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Isolated Surface Hydrides: Formation, Structure, And Reactivity.

C. Copéret, D. Estes, Kim Larmier, Keith Searles
Published 2016 · Chemistry, Medicine

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Surface hydrides are ubiquitous in catalysis. However, their structures and properties are not as well-understood as those of their molecular counterparts, which have been extensively studied for the past 70 years. Hydrides isolated on surfaces have been characterized as stable entities on oxide surfaces or in zeolites. They have also been proposed as reaction intermediates in numerous catalytic processes (hydrogenation, hydrogenolysis, etc.). They have also been prepared via surface organometallic chemistry. In this review, we describe their key structural features and spectroscopic signatures. We discuss their reactivity and stability and also point out unexplored areas.
This paper references
10.1016/0021-9517(78)90288-9
Infrared study of ZnO surface properties: I. Hydrogen and deuterium chemisorption at room temperature
F. Boccuzzi (1978)
10.1126/science.1143078
Dinitrogen Dissociation on an Isolated Surface Tantalum Atom
P. Avenier (2007)
10.1021/IC980443S
THEORETICAL INVESTIGATION OF THE CHEMISORPTION OF H2 AND CO ON THE ZNO(1010) SURFACE
M. Casarin (1998)
10.1524/zpch.1980.121.1.141
Evidence for Heterolytic Dissociation of H2 on the Surface of Thermally Activated MgO Powders
S. Coluccia (1980)
10.1021/JP4037588
From Heterolytic to Homolytic H2 Dissociation on Nanostructured MgO(001) Films As a Function of the Metal Support
H. Chen (2013)
zeolites: a theoretical study
G. M. Zhidomirov (2000)
10.1007/S11244-006-0108-4
Alumina supported tungsten hydrides, new efficient catalysts for alkane metathesis
M. Taoufik (2006)
10.1246/CL.1975.659
HYDROGENATION OF OLEFINS CATALYZED BY ALKALINE EARTH METAL OXIDES
H. Hattori (1975)
Genesis of a Ruthenium Complex Catalyst
C. Aydin (2009)
10.1109/23.211420
Room temperature reactions involving silicon dangling bond centers and molecular hydrogen in amorphous SiO/sub 2/ thin films on silicon
J. Conley (1992)
10.1039/C4NJ00352G
Reactivity of silica supported zirconium hydride towards N2O and CO2 probe molecules: a computational point of view
Mahboubeh Poor Kalhor (2014)
10.1021/JP8113607
Structure-reactivity relationship for catalytic activity of gallium oxide and sulfide clusters in zeolite
E. Pidko (2009)
10.1515/MGMC.2002.25.1-2.15
SURFACE ΟRGANOMETALLIC CHEMISTRY ΟF TIN, GERMANIUM AND ARSENIC
F. Lefebvre (2002)
10.1021/OM070145F
Synthesis, Characterization, and Catalytic Properties of γ-Al2O3-Supported Zirconium Hydrides through a Combined Use of Surface Organometallic Chemistry and Periodic Calculations
J. Joubert (2007)
10.1016/J.CPLETT.2012.04.052
Hydrogenation of lower alkenes and conjugated diene catalyzed by Ga2O3
Tetsuya Shishido (2012)
10.1021/ACS.JPCC.5B04028
Methane Interaction with Zn2+-Exchanged Zeolite H-ZSM-5: Study of Adsorption and Mobility by One- and Two-Dimensional Variable-Temperature 1H Solid-State NMR
M. V. Luzgin (2015)
10.1002/cssc.201402632
On the chemistry of ethanol on basic oxides: revising mechanisms and intermediates in the Lebedev and Guerbet reactions.
A. Chieregato (2015)
10.1039/C39800000357
Synthesis and partial characterization of (silica)rhodium dihydrides: a new catalyst for olefin hydrogenation
M. Ward (1980)
10.1016/J.JCAT.2006.03.011
A comprehensive density functional theory study of ethane dehydrogenation over reduced extra-framework gallium species in ZSM-5 zeolite
E. Pidko (2006)
10.1039/c3cc47296e
A stable 16-electron iridium(III) hydride complex grafted on SBA-15: a single-site catalyst for alkene hydrogenation.
Martino Rimoldi (2013)
10.1039/B616921J
Synthesis, characterization and propane metathesis activity of a tantalum-hydride prepared on high surface area "silica supported zirconium hydroxide".
F. Rataboul (2007)
10.1039/B008699L
Novel inorganic oxide supported organotin hydrides forfine chemical catalysis
Q. J. Fu (2001)
10.1002/cssc.201100223
Tailored ruthenium-N-heterocyclic carbene hybrid catalytic materials for the hydrogenation of carbon dioxide in the presence of amine.
Mathieu Baffert (2011)
10.1021/JP055104G
Theoretical study on the dehydrogenation reaction of alkanes catalyzed by zeolites containing nonframework gallium species.
M. Pereira (2006)
10.1039/c0cp02088e
On the nature of gallium species in gallium-modified mordenite and MFI zeolites. A comparative DRIFT study of carbon monoxide adsorption and hydrogen dissociation.
