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Ruthenium-catalyzed Ring-opening And Ring-closing Enyne Metathesis.

T. Kitamura, M. Mori
Published 2001 · Chemistry, Medicine

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[reaction: see text]. When a CH2Cl2 solution of an enyne containing the cycloalkene moiety was stirred in the presence of ruthenium-carbene complex (10 mol %) at room temperature under ethylene gas (1 atm), ring-opening and ring-closing metathesis occurred to afford cyclized triene. The reaction was carried out under argon gas, and no cyclized product was obtained. Enynes with a terminal alkyne gave good results.
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