Online citations, reference lists, and bibliographies.
← Back to Search

Synthesis And Ring-Opening Metathesis Polymerization Of Norbornene-Terminated Syndiotactic Polypropylene

Amelia Anderson-wile, G. Coates, F. Auriemma, C. Rosa, A. Silvestre
Published 2012 · Chemistry

Cite This
Download PDF
Analyze on Scholarcy
Share
Using nonliving bis(phenoxyimine)titanium catalysts activated by methylaluminoxane (MAO) in the presence of propylene, allyl-terminated syndiotactic polypropylene macromonomers with varying tacticity ([rrrr] = 0.80 and 0.94) and molecular weight (Mn = 3600 and 5600 g/mol) were produced. The end-functionalized polymers were converted to hydroxyl- and subsequently norbornene-terminated macromonomers. Two series of syndiotactic polypropylene comb-polymers were synthesized through metathesis polymerization of the norbornene-functionalized polypropylene. The molecular weight (Mn = 46 000–172 000 g/mol) and polydispersity (Mw/Mn = 1.21–1.89) of the comb polymers was determined by gel permeation chromatography (GPC). Using differential scanning calorimetry (DSC), melting temperature (Tm) and crystallization temperature (Tc) were determined and both were observed to decrease with increasing conversion to poly(macromonomer). To the best of our knowledge, this is the first synthesis of comb-polymers from end-functi...
This paper references
10.1016/J.PROGPOLYMSCI.2008.05.003
Olefin polymer technologies—History and recent progress at The Dow Chemical Company
P. S. Chum (2008)
10.1002/MARC.1987.030080607
Synthesis and characterization of living copolymer of ethylene and propene
Y. Doi (1987)
10.1021/JA0122593
Mechanism of propylene insertion using bis(phenoxyimine)-based titanium catalysts: an unusual secondary insertion of propylene in a group IV catalyst system.
P. Hustad (2002)
10.1021/MA0117559
Well-Defined, Model Long Chain Branched Polyethylene. 2. Melt Rheological Behavior
D. J. Lohse (2002)
10.1002/ANIE.199511431
Stereospecific Olefin Polymerization with Chiral Metallocene Catalysts
H. Brintzinger (1995)
10.1021/OL006059S
Stereoselectivity of macrocyclic ring-closing olefin metathesis
Lee (2000)
10.1021/MA00073A028
Crystal structure of syndiotactic polypropylene
C. Rosa (1993)
10.1134/S002315840602011X
Polypropylene-block-poly(methyl methacrylate) and-block-poly(N-isopropylacrylamide) block copolymers prepared by controlled radical polymerization with polypropylene macroinitiator
Hideyuki Kaneko (2006)
10.1080/00222349108219480
Physical properties of syndiotactic polypropylene
S. Haftka (1991)
10.1002/MARC.1984.030051206
Reaction of carbon monoxide with living polypropylene prepared with a vanadium-based catalyst
Y. Doi (1984)
10.6028/JRES.066A.003
Melting process and the equilibrium melting temperature of polychlorotrifluoroethylene
J. Hoffman (1962)
10.1021/JA047236D
Gel permeation chromatography as a combinatorial screening method: identification of highly active heteroligated phenoxyimine polymerization catalysts.
A. F. Mason (2004)
10.1002/POLA.22837
End group transformations of RAFT-generated polymers with bismaleimides: Functional telechelics and modular block copolymers
M. Li (2008)
10.1021/MA010878Q
Synthesis of end-functionalized poly(norbornene)s via ring-opening metathesis polymerization
C. Bielawski (2001)
10.1016/0032-3861(94)90978-4
Crystallization, melting and morphology of syndiotactic polypropylene fractions: 1. Thermodynamic properties, overall crystallization and melting☆
Jonahira Rodriguez-Arnold (1994)
10.1021/OM049296Y
Living propene polymerization with bis(phenoxyimine) group 4 metal catalysts: New strategies and old concepts
G. Talarico (2004)
10.1021/ja109191z
Dynamic cylindrical assembly of triblock copolymers by a hierarchical process of covalent and supramolecular interactions.
