Online citations, reference lists, and bibliographies.
← Back to Search

RGe(I)Ge(I)R Compound (R = PhC(NtBu)2) With A Ge−Ge Single Bond And A Comparison With The Gauche Conformation Of Hydrazine†

Selvarajan Nagendran, S. S. Sen, H. Roesky, Debasis Koley, H. Grubmüller, A. Pal, R. Herbst-Irmer
Published 2008 · Chemistry

Cite This
Download PDF
Analyze on Scholarcy
Share
This article reports the reduction of the chloride [PhC(NtBu)2]GeCl with potassium in THF to afford the reddish crystals of [PhC(NtBu)2]2Ge2 (2). The molecule of 2 contains a Ge−Ge bond. The X-ray structure and DFT calculation indicate that the Ge−Ge bond possesses an unusual gauche-bent geometry. The Ge−Ge bond length in 2 is 2.570 A, which is very close to the single Ge−Ge interaction (2.61 A) but significantly longer than that for typical digermenes, R2GeGeR2 (2.21−2.51 A) and the two structurally characterized digermynes (2.2850 A and 2.2060 A), which proves that there is no multiple bond character in 2.
This paper references



This paper is referenced by
10.1039/c6dt01616b
Germylenes and stannylenes stabilized within N2PE rings (E = Ge or Sn): combined experimental and theoretical study.
J. Vrána (2016)
10.1016/J.CCR.2009.07.014
Bulky guanidinates for the stabilization of low oxidation state metallacycles
Cameron J. Jones (2010)
10.1021/ic3016194
Bis(amidinato)germylenerhodium complexes: synthesis, structure, and density functional theory calculations.
D. Matioszek (2012)
10.1021/OM500698K
Intramolecularly C,N-Coordinated Homo- and Heteroleptic Organostannylenes
M. Novak (2014)
10.1002/anie.201202175
Bis(silylenyl)- and bis(germylenyl)-substituted ferrocenes: synthesis, structure, and catalytic applications of bidentate silicon(II)-cobalt complexes.
W. Wang (2012)
10.1021/OM101194F
Synthesis and Characterization of an Amidinate-Stabilized Bisgermylene Oxide and Sulfide
S. Zhang (2011)
10.1021/acs.inorgchem.5b00084
Amidinatogermylene derivatives of ruthenium carbonyl: new insights into the reactivity of [Ru3(CO)12] with two-electron-donor reagents of high basicity.
L. Álvarez-Rodríguez (2015)
10.1002/ANGE.202001178
Indirekte und direkte Anknüpfung von Übergangsmetallen an Silicoide
Nadine E Poitiers (2020)
10.1002/EJIC.200900233
Heteroleptic Amidinate Complexes of Heavy Group 15 Elements – Synthesis, X‐ray Crystal Structures and Theoretical Calculations
Benjamin Lyhs (2009)
10.1039/c7dt01796k
Carbene stabilized interconnected bis-germylene and its silicon analogue with small methyl substituents.
Subrata Kundu (2017)
10.1002/EJIC.201500074
Germanium(II) and Tin(II) Halide Complexes Containing the Triimido Sulfur(VI) Phosphanyl Ligand
E. Carl (2015)
10.1021/ar2002073
Interconnected bis-silylenes: a new dimension in organosilicon chemistry.
S. S. Sen (2012)
10.1002/poc.4032
Estimating the stability and reactivity of cyclic tetrahalo substituted germylenes: A density functional theory investigation
M. Koohi (2020)
10.1039/c7dt01055a
Strikingly diverse reactivity of structurally identical silylene and stannylene.
Nasrina Parvin (2017)
10.1002/anie.201805936
Silanylidene and Germanylidene Anions: Valence-Isoelectronic Species to the Well-Studied Phosphinidene.
Mujahuddin M. Siddiqui (2018)
10.1002/EJIC.201000803
Synthesis of Monomeric Divalent Tin(II) Compounds with Terminal Chloride, Amide, and Triflate Substituents
S. S. Sen (2010)
10.1021/acs.inorgchem.5b01643
Alkaline-Earth-Metal-Induced Liberation of Rare Allotropes of Elemental Silicon and Germanium from N-Heterocyclic Metallylenes.
Burgert Blom (2015)
10.1039/c2cc18086c
Contrasting reductions of group 14 metal(II) chloride complexes: synthesis of a β-diketiminato tin(I) dimer.
Sam L. Choong (2012)
10.1021/ja207538g
Preparation of RSn(I)-Sn(I)R with two unsymmetrically coordinated Sn(I) atoms and subsequent gentle activation of P4.
S. Khan (2011)
10.1039/c7dt01950e
Facile activation of alkynes with a boraguanidinato-stabilized germylene: a combined experimental and theoretical study.
Jiří Böserle (2017)
10.1039/c9dt02562f
Kinetic stabilization of low-oxidation state and terminal hydrido main group metal complexes by a sterically demanding N,N'-bis(2,6-terphenyl)triazenide.
Anthony R Leverett (2019)
10.1002/chem.201403598
Can low-valent germanium chemistry be practiced under ambient conditions? A tale of a water-stable yet reactive germylene monochloride complex.
C. Jha (2014)
10.1039/c2dt32654j
Expanding the coordination chemistry of donor-stabilized group-14 metalenes.
J. A. Cabeza (2013)
10.1016/J.CCR.2015.04.008
The transition-metal chemistry of amidinatosilylenes, -germylenes and -stannylenes
L. Álvarez-Rodríguez (2015)
10.1039/c3cc49635j
A functionalized Ge3-compound with a dual character of the central germanium atom.
Yan Li (2014)
10.1002/chem.201300447
Zwitterionic base-stabilized digermadistannacyclobutadiene and tetragermacyclobutadiene.
Hui-Xian Yeong (2013)
10.1002/anie.201605636
Isolation and Structure of Germylene-Germyliumylidenes Stabilized by N-Heterocyclic Imines.
T. Ochiai (2016)
10.1039/c9dt03803e
A diamidinatogermylene as a Z-type ligand in a nickel(0) complex.
Zhongtao Feng (2019)
10.1021/OM501074M
Oxidative Additions of Homoleptic Tin(II) Amidinate
T. Chlupatý (2015)
10.1007/s00894-011-1122-4
Architecture, electronic structure and stability of TM@Ge(n) (TM = Ti, Zr and Hf; n = 1-20) clusters: a density functional modeling
M. Kumar (2011)
10.1002/anie.200902995
A remarkable base-stabilized bis(silylene) with a silicon(I)-silicon(I) bond.
S. S. Sen (2009)
10.1002/ANGE.201407751
Eine mehrfach funktionalisierte Basen‐koordinierte GeII‐Verbindung und ihre reversible Dimerisierung zum Digermen
Anukul Jana (2015)
See more
Semantic Scholar Logo Some data provided by SemanticScholar