A. I. Serykh (2011)
10.1016/J.MOLCATA.2006.04.051
Heterolytic dissociation and recombination of H2 over Zn,H-ZSM-5 zeolites—A density functional model study
Hristiyan A Aleksandrov (2006)
10.1016/0039-6028(70)90040-3
Polar surfaces of wurtzite and zincblende lattices
R. W. Nosker (1970)
and catalytic hydrogenation reactions of alkynes and alkenes
B. Marciniec (1988)
10.1063/1.1378308
On the role of electrostatics in the heterolytic splitting of covalent bonds at defective oxide surfaces
A. D'ercole (2001)
10.1021/JP990117D
Embedded-cluster study of hydrogen interaction with an oxygen vacancy at the magnesium oxide surface
A. D'ercole (1999)
10.1039/FT9908601615
A Fourier-transform spectral-ratioed reinvestigation of the infrared spectra from H2 and D2 adsorbed on ZnO at room temperature and at 160 °C
G. Hussain (1990)
10.1016/0039-6028(88)90220-8
The interaction of tris(allyl)rhodium with (001) titanium dioxide
P. B. Smith (1988)
10.1002/ANIE.200501382
Development of tungsten-based heterogeneous alkane metathesis catalysts through a structure-activity relationship.
E. Le Roux (2005)
10.1021/ja3008566
Nature and structure of aluminum surface sites grafted on silica from a combination of high-field aluminum-27 solid-state NMR spectroscopy and first-principles calculations.
R. Kerber (2012)
10.1021/JA983940G
PREPARATION, CHARACTERIZATION, AND PERFORMANCE OF TRIPODAL POLYPHOSPHINE RHODIUM CATALYSTS IMMOBILIZED ON SILICA VIA HYDROGEN BONDING
C. Bianchini (1999)
anchoring organic and organometallic complexes
M. Rimoldi (2011)
10.1016/J.CATTOD.2010.10.003
Ethanol catalytic condensation over Mg–Al mixed oxides derived from hydrotalcites
M. León (2011)
10.1016/0304-5102(77)80013-8
Formation of zirconium hydrides in supported organozirconium catalysts and their role in ethylene polymerization
V. Zakharov (1977)
10.1002/MAWE.201300115
Platinum nanoparticles on the surface of silica modified with silicon hydride groups
V. Tertykh (2013)
10.1111/J.1551-2916.2004.00683.X
Thermodynamic Assessment of the Gallium‐Oxygen System
M. Zinkevich (2004)
10.1016/S0920-5861(98)00504-5
IR study of polycrystalline ceria properties in oxidised and reduced states
C. Binet (1999)
10.1021/ja3042383
γ-Alumina: the essential and unexpected role of water for the structure, stability, and reactivity of "defect" sites.
Raphael Wischert (2012)
10.1063/1.3485049
Hydrogen related defect complexes in ZnO nanoparticles
K. Senthilkumar (2010)
10.1021/JP0487410
Vibrational and Thermodynamic Properties of H2 Adsorbed on MgO in the 300−20 K Interval
E. Gribov (2004)
10.1021/AC00054A027
A New Approach for the Preparation of a Hydride-Modified Substrate Used as an Intermediate in the Synthesis of Surface-Bonded Materials
C. Chu (1993)
10.1016/0926-860X(93)80276-V
Intermediate species on zirconia supported methanol aerogel catalysts: I. State of the catalyst surface before and after the adsorption of hydrogen
D. Bianchi (1993)
10.1016/J.CPLETT.2010.07.063
Metal-alkyl species are formed on interaction of small alkanes with gallium oxide: Evidence from solid-state NMR
A. Gabrienko (2010)
10.1016/0039-6028(81)90476-3
Hydrogen on WO3(001)
R. D. Bringans (1981)
10.1016/J.JCAT.2008.03.018
Defect formation and the water–gas shift reaction on β-Ga2O3
W. Jochum (2008)
10.1016/J.JCAT.2005.05.004
DRIFTS study of the nature and chemical reactivity of gallium ions in Ga/ZSM-5: II. Oxidation of reduced Ga species in ZSM-5 by nitrous oxide or water
V. Kazansky (2005)
10.1134/S0036024407050184
The activation of C-H bonds in C1-C3 alkanes by zirconium(III,IV) and titanium(III,IV) hydrides immobilized on the surface of SiO2: a density functional theory study
L. Ustynyuk (2007)
10.1016/0304-5102(89)80182-8
Surface hydride complexes of group IV transition metals as active sites for polymerization and hydrogenation reactions
V. Zakharov (1989)
10.1021/JA00173A009
Organometallic molecule-inorganic surface coordination and catalytic chemistry. In situ CPMAS NMR delineation of organoactinide adsorbate structure, dynamics, and reactivity
W. Finch (1990)
10.1021/JP072110Z
Dehydrogenation of light alkanes over isolated gallyl ions in Ga/ZSM-5 zeolites
E. Pidko (2007)
10.1002/CHIN.198335330
Surface organometallic chemistry: reactivity of silica-bound rhodium allyl complexes and the genesis of highly dispersed supported rhodium catalysts
H. Foley (1983)
10.1016/S0920-5861(00)00607-6
Properties of chemisorbed hydrogen species on Ag-A zeolite partially reduced with hydrogen as studied by 1H MAS NMR
T. Baba (2001)
10.1520/STP18605S
Influence of Impurities and Defects on 1064 nm and 532 nm Damage in Quartz
Ld Merkle (1988)
10.1016/J.SNB.2004.04.041
CO-sensing properties of doped SnO2 sensors in H2-rich gases
O. Wurzinger (2004)
10.1016/0021-9517(71)90271-5
Adsorption of hydrogen and H2-D2 exchange reaction on alumina
Y. Amenomiya (1971)
In IR Di ff use Re fl ectance Study of oxide Catalysts
V. B. Kazansky (1984)
10.1021/JP993804D
Hydrogen Cracking in SiO 2 : Kinetics for H 2 Dissociation at Silicon Dangling Bonds †
H. A. Kurtz (2000)
10.1021/LA990849X
1H Magic Angle Spinning NMR Evidence for Dissociative Adsorption of Hydrogen on Ag+-Exchanged A- and Y-Zeolites
T. Baba (1999)
10.1016/S0021-9517(02)00117-3
Localization of bivalent transition metal ions in high-silica zeolites with the very broad range of Si/Al ratios in the framework probed by low-temperature H2 adsorption
V. B. Kazansky (2003)
10.1016/J.JCAT.2014.10.018
Selective propane dehydrogenation with single-site CoII on SiO2 by a non-redox mechanism
Bo Hu (2015)
10.1021/LA00075A004
Concentration of hydroxyl groups on the surface of amorphous silicas
L. T. Zhuravlev (1987)
10.1016/J.SUSC.2013.09.020
Formation of metastable, heterolytic H-pairs on the RuO2(110) surface
Y. Wei (2014)
10.1016/J.JCAT.2006.02.017
Support effect in dehydrogenation of propane in the presence of CO2 over supported gallium oxide catalysts
B. Xu (2006)
10.1016/J.TSF.2005.11.044
The oxidation kinetics of magnesium at low temperatures and low oxygen partial pressures.