Z. Li (2011)
10.1021/MA049647K
Synthesis of ultralarge molecular weight bottlebrush polymers using Grubbs' catalysts
S. Jha (2004)
10.1016/J.PROGPOLYMSCI.2006.11.001
Living alkene polymerization : New methods for the precision synthesis of polyolefins
Gregory J. Domski (2007)
10.1016/J.PROGPOLYMSCI.2008.01.003
The architectures and surface behavior of highly branched molecules
S. Peleshanko (2008)
10.1021/MA902464A
Ambient Temperature Synthesis of a Versatile Macromolecular Building Block: Cyclopentadienyl-Capped Polymers
A. J. Inglis (2010)
10.1007/3-540-15786-7_10
Synthesis of “living” polyolefins with soluble Ziegler-Natta catalysts and application to block copolymerization
Y. Doi (1986)
10.1021/MA1021506
Drug-loaded, bivalent-bottle-brush polymers by graft-through ROMP.
J. A. Johnson (2010)
10.1002/CHEM.200304661
Unprecedented living olefin polymerization derived from an attractive interaction between a ligand and a growing polymer chain.
M. Mitani (2003)
10.1016/S0079-6700(97)00049-X
Polymeric design by macromonomer technique
K. Ito (1998)
10.1021/JA073690G
Arm-first method as a simple and general method for synthesis of miktoarm star copolymers.
Haifeng Gao (2007)
10.1007/3-540-68310-0_3
Poly(macromonomers): Homo- and Copolymerization
K. Ito (1999)
10.1021/cr100294r
FI catalysts for olefin polymerization--a comprehensive treatment.
H. Makio (2011)
10.1021/MA00087A038
Synthesis of Isotactic Polypropylene Functionalized with a Primary Amino Group at the Initiation Chain End
T. Shiono (1994)
10.1021/cr900138t
Applications of orthogonal "click" chemistries in the synthesis of functional soft materials.
Rhiannon K. Iha (2009)
10.1021/MA0010635
Chain end isomerization as a side reaction in metallocene-catalyzed ethylene and propylene polymerizations
P. Lehmus (2000)
10.1021/MA902176J
Synthesis of Novel Rod-Coil Brush Polymers with Conjugated Backbones through Bergman Cyclization
X. Cheng (2010)
10.1021/MA702190C
Poly(ethylene-co-propylene macromonomer)s: Synthesis and Evidence for Starlike Conformations in Dilute Solution
Jeffrey M Rose (2008)
10.1002/1521-3935(200207)203:10/11<1564::AID-MACP1564>3.0.CO;2-V
A possible unified mechanism of Like and Unlike chain-end stereocontrol for primary propene-coordinated polymerizations
G. Milano (2002)
10.1039/b708843b
High-performance olefin polymerization catalysts discovered on the basis of a new catalyst design concept.
Tomoaki Matsugi (2008)
10.1021/JA0117581
Living polymerization of ethylene catalyzed by titanium complexes having fluorine-containing phenoxy-imine chelate ligands.
M. Mitani (2002)
10.1002/TCR.20010
FI catalysts: new olefin polymerization catalysts for the creation of value-added polymers.
