)
10.1021/JP984288E
STUDY OF INTERFACIAL CHARGE-TRANSFER COMPLEX ON TIO2 PARTICLES IN AQUEOUS SUSPENSION BY SECOND-HARMONIC GENERATION
Y. Liu (1999)
10.1021/JP9026139
Single Metallic Nanoparticle Sensitivity with Hyper Rayleigh Scattering
Julien Duboisset (2009)



This paper is referenced by
10.1021/ACS.JPCC.7B05058
Impacts of Salt, Buffer, and Lipid Nature on Molecular Adsorption and Transport in Liposomes As Observed by Second Harmonic Generation
Raju R. Kumal (2017)
Ultrafast and Nonlinear Spectroscopy of Nanomaterials
R. A. Khoury (2018)
10.1021/ACS.JPCC.7B03272
Absolute Molecular Orientation of Isopropanol at Ceria (100) Surfaces: Insight into Catalytic Selectivity from the Interfacial Structure
Benjamin Doughty (2017)
Coupled Plasmon/Molecule Dynamics Near Core-Shell Nanoparticles: Synthesis, Ultrafast Characterization, and Quantum/Classical Modeling
Holden T Smith (2017)
Ultrafast and Nonlinear Spectroscopy of Colloidal Nanomaterials
Tony E Karam (2016)
10.1021/JP510042C
Restriction of Molecular Rotation and Intramolecular Charge Distribution in the Photoexcited State of Coumarin Dyes on Gold Nanoparticle Surface
J. Dana (2015)
10.1063/1.5127941
Monitoring the growth dynamics of colloidal gold-silver core-shell nanoparticles using in situ second harmonic generation and extinction spectroscopy.
J. C. Ranasinghe (2019)
10.1021/acs.langmuir.6b01643
Adsorption, Ordering, and Local Environments of Surfactant-Encapsulated Polyoxometalate Ions Probed at the Air-Water Interface.
Benjamin Doughty (2016)
10.1021/ACS.LANGMUIR.6B02538
Plasmon-Enhanced Photocleaving Dynamics in Colloidal MicroRNA-Functionalized Silver Nanoparticles Monitored with Second Harmonic Generation.
Raju R. Kumal (2016)
10.1146/annurev-anchem-071015-041453
Applications of Surface Second Harmonic Generation in Biological Sensing.
Renee J Tran (2017)
10.1039/c9cp04939h
Surface curvature-dependent adsorption and aggregation of fluorescein isothiocyanate on gold nanoparticles.
Shan Xue (2019)
10.1021/ACS.JPCC.7B03440
Capturing Plasmon–Molecule Dynamics in Dye Monolayers on Metal Nanoparticles Using Classical Electrodynamics with Quantum Embedding
H. Smith (2017)
10.1021/ACSMACROLETT.6B00915
Unraveling the Molecular Weight Dependence of Interfacial Interactions in Poly(2-vinylpyridine)/Silica Nanocomposites
D. Voylov (2017)
10.1364/OPTICA.1.000388
Condition for perfect antireflection by optical resonance at material interface
K. Wang (2014)
10.1016/J.DYEPIG.2017.02.004
Gold nanoparticles modified by new conjugated S=C=N terminal and its biological imaging application
Anran Wang (2017)
10.1021/ACS.JPCC.6B01786
On Electronic and Charge Interference in Second Harmonic Generation Responses from Gold Metal Nanoparticles at Supported Lipid Bilayers
Julianne M. Troiano (2016)
Nanoparticle-Based Drug-Delivery Systems Studied by Second Harmonic Generation
Raju R. Kumal (2017)
10.1021/ACS.JPCC.5B00568
Determination of the Surface Charge Density of Colloidal Gold Nanoparticles Using Second Harmonic Generation
Raju R. Kumal (2015)
10.1063/1.4994712
Ultrafast and nonlinear spectroscopy of brilliant green-based nanoGUMBOS with enhanced near-infrared emission.
Tony E Karam (2017)
10.1021/acs.analchem.5b04109
Fluorescence, Phosphorescence, and Chemiluminescence.
N. Siraj (2016)
10.1021/ACS.JPCC.5B05110
Enhanced Photothermal Effects and Excited-State Dynamics of Plasmonic Size-Controlled Gold–Silver–Gold Core–Shell–Shell Nanoparticles
Tony E Karam (2015)
10.1021/acs.langmuir.5b02199
Monitoring the Photocleaving Dynamics of Colloidal MicroRNA-Functionalized Gold Nanoparticles Using Second Harmonic Generation.
Raju R. Kumal (2015)
10.1016/J.NANTOD.2015.02.007
Strategies for enhancing the sensitivity of plasmonic nanosensors
L. Guo (2015)
10.1002/slct.202001751
An Insight of Molecular Twisting of Coumarin Dyes
Tushar Debnath (2020)
10.1063/1.4944385
Excited-state dynamics of size-dependent colloidal TiO2-Au nanocomposites.
Tony E Karam (2016)
10.1021/ACS.JPCC.8B07176
Monitoring the Seed-Mediated Growth of Gold Nanoparticles Using in Situ Second Harmonic Generation and Extinction Spectroscopy
R. Khoury (2018)
10.1021/JP510357P
Probing Interfacial Electronic States in CdSe Quantum Dots Using Second Harmonic Generation Spectroscopy
Benjamin Doughty (2015)
10.1016/J.POLYMER.2017.09.003
Preparation and Characterization of polypropylene/noble metal nanocomposites based on reactor granule technology
Airong Qiagedeer (2016)
10.1016/J.MOLLIQ.2016.03.025
Analyzing the stability of second harmonic intensity provides a sensitive probe of the aggregating of conjugated molecules at the interface
Yuanyuan Niu (2016)
Semantic Scholar Logo Some data provided by SemanticScholar