M. Kurth (2006)
10.1016/0038-1098(73)90754-0
Exciton thermoreflectance of MgO and CaO
R. Whited (1973)
10.1126/science.271.5251.966
Catalytic Cleavage of the C-H and C-C Bonds of Alkanes by Surface Organometallic Chemistry: An EXAFS and IR Characterization of a Zr-H Catalyst
J. Corker (1996)
10.1016/B978-0-08-097774-4.00931-1
H–H Bond Activation
R. Mas-Ballesté (2013)
10.1002/cctc.201100130
Efficient Hydrogenolysis of Alkanes at Low Temperature and Pressure Using Tantalum Hydride on MCM‐41, and a Quantum Chemical Study
V. Polshettiwar (2012)
10.1021/OM0007926
Hydrogen/Deuterium Exchange Kinetics by a Silica-Supported Zirconium Hydride Catalyst: Evidence for a σ-Bond Metathesis Mechanism
Gary L. Casty (2001)
b-Ga2O3 (100) surface containing oxygen vacancies
W. Jochum (2005)
Theoretical Investigation of the Chemisorption of H(2) and CO on the ZnO(10&onemacr;0) Surface.
M. Casarin (1998)
10.1021/JA00037A031
Surface organometallic chemistry: reaction of tris(allyl)rhodium with surfaces of silica, alumina, titania and magnesia
Pascal Dufour (1992)
10.1021/JP049224K
Intensities of IR stretching bands as a criterion of polarization and initial chemical activation of adsorbed molecules in acid catalysis. Ethane adsorption and dehydrogenation by zinc ions in ZnZSM-5 zeolite.
V. Kazansky (2005)
10.1021/JA0282240
Paramagnetic defect centers at the MgO surface. An alternative model to oxygen vacancies.
D. Ricci (2003)
10.1021/ja038486h.s001
Molecular understanding of the formation of surface zirconium hydrides upon thermal treatment under hydrogen of [([triple bond]SiO)Zr(CH2tBu)3] by using advanced solid-state NMR techniques.
F. Rataboul (2004)
Surface: A FirstPrinciples Investigation
M. Menetrey (2011)
10.1021/JP200111X
Characterization of Surface Hydride Hafnium Complexes on Alumina by a Combination of Experiments and DFT Calculations
M. Delgado (2011)
10.1246/CL.1993.1931
Hafnium-Hydride Complexes Anchored to Silica. Catalysts of the Low Temperature Hydrogenolysis of Alkanes and Hydrogenation of Olefins
OrnelasLindora d (1993)
10.1039/b823226a
Selective and unexpected transformations of 2-methylpropane to 2,3-dimethylbutane and 2-methylpropene to 2,3-dimethylbutene catalyzed by an alumina-supported tungsten hydride.
N. Merle (2009)
10.1007/S10562-008-9478-5
Enhanced Activity of Spinel-type Ga2O3–Al2O3 Mixed Oxide for the Dehydrogenation of Propane in the Presence of CO2
M. Chen (2008)
Hydrogenation of Ethylene by Zinc
A. L. Dent (1989)
10.1021/ACSCATAL.5B00723
Mechanistic Investigation of Isopropanol Conversion on Alumina Catalysts: Location of Active Sites for Alkene/Ether Production
Kim Larmier (2015)
10.1021/OM010188A
Synthesis, Characterization, and Properties of Silica-Supported Trimethylphosphine Disiloxy Tantalum Hydride, (⋮SiO)2TaH(PMe3)
M. Taoufik (2001)
10.1021/ACS.JPCC.5B03969
Effect of Si/Al Ratio and Rh Precursor Used on the Synthesis of HY Zeolite-Supported Rhodium Carbonyl Hydride Complexes
K. Khivantsev (2015)
10.1103/PHYSREVB.19.3107
Transmission, photoconductivity, and the experimental band gap of thermally grown SiO 2 films
Z. Weinberg (1979)
10.1007/978-3-319-94983-3_3
First Principles Calculations
P. Alvarez (2018)
10.1002/anie.201505867
Iridium(I)/N-Heterocyclic Carbene Hybrid Materials: Surface Stabilization of Low-Valent Iridium Species for High Catalytic Hydrogenation Performance.