M. Mitani (2004)
10.1016/J.PROGPOLYMSCI.2004.12.002
Precise syntheses of chain-multi-functionalized polymers, star-branched polymers, star-linear block polymers, densely branched polymers, and dendritic branched polymers based on iterative approach using functionalized 1,1-diphenylethylene derivatives
A. Hirao (2005)
10.1002/POLA.20963
Syntheses of graft and star copolymers possessing polyolefin branches by using polyolefin macromonomer
Hideyuki Kaneko (2005)
10.1002/POLA.20900
Cylindrical polymer brushes
M. Zhang (2005)
10.1016/J.PROGPOLYMSCI.2007.01.004
Synthesis of well-defined polymer architectures by successive catalytic olefin polymerization and living/controlled polymerization reactions
Ricardo Godoy Lopez (2007)
10.1021/MA0494479
Morphology and Thermodynamic Behavior of Syndiotactic Polypropylene−Poly(ethylene-co-propylene) Block Polymers Prepared by Living Olefin Polymerization
J. Ruokolainen (2005)
10.1021/MA900280C
Efficient Synthesis of Narrowly Dispersed Brush Polymers via Living Ring-Opening Metathesis Polymerization of Macromonomers
Yan Xia (2009)
10.1002/APP.25745
Synthesis and characterization of hindered amine light stabilizers based on end functionalization of polypropylene
K. R. Reddy (2007)
10.1039/B912447K
Self-assembly of an ultra-high-molecular-weight comb block copolymer at the air–water interface
L. Zhao (2009)
10.1021/CR990129V
Visualization of macromolecules--a first step to manipulation and controlled response.
S. Sheiko (2001)
10.1002/POLA.22551
The comonomer inducing selective β‐methyl elimination chain transfer: A new approach for end‐functionalizations of syndiotactic polypropylene‐based copolymers
Wenfu Lin (2008)
10.1021/MA00186A013
Crystal structure and morphology of syndiotactic polypropylene single crystals
B. Lotz (1988)
10.1002/(SICI)1097-4628(20000103)75:1<44::AID-APP6>3.0.CO;2-1
Thermal properties and isothermal crystallization of syndiotactic polypropylenes: Differential scanning calorimetry and overall crystallization kinetics
P. Supaphol (2000)
10.1021/MA00066A006
Structure and defects in fully syndiotactic polypropylene
A. J. Lovinger (1993)
10.1002/POLA.23626
Facile syntheses of cylindrical molecular brushes by a sequential RAFT and ROMP "grafting-through" methodology.
Z. Li (2009)
10.1002/1097-4628(20010228)79:9<1603::AID-APP90>3.0.CO;2-Q
Unbiased evaluation of literature data on equilibrium melting temperature and enthalpy of fusion of perfectly syndiotactic polypropylene
P. Supaphol (2001)
10.1021/MA011389T
Syndiospecific Polymerization of Propene Promoted by Bis(salicylaldiminato)titanium Catalysts: Regiochemistry of Monomer Insertion and Polymerization Mechanism
M. Lamberti (2002)
10.1002/marc.200900146
Synthesis of comb tri- and tetrablock copolymers catalyzed by the grubbs first generation catalyst.
M. Runge (2009)
10.1002/POLA.23943
Synthesis of comb polymers via grafting‐onto macromolecules bearing pendant diene groups via the hetero‐Diels‐Alder‐RAFT click concept
A. Bousquet (2010)
10.1021/CM900032M
Template-Directed Synthesis of Hybrid Titania Nanowires within Core−Shell Bishydrophilic Cylindrical Polymer Brushes
J. Yuan (2009)
10.1021/MA051530O
Functionalization and applications of telechelic oligopropylenes : Preparation of α,ω-dihydroxy- and diaminooligopropylenes
T. Hagiwara (2005)
10.1002/1521-3927(20010901)22:13<1072::AID-MARC1072>3.0.CO;2-7
Microstructure of Highly Syndiotactic “Living” Poly(propylene)s Produced from a Titanium Complex with Chelating Fluorine-Containing Phenoxyimine Ligands (an FI Catalyst)
J. Saito (2001)
10.1021/cr900068q
Hyperbranched and highly branched polymer architectures--synthetic strategies and major characterization aspects.
B. Voit (2009)
10.1002/MARC.1983.030040805
Synthesis of a propylene-tetrahydrofuran block copolymer via “living” coordination polymerization
Y. Doi (1983)
10.1021/MA071121N
Reactive Alkyne and Azide Solid Supports To Increase Purity of Novel Polymeric Stars and Dendrimers via the “Click” Reaction
C. Urbani (2007)
10.1002/POLA.22516
Precise control of microstructure of functionalized polypropylene synthesized by the ansa-zirconocene/ MAO catalysts
H. Hagihara (2008)
10.1560/XKLD-HWTH-Q45E-1V9G
Syndiospecific living catalysts for propylene polymerization: Effect of fluorination on activity, stereoselectivity, and termination
A. F. Mason (2002)
10.1021/ja211676y
Cis-selective ring-opening metathesis polymerization with ruthenium catalysts.
B. K. Keitz (2012)
10.1002/MARC.200600853
Synthesis of Chain‐End Functionalized Polyolefins with a Bis(phenoxy imine) Titanium Catalyst
H. Makio (2007)
10.1021/MA100779Q
Synthesis of Well-Defined ω-Oxanorbornenyl Poly(ethylene oxide) Macromonomers via Click Chemistry and Their Ring-Opening Metathesis Polymerization
D. Le (2010)
10.1021/MA050735U
Synthesis of Allyl-Terminated Syndiotactic Polypropylene: Macromonomers for the Synthesis of Branched Polyolefins
Anna E. Cherian (2005)
10.1021/JA029560J
Syndiospecific living propylene polymerization catalyzed by titanium complexes having fluorine-containing phenoxy-imine chelate ligands.
M. Mitani (2003)
10.1021/JA072929Q
Synthesis of high molecular weight comb block copolymers and their assembly into ordered morphologies in the solid state.
M. Runge (2007)
10.1021/JA0157189
A new catalyst for highly syndiospecific living olefin polymerization: homopolymers and block copolymers from ethylene and propylene.
J. Tian (2001)
10.1021/MA980789M
On the Form II of Syndiotactic Polypropylene
C. Rosa (1998)
10.1002/MREN.200800038
On the Cascade Polymerization Process Consisting of Metallocene Polymerization and ATRP to Prepare i-PP-Based Polar Block Copolymers
Q. Yi (2009)
10.1016/J.POLYMER.2004.02.055
Study on chain end structures of polypropylenes prepared with different symmetrical metallocene catalysts
N. Kawahara (2004)
10.1016/J.EURPOLYMJ.2011.11.015
A novel strategy for the preparation of long chain branching polypropylene and the investigation on foamability and rheology
Shuzhao Li (2012)
10.1016/S0032-3861(01)00553-5
Peroxydicarbonate modification of polypropylene and extensional flow properties
R. Lagendijk (2001)
10.1002/POLA.23324
Three‐arm star ring opening metathesis polymers via alkyne‐azide click reaction
A. Dag (2009)
10.1021/MA8007288
Isotactic Polypropylene-Based Stereoregular Diblock Copolymers: Syntheses and Self-Assembly
Jing-Chung Kuo (2008)
10.1002/POLA.23864
Titanium‐mediated [CpTiCl2(OEt)] ring‐opening polymerization of lactides: A novel route to well‐defined polylactide‐based complex macromolecular architectures
Nikolaos Petzetakis (2010)
10.1016/S0079-6700(01)00011-9
Melt rheology of polyolefins
M. Gahleitner (2001)
10.1021/JA990617K
Silicon-Modified Ziegler−Natta Polymerization. Catalytic Approaches to Silyl-Capped and Silyl-Linked Polyolefins Using “Single-Site” Cationic Ziegler−Natta Catalysts
Kwangmo Koo (1999)
10.1021/JA029604O
Origin of the regiochemistry of propene insertion at octahedral column 4 polymerization catalysts: design or serendipity?