I. Romanenko (2015)
10.1016/0304-5102(86)85082-9
Catalysts prepared by the interaction of transition metal tetrahydroborates with oxide supports: synthesis of surface Ti, Zr, Hf hydrides and their catalytic properties in ethylene polymerization
G. Nesterov (1986)
10.1039/FT9949002969
Chemisorption of H2 and H2—O2 on polymorphic zirconia
K. Jacob (1994)
10.1016/J.JCAT.2008.08.005
Reaction of ethanol over hydroxyapatite affected by Ca/P ratio of catalyst
T. Tsuchida (2008)
10.1021/OM4012399
Kinetics and Mechanism of the Hydrogenation of the CpCr(CO)3•/[CpCr(CO)3]2 Equilibrium to CpCr(CO)3H
J. Norton (2014)
10.1143/JJAP.19.1863
Magnetic Resonance Studies of Hydrogen Adsorbed on Zinc Oxide. II. Proton NMR of Chemisorbed Hydrogen and Molecular Hydrogen Adsorbed Ionically
M. Watanabe (1980)
10.1039/A909426A
Activation of ethane in Zn-exchanged zeolites: a theoretical study
M. Frash (2000)
10.1021/LA0481389
Hydrogen chemisorption on gallium oxide polymorphs.
S. Collins (2005)
10.1016/J.SUSC.2014.05.008
STM and XPS study of CeO2(111) reduction by atomic hydrogen
S. M. F. Shahed (2014)
10.1063/1.1992666
A COMPREHENSIVE REVIEW OF ZNO MATERIALS AND DEVICES
Ü. Özgür (2005)
10.1016/J.SUSC.2004.11.018
Hydrogen adsorption on β-Ga2O3(100) surface containing oxygen vacancies
E. A. Gonzalez (2005)
10.1021/JP013245M
Kinetics and Reaction Pathways for Propane Dehydrogenation and Aromatization on Co/H-ZSM5 and H-ZSM5
S. Y. Yu (2002)
10.1002/ANIE.198811271
Molecular Organometallic Chemistry on Surfaces: Reactivity of Metal Carbonyls on Metal Oxides
H. H. Lamb (1988)
10.1021/JA00707A075
Formation of .pi.-allyl complexes by adsorption of propylene on zinc oxide
A. Dent (1970)
10.1016/0021-9797(82)90046-7
Infrared study of the sorption of HSiCl3 on silica and the stability of the chemisorbed layers
M. Low (1982)
material active toward hydrogen adsorption
D. Scarano (2006)
10.1039/c5sc02276b
Well-defined silica supported aluminum hydride: another step towards the utopian single site dream?† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c5sc02276b Click here for additional data file.
Baraa Werghi (2015)
10.1021/JP1064962
Access to Well-Defined Ruthenium Mononuclear Species Grafted via a Si−Ru Bond on Silane Functionalized Silica†
Fernando Rascón (2011)
10.1021/CR020055E
The surface of inorganic oxides or zeolites as a nonconventional reaction medium for the selective synthesis of metal carbonyl complexes and clusters.
E. Cariati (2003)
10.1063/1.1947372
Interface traps and dangling-bond defects in (100)Ge/HfO2
V. Afanas'ev (2005)
DFT cluster modeling of molecular and dissociative hydrogen adsorption on Zn2+ ions with distant placing of aluminum in the framework of high-silica zeolites
A. Shubina (2003)
10.1021/J100245A019
Active sites for hydrogen adsorption on magnesium oxide
Tomoyasu Ito (1983)
10.1016/J.IJHYDENE.2012.10.108
Mechanism for adsorption, dissociation and diffusion of hydrogen in hydrogen permeation barrier of α-Al2O3: A density functional theory study
Guikai Zhang (2013)
10.1016/J.SNB.2011.05.011
Conduction mechanisms in SnO2 based polycrystalline thick film gas sensors exposed to CO and H2 in different oxygen backgrounds
N. Barsan (2011)
10.1023/A:1018979731407
Study of the acidic character of modified metal oxide surfaces using the test of isopropanol decomposition
A. Gervasini (1997)
10.1007/BF00524013
Formation of Zr3+ compounds in applied organozirconium catalysts and their role in the polymerization of ethylene
N. G. Maksimov (1978)
10.1627/JPI.47.67
固体塩基触媒: 塩基点の発現, キャラクタリゼーションおよび触媒作用
H. Hattori (2004)
10.1039/FT9908600397
Infrared study of hydrogen adsorbed on ZrO2
J. Kondo (1990)
10.1021/ic502696n
Heterolytic Activation of C-H Bonds on Cr(III)-O Surface Sites Is a Key Step in Catalytic Polymerization of Ethylene and Dehydrogenation of Propane.
Matthew P Conley (2015)
10.1039/C39940002011
Surface-mediated organometallic synthesis of [SiO]–[RhH2(PMe3)4]+: the first example of a cationic organometallic complex attached to the silica surface by ion pairing
S. Scott (1994)
10.1021/JP993414R
Activation of small alkanes on Ga-exchanged zeolites: A quantum-chemical study of ethane dehydrogenation
Mv Frash (2000)
10.1021/AR00118A004
Alkane activation by oxide-bound organorhodium complexes
J. Schwartz (1985)
10.1016/j.physleta.2010.08.031
Dissociation of H2 molecule on the β-Ga2O3 (100)B surface: The critical role of oxygen vacancy
Y. Yang (2010)
10.1016/J.SUSC.2008.09.063
The surface chemistry of ZnO nanoparticles applied as heterogeneous catalysts in methanol synthesis
J. Strunk (2009)
10.1021/OM000309R
Preparation, Characterization, and Performance of the Supported Hydrogen-Bonded Ruthenium Catalyst [(sulphos)Ru(NCMe)3](OSO2CF3)/SiO2. Comparisons with Analogous Homogeneous and Aqueous-Biphase Catalytic Systems in the Hydrogenation of Benzylideneacetone and Benzonitrile
C. Bianchini (2000)
Electronic Effects of H2
O. Wurzinger (1993)
10.1016/J.CPLETT.2005.02.108
Theoretical study of the dehydrogenation reaction of ethane catalyzed by zeolites containing non-framework gallium species: The 3-step mechanism × the 1-step concerted mechanism
M. Pereira (2005)
10.1021/J100701A025
Reactive silica. III. Formation of boron hydrides, and other reactions, on the surface of boria-impregnated aerosil
C. Morterra (1970)
10.1021/ACSCATAL.5B00248
Isolated FeII on Silica As a Selective Propane Dehydrogenation Catalyst
Bo Hu (2015)
10.1023/A:1022501613772
Dehydrogenation of propane in the presence of carbon dioxide over oxide-based catalysts
P. Michorczyk (2003)
10.1021/JP201107X
Effect of the Zeolite Cavity on the Mechanism of Dehydrogenation of Light Alkanes over Gallium-Containing Zeolites
M. Pereira (2011)
10.1039/c0dt01369b
Reactions of phosphinites with oxide surfaces: a new method for anchoring organic and organometallic complexes.