G. Talarico (2003)
10.1002/MACP.200800463
Block Copolymer Synthesis via Chemoselective Stepwise Coupling Reactions
Vasilios Bellas (2009)
10.1021/MA047381B
Solid-State 13C NMR Investigation of the Oxidative Degradation of Selectively Labeled Polypropylene by Thermal Aging and γ-Irradiation
D. M. Mowery (2005)
10.1021/JA01188A026
Synthesis of Multichain Polymers and Investigation of their Viscosities1
J. R. Schaefgen (1948)
10.1016/J.PROGPOLYMSCI.2008.05.001
Cylindrical molecular brushes: Synthesis, characterization, and properties
S. Sheiko (2008)
10.1002/1615-4169(200207)344:5<477::AID-ADSC477>3.0.CO;2-6
FI Catalysts: A New Family of High Performance Catalysts for Olefin Polymerization
H. Makio (2002)
10.1002/PEN.20798
The rheological and physical properties of linear and branched polypropylene blends
T. J. McCallum (2007)
10.1021/MA011074D
Metallocene-Mediated Olefin Polymerization with B−H Chain Transfer Agents: Synthesis of Chain-End Functionalized Polyolefins and Diblock Copolymers
T. Chung (2001)
10.1002/APP.25869
Grafting poly(t-butyl acrylate) to poly(allylamine) by inverse microemulsion radical polymerization: From comb-polymer to amphiphilic shell crosslinked polymer nanocapsule
D. Sarkar (2007)
10.1002/marc.200900494
Star-Shaped Polyacrylates: Highly Functionalized Architectures via CuAAC Click Conjugation.
M. Lammens (2009)
10.1295/POLYMJ.31.332
Reactivity of Aluminum-Functionalized Isotactic Polypropylene with Molecular Oxygen
S. Kojoh (1999)
10.1021/ja108441d
Core-clickable PEG-branch-azide bivalent-bottle-brush polymers by ROMP: grafting-through and clicking-to.
J. A. Johnson (2011)
10.1021/MA00060A042
Synthesis of polypropylenes functionalized with secondary amino groups at the chain ends
T. Shiono (1993)
10.1021/MA048753J
Structure and Physical Properties of Syndiotactic Polypropylene from Living Polymerization with Bis(phenoxyimine)-Based Titanium Catalysts
C. Rosa (2004)
10.1021/MA8009323
Investigation of the Assembly of Comb Block Copolymers in the Solid State
M. Runge (2008)
10.1002/1521-3927(20001101)21:16<1103::AID-MARC1103>3.0.CO;2-F
Synthesis of vinyl‐terminated isotactic poly(propylene)
Weiqing Weng (2000)
10.1016/J.PROGPOLYMSCI.2005.11.002
Structure and physical properties of syndiotactic polypropylene: A highly crystalline thermoplastic elastomer
C. Rosa (2006)
10.1021/CR990286U
Precise control of polyolefin stereochemistry using single-site metal catalysts.
G. Coates (2000)
10.1021/MA9703923
A Four-State Scheme for Treating Polymer Crystallization and Melting Suggested by Calorimetric and Small Angle X-ray Scattering Experiments on Syndiotactic Polypropylene†
J. Schmidtke (1997)
10.1021/MA025902U
Living and Block Copolymerization of Ethylene and α-Olefins Using Palladium(II)−α-Diimine Catalysts
Amy C. Gottfried (2003)
10.1021/CR9901337
Polymers with complex architecture by living anionic polymerization.
N. Hadjichristidis (2001)
10.1002/POLA.10653
Synthesis of branched polypropylene with isotactic backbone and atactic side chains by binary iron and zirconium single‐site catalysts
Z. Ye (2003)
10.1021/MA900329Y
Bottle-Brush Brushes: Cylindrical Molecular Brushes of Poly(2-oxazoline) on Glassy Carbon
N. Zhang (2009)
10.1021/MA035120G
Bis(phenoxyimine)zirconium and -titanium catalysts affording prevailingly syndiotactic polypropylenes via opposite modes of monomer insertion
M. Lamberti (2004)
10.1023/A:1019115801193
Chain transfer reactions in propylene polymerization with zirconocene catalysts
L. Resconi (1999)
10.1002/MACP.1987.021880605
Syntheses and characterization of terminally functionalized polypropylenes
Y. Doi (1987)
10.1002/POL.1982.180201210
Crystallization kinetics of syndiotactic polypropylene
R. L. Miller (1982)
10.1021/OM950197H
High-Molecular-Weight Atactic Polypropylene from Metallocene Catalysts. 1. Me2Si(9-Flu)2ZrX2 (X = Cl, Me)
L. Resconi (1996)
10.1002/(SICI)1521-3927(19981201)19:12<651::AID-MARC651>3.0.CO;2-E
Isotactic-specific polymerization of propene with an iron-based catalyst : polymer end groups and regiochemistry of propagation
C. Pellecchia (1998)
10.1002/POLA.23709
Stepped association of comb‐like and stimuli‐responsive graft chitosan copolymer synthesized using ATRP and active ester conjugation methods
Hongqian Bao (2009)
10.1021/MA9805248
Equilibrium Melting Temperature of Syndiotactic Polypropylene
C. Rosa (1998)
10.1002/POLA.22817
Syntheses of Polyolefin-Based Stereoregular Diblock Copolymers for Self-Assembled Nanostructures
Wenfu Lin (2008)
10.1021/CR980461R
Advances in non-metallocene olefin polymerization catalysis.
V. Gibson (2003)
10.1002/POLA.23140
Multiarm Star Block Copolymers via Diels-Alder Click Reaction
A. Dag (2009)
10.1021/JO00050A037
Stereoselection in thermal asymmetric Diels-Alder reactions. Electronic vs. steric effects
B. Stammen (1992)
10.1021/JA0711617
Synthesis of molecular brushes by "grafting onto" method: combination of ATRP and click reactions.
Haifeng Gao (2007)
10.1021/CR9804691
Selectivity in propene polymerization with metallocene catalysts.
L. Resconi (2000)
10.1002/MASY.200450930
Polymacromonomers with polyolefin branches synthesized by free‐radical homopolymerization of polyolefin macromonomer with a methacryloyl end group
Hideyuki Kaneko (2004)
10.1016/J.POLYMER.2011.04.020
Synthesis of complex architectures of comb block copolymers
J. Yoo (2011)
10.1021/MA00039A006
Synthesis of terminally aluminum-functionalized polypropylene
T. Shiono (1992)
10.1021/ja901936g
Well-defined organic nanotubes from multicomponent bottlebrush copolymers.
K. Huang (2009)
10.1002/POLA.21538
Novel organosoluble polynorbornene bearing a polar, pendant, ester‐bridged epoxy group via living ring‐opening metathesis polymerization
Der-Jang Liaw (2006)
10.1021/MA981698S
Polymerization of Propylene by a New Generation of Iron Catalysts: Mechanisms of Chain Initiation, Propagation, and Termination
B. L. Small (1999)
10.1002/POLC.5070160503
Crystal structure of syndiotactic polypropylene: CRYSTAL STRUCTURE OF SYNDIOTACTIC POLYPROPYLENE
P. Corradini (1967)
10.1021/MA050263J
Synthesis of block and graft copolymers with linear polyethylene segments by combination of degenerative transfer coordination polymerization and atom transfer radical polymerization
Hiromu Kaneyoshi (2005)
10.1021/MA801469S
Synthesis of Chain End Functional Isotactic Polypropylene by the Combination of Metallocene/MAO Catalyst and Organoborane Chain Transfer Agent
W. Lin (2008)
10.1016/J.PROGPOLYMSCI.2006.01.001
Crystallization and melting of bulk polymers: New observations, conclusions and a thermodynamic scheme
G. Strobl (2006)
10.1039/A801933I
Novel olefin polymerization catalysts based on iron and cobalt
G. Britovsek (1998)
10.1122/1.1567751
Separating the effects of sparse long-chain branching on rheology from those due to molecular weight in polyethylenes
J. Doerpinghaus (2003)
10.1021/MA030118A
Synthesis of Well-Defined Star-Branched Polymers by Coupling Reactions of Polymer Anions Consisting of Two Polymer Chains with Chain-End-Multifunctionalized Polystyrenes with Benzyl Bromide Moieties
A. Hirao (2003)
10.1021/MA0109119
Polymorphism in Syndiotactic Polypropylene: Thermodynamic Stable Regions for Form I and Form II in Pressure−Temperature Phase Diagram
S. Rastogi (2001)
10.1021/cr1003634
Multinuclear olefin polymerization catalysts.