B. Vicente (2011)
10.1021/JP2014226
Hydrogen Adsorption on Ga2O3 Surface: A Combined Experimental and Computational Study
Yun-xiang Pan (2011)
10.1021/JP953704H
Hydrogen Dissociation on Reconstructed ZnO Surfaces
M. Nyberg (1996)
10.1016/S0167-2991(01)80143-9
Dissociative adsorption of H2 on defect sites of MgO: A combined IR spectroscopic and quantum chemical study
M. Cavalleri (2001)
10.1049/EL:19930825
Mechanisms of enhanced UV photosensitivity via hydrogen loading in germanosilicate glasses
R. Atkins (1993)
10.1023/B:TOCA.0000003087.47073.DE
Identification and Characterization of Active Sites and Their Catalytic Processes—the Cu/ZnO Methanol Catalyst
S. A. French (2003)
10.1021/AR00014A001
Surface-bound metal hydrocarbyls. Organometallic connections between heterogeneous and homogeneous catalysis
T. Marks (1992)
10.1002/CHEM.200390162
Hydrogenolysis of cycloalkanes on a tantalum hydride complex supported on silica and insight into the deactivation pathway by the combined use of 1D solid-state NMR and EXAFS spectroscopies.
F. Rataboul (2003)
10.1021/ic300498b
Successive heterolytic cleavages of H2 achieve N2 splitting on silica-supported tantalum hydrides: a DFT proposed mechanism.
X. Solans-Monfort (2012)
10.1021/ic501593k
Silica-grafted 16-electron hydride pincer complexes of iridium(III) and their soluble analogues: synthesis and reactivity with CO.
Martino Rimoldi (2014)
10.1016/0021-9517(75)90327-9
The joint application of flow-system and micropulse techniques for a comparative study of 2-propanol decomposition over MgO, CaO and SrO
Z. G. Szabó (1975)
10.1039/c3dt52164h
Activation of carbon-hydrogen bonds and dihydrogen by 1,2-CH-addition across metal-heteroatom bonds.
Joanna R. Webb (2013)
10.1098/rspa.1956.0175
The catalysis of H2—D2 exchange by oxides
D. A. Dowden (1956)
10.1021/J100727A060
Addition of hydrogen-deuterium mixtures to ethylene over chromia and zinc oxide
W. C. Conner (1969)
10.1021/JA0116829
Measurement of the hydride donor abilities of [HM(diphosphine)2]+ complexes (M = Ni, Pt) by heterolytic activation of hydrogen.
C. Curtis (2002)
10.1021/JP0533729
A density functional theory study of molecular and dissociative adsorption of H2 on active sites in mordenite.
L. Benco (2005)
10.1021/cr900122p
C-H bond activation and organometallic intermediates on isolated metal centers on oxide surfaces.
C. Copéret (2010)
10.1039/c2cp42288c
Hydrogen interaction with the anatase TiO2(101) surface.
U. Aschauer (2012)
10.1016/J.CATTOD.2003.12.015
Electron-count control on adsorption upon reducible and irreducible clean metal-oxide surfaces
M. Calatayud (2004)
10.1016/S0021-9517(66)80013-1
On the reduction of tungsten trioxide accelerated by platinum and water
J. E. Benson (1966)
10.1039/A800184G
Dehydrogenation of ethane over gallium oxide in the presence of carbon dioxide
K. Nakagawa (1998)
10.1006/JCAT.2000.2930
In Situ Investigations of Structural Changes in Cu/ZnO Catalysts
J. Grunwaldt (2000)
10.1021/JP1017423
Hydrogen on In2O3: Reducibility, Bonding, Defect Formation, and Reactivity
Thomas Bielz (2010)
10.1021/JP103463S
Hydrogen Adsorption on Monoclinic (1̅11) and (1̅01) ZrO2 Surfaces: A Periodic ab Initio Study
O. Syzgantseva (2010)
10.1016/J.JCAT.2012.12.026
Surface species formed during thermal transformation of ethanol on ZnO powder
Jia Gao (2013)
10.1039/A910239F
H/D exchange between CH4 and CD4 catalysed by a silica supported tantalum hydride, (SiO)2Ta–H
L. Lefort (2000)
10.1039/b815943b
Multinuclear gallium-oxide cations in high-silica zeolites.
E. Pidko (2009)
10.1039/F19827802111
Infrared study of hydrogen adsorption on MgO, CaO and SrO. Possible mechanism in promoting O–2 formation
S. Coluccia (1982)
10.1039/c1cp20923j
Electronic structure and oxygen vacancies in PdO and ZnO: validation of DFT models.