M. Delferro (2011)
10.1021/MA961691F
Disordered polymorphic modifications of form I of syndiotactic polypropylene
C. Rosa (1997)
10.1016/J.POLYMER.2008.03.029
Precision polyolefin structure: Modeling polyethylene containing alkyl branches
Giovanni Rojas (2008)
10.1002/APP.26048
Synthesis of a linear polyethylene macromonomer and preparation of polystyrene-graft-polyethylene copolymers via grafting-through atom transfer radical polymerization†
Hiromu Kaneyoshi (2007)
10.1021/MA052012G
Synthesis of Comb Block Copolymers by ROMP, ATRP, and ROP and Their Assembly in the Solid State
M. Runge (2006)
10.1021/ja908379q
Efficient synthesis of narrowly dispersed brush copolymers and study of their assemblies: the importance of side chain arrangement.
Y. Xia (2009)
10.1021/MA902513N
Synthesis of Hetero-Grafted Amphiphilic Diblock Molecular Brushes and Their Self Assembly in Aqueous Medium
Z. Li (2010)
10.1002/anie.200804445
Polyethylene building blocks by catalyzed chain growth and efficient end functionalization strategies, including click chemistry.
Rémi Briquel (2008)
10.1002/MACP.200390106
Propylene polymerization with rac-SiMe2(2-Me-4-Phind)2ZrMe2/MAO: Polymer characterization and kinetic models
M. Lahelin (2003)
10.1021/JO9908703
Ruthenium Carbene-Based Olefin Metathesis Initiators: Catalyst Decomposition and Longevity
M. Ulman (1999)
10.1002/MARC.200300050
The Strength of the Macromonomer Strategy for Complex Macromolecular Architecture: Molecular Characterization, Properties and Applications of Polymacromonomers
N. Hadjichristidis (2003)
10.1002/MACP.200800560
Methacryloyl and/or Hydroxyl End-Functional Star Polymers Synthesized by ATRP Using the Arm-First Method
S. Ohno (2009)



This paper is referenced by
10.1021/jp404394y
Small angle X-ray scattering investigation of norbornene-terminated syndiotactic polypropylene and corresponding comb-like poly(macromonomer).
F. Auriemma (2013)
10.1039/C4RA11056K
In situ compatibilisation of alkenyl-terminated polymer blends using cross metathesis
Camille Descour (2015)
10.1016/J.CCLET.2014.01.001
A convenient, highly-efficient method for preparation of hydroxyl-terminated isotactic poly(propylene) and functional di-block copolymer
Ya-nan Ye (2014)
10.1002/MREN.201500054
A Comprehensive Review on Controlled Synthesis of Long‐Chain‐Branched Polyolefins: Part 2, Multiple Catalyst Systems and Prepolymer Modification
W. Liu (2016)
10.1007/s12039-014-0623-y
Ring opening of monocyclic dimethyl cyclopropene via metathesis by tungsten catalyst– A computational study
J. S. Meena (2014)
10.1016/J.SSI.2014.05.012
Investigating polypropylene-poly(ethylene oxide)-polypropylene triblock copolymers as solid polymer electrolytes for lithium batteries☆
N. Young (2014)
10.1016/J.CCR.2014.02.026
The chemistry of the carbon-transition metal double and triple bond: Annual survey covering the year 2012
J. W. Herndon (2014)
10.1002/MACP.201300749
Synthesis and Properties of Polyethylene‐Bound Antioxidants
Y. Zhang (2014)
10.1021/MA501647M