M. K. Bruska (2011)
10.1016/0022-2860(90)80294-T
IR spectra of hydrogen absorbed on solids
G. Busca (1990)
10.1627/JPI.51.205
Propene Production from Ethene and Methane Using Silver-and Proton-exchanged Zeolite Catalysts
K. Inazu (2008)
10.1080/01614949208020306
Transformation of Lower Alkanes into Aromatic Hydrocarbons over ZSM-5 Zeolites
Y. Ono (1992)
10.1016/S0022-328X(00)80107-2
Kinetics and mechanism of the decomposition of cobalt tetracarbonyl hydride to dicobalt octacarbonyl and hydrogen
F. Ungváry (1969)
10.1063/1.4825256
The Thermodynamic Properties of the f-Elements and their Compounds. Part 2. The Lanthanide and Actinide Oxides
R. J. Konings (2014)
10.1021/JP002102H
Structure and Properties of Cobalt-Exchanged H-ZSM5 Catalysts for Dehydrogenation and Dehydrocyclization of Alkanes
W. Li (2001)
10.1039/FT9949000653
IR studies of cerium dioxide: influence of impurities and defects
F. Bozon-Verduraz (1994)
H2-Co Interaction at Room-Temperature
C C. (1978)
10.1246/CL.1976.37
Selective hydrogenation of 1,3-butadiene over alkaline earth metal oxides.
Y. Tanaka (1976)
10.1021/ACSCATAL.5B01671
Mesoporous Silica-Supported Amidozirconium-Catalyzed Carbonyl Hydroboration
N. Eedugurala (2015)
10.1063/1.108812
Room temperature reactions involving silicon dangling bond centers and molecular hydrogen in amorphous SiO2 thin films on silicon
J. Conley (1993)
10.1021/J100672A006
Low-temperature hydrogenation of ethylene on zinc oxide by temperature-programmed desorption
R. Cvetanovic (1971)
10.1021/ja00269a022
Kinetic and thermodynamic acidity of hydrido transition-metal complexes. 3. Thermodynamic acidity of common mononuclear carbonyl hydrides.
E. Moore (1986)
10.1016/S0021-9673(03)00275-9
Synthesis and evaluation of a C8 stationary phase on a silica hydride surface by hydrosilation of 1-octyne.
J. Pesek (2003)
10.1016/0021-9673(93)80444-D
New Alumina-Based Stationary Phases for High-Performance Liquid Chromatography. Synthesis by Olefin Hydrosilation on a Silicon Hydride Modified Alumina Intermediate
J. Pesek (1993)
10.1002/CHIN.197832343
CATALYTIC ALUMINAS- SURFACE MODELS AND CHARACTERIZATION OF SURFACES SITES
H. Knözinger (1978)
10.1016/J.MOLCATA.2014.01.025
Insights into the deactivation mechanism of supported tungsten hydride on alumina (W-H/Al2O3) catalyst for the direct conversion of ethylene to propylene
E. Mazoyer (2014)
10.1021/OM900151A
Surface Organometallic Chemistry of Titanium on Silica−Alumina and Catalytic Hydrogenolysis of Waxes at Low Temperature
Cherif Larabi (2009)
10.1021/JP200408V
Hydrogen Adsorption and Diffusion on the Anatase TiO2(101) Surface: A First-Principles Investigation
M. Islam (2011)
10.1021/OM980295D
NITROUS OXIDE MEDIATED SYNTHESIS OF MONOMERIC HYDROXORUTHENIUM COMPLEXES. REACTIVITY OF (DMPE)2RU(H)(OH) AND THE SYNTHESIS OF A SILICA-BOUND RUTHENIUM COMPLEX
Anne W. Kaplan and (1998)
10.1016/0304-5102(92)80205-U
Surface organometallic chemistry on oxides: Reaction of hydrogen with bis(allyl)rhodium grafted to silica, titania and alumina
Pascal Dufour (1992)
10.1002/anie.201200903
Electronic modulation of a copper/zinc oxide catalyst by a heterojunction for selective hydrogenation of carbon dioxide to methanol.
Fenglin Liao (2012)
10.1016/J.MOLCATA.2009.05.013
Catalysis of hydrosilylation by well-defined rhodium siloxide complexes immobilized on silica
B. Marciniec (2009)
10.1002/anie.201411581
Formation of a ZnO overlayer in industrial Cu/ZnO/Al2 O3 catalysts induced by strong metal-support interactions.
T. Lunkenbein (2015)
10.1021/ja211380p
Hydrogen activation and metal hydride formation trigger cluster formation from supported iridium complexes.
J. Lu (2012)
10.1021/JP055793W
Unusual infrared spectrum of ethane adsorbed by gallium oxide.
V. Kazansky (2006)
10.1007/S00214-005-0648-X
Spectroscopic identification of adsorption properties of Zn2+ ions at cationic positions of high-silica zeolites with distant placing of aluminium ions
G. M. Zhidomirov (2005)
10.1016/0304-5102(90)85157-D
FTIR study of hydrogen adsorption on α-Ga2O3
P. Mériaudeau (1990)
10.1021/J100714A018
INTERMEDIATES IN ETHYLENE HYDROGENATION OVER ZINC OXIDE.
A. Dent (1970)
10.1039/FT9918701601
Reduction of CeO2 by hydrogen. Magnetic susceptibility and Fourier-transform infrared, ultraviolet and X-ray photoelectron spectroscopy measurements
A. Laachir (1991)
10.1039/C2RA21590J
Surfactant-assisted synthesis of CeO2 nanoparticles and their application in wastewater treatment
He Li (2012)
10.1021/cr5002436
Catalytic dehydrogenation of light alkanes on metals and metal oxides.