Stereoblock-like Brush Copolymers Consisting of Poly(l-lactide) and Poly(d-lactide) Side Chains along Poly(norbornene) Backbone: Synthesis, Stereocomplex Formation, and Structure–Property Relationship
Takuya Isono (2014)
10.1021/ACS.MACROMOL.5B01176
Importance of Macromonomer Quality in the Ring-Opening Metathesis Polymerization of Macromonomers
Yew Chin Teo (2015)
10.1016/J.EURPOLYMJ.2013.01.008
Cyclobutenyl macromonomers: Synthetic strategies and ring-opening metathesis polymerization
D. Le (2013)
10.1002/MACP.201400379
Synthesis of High‐Molecular‐Weight Brush Polymers via RAFT Polymerization within the Micellar Nanoreactor of a PEG‐Based Macromonomer
N. Li (2015)
10.1039/C8QM00201K
A novel post-polymerizable polynorbornene prepared via ROMP: easy synthesis and conversion into a free-standing film with high Tg and low dielectric constant
J. Wang (2018)
10.1021/MZ500082H
Molecular Weight Dependence of Zero-Shear Viscosity in Atactic Polypropylene Bottlebrush Polymers
Samuel J. Dalsin (2014)
10.1021/ACS.MACROMOL.5B02652
Well-Defined Bilayered Molecular Cobrushes with Internal Polyethylene Blocks and ω-Hydroxyl-Functionalized Polyethylene Homobrushes
Hefeng Zhang (2016)
10.1039/C4PY00815D
Well-defined polyethylene molecular brushes by polyhomologation and ring opening metathesis polymerization
Hefeng Zhang (2014)
10.5772/intechopen.92067
Introductory Chapter: Polypropylene - Synthesis and Functionalization
Weiyu Wang (2020)
10.1039/C3PY01611K
Synthesis and polymerization of cyclobutenyl-functionalized polylactide and polycaprolactone: a consecutive ROP/ROMP route towards poly(1,4-butadiene)-g-polyesters
Flavien Leroux (2014)
10.1002/MACP.201300695
Synthesis and Characterization of Comb‐Like Copolymers Based on Poly(ε‐caprolactone) and Poly(α‐olefin)
Sabina Kinder (2014)
10.1021/ACS.MACROMOL.5B01153
Linear Rheology of Polyolefin-Based Bottlebrush Polymers
Samuel J. Dalsin (2015)
10.1021/ACS.MACROMOL.5B00713
Well-Defined Polyethylene-Based Random, Block, and Bilayered Molecular Cobrushes
Hefeng Zhang (2015)
10.1002/POLA.27029
Use of an isotactic‐propylene/hexene copolymer as a new, versatile, soluble support
Abbey Hicks (2014)
10.1016/J.TETLET.2012.12.046
Terminal functionalization of atactic polypropylene: a new soluble polymer support
Binhong Lin (2013)
10.1021/ACS.MACROMOL.5B02295
Stereoregular High-Density Bottlebrush Polymer and Its Organic Nanocrystal Stereocomplex through Triple-Helix Formation
J. M. Ren (2016)
10.1039/c4cs00329b
Structure, function, self-assembly, and applications of bottlebrush copolymers.
Rafael Verduzco (2015)
10.1039/c8dt03052a
Cycloheptyl-fused N,N,N'-chromium catalysts with selectivity for vinyl-terminated polyethylene waxes: thermal optimization and polymer functionalization.
Chuanbing Huang (2018)
10.1039/C7PY00581D
C1 polymerization: a unique tool towards polyethylene-based complex macromolecular architectures
De Wang (2017)
10.1039/C3PY00727H
Facile synthesis of chain end functionalized polyethylenes via epoxide ring-opening and thiol–ene addition click chemistry
Y. Zhang (2014)
Semantic Scholar Logo Some data provided by SemanticScholar