J. Sattler (2014)
10.1002/1521-3951(200201)229:2<859::AID-PSSB859>3.0.CO;2-K
Optical Properties of as‐Grown and Proton Irradiated ZnO
D. Brink (2002)
Ga2O3 Surface: A Combined Experimental and Computational Study
Zhang (2011)
10.1039/F19878301323
Tin dioxide gas sensors. Part 1.—Aspects of the surface chemistry revealed by electrical conductance variations
J. Mcaleer (1987)
10.1023/A:1012747314247
Theoretical Study of the Molecular Hydrogen Adsorption and Dissociation on Different Zn(II) Active Sites of Zeolites
L. A. Barbosa (2001)
10.1201/9781420028126.ch18
Hydrogenation of Carbon Oxides on Metal Oxides
J. Fierro (2005)
10.1021/JP0373043
Generation and Characterization of Well-Defined Zn2+ Lewis Acid Sites in Ion Exchanged Zeolite BEA
Jochen Penzien (2004)
10.1063/1.3313945
Optical band-gap determination of nanostructured WO3 film
P. P. González-Borrero (2010)
10.1002/anie.201007254
"Hydro-metathesis" of olefins: a catalytic reaction using a bifunctional single-site tantalum hydride catalyst supported on fibrous silica (KCC-1) Nanospheres.
V. Polshettiwar (2011)
Reduced and n-Type Doped
C. Di Valentin (2006)
10.1016/J.JCAT.2013.01.016
Study of ethylene/2-butene cross-metathesis over W-H/Al2O3 for propylene production: Effect of the temperature and reactant ratios on the productivity and deactivation
E. Mazoyer (2013)
10.1021/JA972488I
Catalytic Hydrogenolysis and Isomerization of Light Alkanes over the Silica-Supported Titanium Hydride Complex (⋮SiO)3TiH
C. Rosier (1997)
10.1016/0021-9517(78)90044-1
Reactive silica: XIII. Activation of silica by pyrolizing chemisorbed HSiCl3☆
M. Low (1978)
10.1007/BF02076535
ESR studies of ethylene interaction with active sites of supported organometallic catalysts for ethylene polymerization
V. A. Poluboyarov (1984)
10.1021/ja00522a086
Inelastic electron tunneling spectroscopy of zirconium tetraborohydride supported on aluminum oxide
H. E. Evans (1980)
10.1007/S10562-010-0496-8
(100) facets of γ-Al2O3: The Active Surfaces for Alcohol Dehydration Reactions
J. H. Kwak (2011)
10.1021/ja800863x
Non-oxidative coupling reaction of methane to ethane and hydrogen catalyzed by the silica-supported tantalum hydride: ([triple bond]SiO)2Ta-H.
D. Soulivong (2008)
hydride: another step towards the utopian single site dream
E. Mazoyer (2015)
10.1016/S0039-6028(98)00795-X
Colour centres at the surface of alkali-earth oxides. A new hypothesis on the location of surface electron traps
M. Paganini (1999)
10.1016/S0039-6028(02)02464-0
Reactivity of a reduced metal oxide surface: hydrogen, water and carbon monoxide adsorption on oxygen defective rutile TiO2(110)
M. Ménétrey (2003)
10.1021/JA01100A517
The Partial Hydrolysis of Chlorosilanes
R. West (1953)
10.1021/JA01053A063
Evidence for intermediates during hydrogenation over zinc oxide
A. Dent (1969)
10.1246/CL.2003.792
Probing the Locations of Ag+ and Hydroxy Groups in AgA Zeolites by in situ FTIR Spectroscopy
P. Wang (2003)
10.1016/0250-6874(89)87067-2
Infrared study of surface chemistry and electronic effects of different atmospheres on SnO2
G. Ghiotti (1989)
10.1080/10826079608015114
Hydride-based Surface Materials for HPLC, HPCE and Electrochromatography
J. Pesek (1996)
10.1016/0304-5102(93)E0163-B
Stoichiometric and catalytic reactivity of organometallic fragments supported on inorganic oxides
S. Scott (1994)
10.1116/1.1396639
Rapid thermal chemical vapor deposition of zirconium oxide for metal-oxide-semiconductor field effect transistor application
J. Chang (2001)
10.1016/J.JCAT.2008.03.021
Dehydrogenation of propane over spinel-type gallia–alumina solid solution catalysts
M. Chen (2008)
10.1002/anie.201007108
Morphology-dependent interactions of ZnO with Cu nanoparticles at the materials' interface in selective hydrogenation of CO2 to CH3OH.
Fenglin Liao (2011)
10.1039/b918648d
H/D exchange of molecular hydrogen with Brønsted acid sites of Zn- and Ga-modified zeolite BEA.
A. Gabrienko (2010)
Dehydrogenation of Propane over Pd-Composite Membrane
노현석 (1999)
10.1016/0021-9517(77)90250-0
An infrared study of hydroboration of lower olefins with diborane on γ-Al2O3
Tsuneo Matsuda (1977)
10.1039/C1CY00256B
Low temperature hydrogenolysis of waxes to diesel range gasoline and light alkanes: Comparison of catalytic properties of group 4, 5 and 6 metal hydrides supported on silica–alumina
S. Norsic (2012)
10.1002/ANIE.200390072
Homogeneous and heterogeneous catalysis: bridging the gap through surface organometallic chemistry.
C. Copéret (2003)
10.1016/J.MICROMESO.2004.02.004
A new charge alternating model of localization of bivalent cations in high silica zeolites with distantly placed aluminum atoms in the framework
V. Kazansky (2004)
Hydrogen Adsorption On the Monoclinic WO3
G. Busca (2012)
10.1016/0039-6028(93)90776-G
Surface chemistry and electronic effects of H2 (D2) on two different microcrystalline ZnO powders
G. Ghiotti (1993)
Revealed by Electrical Conductance Variations
C. Binet (1987)
10.1016/0304-5102(81)87027-7
Catalytically active metal oxide-supported rhodium hydride complexes
M. Ward (1981)
10.1021/JP502309R
Homolytic Products from Heterolytic Paths in H2 Dissociation on Metal Oxides: The Example of CeO2
M. García-Melchor (2014)
10.1021/JP004037H
Comparative quantum chemical study of stabilization energies of Zn 2+ ions in different zeolite structures
A. A. Shubin (2001)
10.1039/FT9969204491
Isotope-exchange reaction between hydrogen molecules and surface hydroxy groups on bare and modified ZrO2
F. Ouyang (1996)
10.1002/ANIE.200503068
On the role of oxygen defects in the catalytic performance of zinc oxide.
S. Polarz (2006)
10.1021/OM070214Q
Reactivity of Silica-Supported Hafnium Tris-neopentyl with Dihydrogen: Formation and Characterization of Silica Surface Hafnium Hydrides and Alkyl Hydride
G. Tosin (2007)
10.1002/macp.200800084
Novel Zirconocene Hydride Complexes in Homogeneous and in SiO2‐Supported Olefin‐Polymerization Catalysts Modified with Diisobutylaluminum Hydride or Triisobutylaluminum
D. E. Babushkin (2008)
10.1021/CR00035A003
Supported Metal Clusters: Synthesis, Structure, and Catalysis
B. Gates (1995)
10.1002/ANIE.198110431
Heterogeneous Hydrogenation of Organic Halogen Compounds by Carrier‐Supported Organotin Hydrides
H. Schumann (1981)
10.1016/1381-1169(96)00114-8
Extraction methods and surface reactions as a convenient methodology for the characterization of surface organometallic species
D. Roberto (1996)
10.1007/B71138
Non-tetrahedrally bonded elements and binary compounds I
O. Madelung (1998)
10.1039/FT9908603751
Estimation of the distribution of surface hydroxyl groups on silica gel, using chemical modification with trichlorosilane
P. Voort (1990)
10.1021/J100324A045
Hydrogen adsorption on ultraviolet-irradiated magnesium oxide
Tomoyasu Ito (1988)
10.1021/J100072A015
DISSOCIATIVE ADSORPTION OF HYDROGEN MOLECULE IN MGO SURFACES STUDIED BY THE DENSITY FUNCTIONAL METHOD
H. Kobayashi (1994)
10.1021/JA00722A009
Oligomeric silsesquioxanes, (HSiO3/2)n
C. L. Frye (1970)
10.1021/JP407021V
Hydroxyl Identification on ZnO by Infrared Spectroscopies: Theory and Experiments
F. Viñes (2014)
10.1006/JCAT.1999.2734
Structural Requirements and Reaction Pathways in Condensation Reactions of Alcohols on MgyAlOx Catalysts
J. I. D. Cosimo (2000)
10.1021/ar500170k
Molecular metal catalysts on supports: organometallic chemistry meets surface science.
Pedro Serna (2014)
10.1021/ja00431a056
A novel catalytic property of magnesium oxide for hydrogenation of 1,3-butadiene
H. Hattori (1976)
Thermoreflectance of MgO and CaO
M. Kurth (1973)
10.1002/ANIE.200704362
Synthesis, characterization, and catalytic activity of a well-defined rhodium siloxide complex immobilized on silica.
B. Marciniec (2008)
thermodynamics of CO and H2 adsorbed on gamma-, delta- and alpha-Al2O3
S. E. Collins (2005)
10.1021/cr300323w
Surface chemistry of late transition metal oxides.
J. Weaver (2013)
10.1002/anie.201301419
The role of the oxide component in the development of copper composite catalysts for methanol synthesis.
S. Zander (2013)
10.1007/BF02274578
The modiffication of alumina, zirconia, thoria and titania for potential use as HPLC stationary phases through a silanization/hydrosilation reaction scheme
J. J. Pesek (1994)
10.1021/JP990866V
Structure and Density of Mo and Acid Sites in Mo-Exchanged H-ZSM5 Catalysts for Nonoxidative Methane Conversion
R. W. Borry (1999)
10.1021/JP907888Q
Transient Spectroscopic Characterization of the Genesis of a Ruthenium Complex Catalyst Supported on Zeolite Y
Isao Ogino (2009)
10.1116/1.577986
Interaction of water, oxygen, and hydrogen with TiO2(110) surfaces having different defect densities
Jian-Mei Pan (1992)
10.1006/JCAT.2002.3734
Gallium–Hydrogen Bond Formation on Gallium and Gallium–Palladium Silica-Supported Catalysts
S. Collins (2002)
Crystallographic Structure of Gamma-Alumina Thin-Films
R.J.M. Konings (1994)
10.1021/JP209898Q
Revealing the Surface Reactivity of Zirconia by Periodic DFT Calculations
O. A. Syzgantseva (2012)
10.1016/0304-5102(80)80085-X
Silica-supported zirconium hydrides as isomerization or hydrogenation catalysts for long-chain olefins
J. Schwartz (1980)
10.1021/JA01026A061
Catalysis of addition of deuterium to ethylene over zinc oxide
W. C. Conner (1968)
10.1021/IC00297A019
Synthesis, characterization, and electrochemical properties of a family of dinuclear rhodium complexes containing two terminal hydride ligands and two hydride (or chloride) bridges. Stoichiometric and catalytic hydrogenation reactions of alkynes and alkenes
C. Bianchini (1988)
10.1016/J.JCAT.2008.02.027
Non-localized charge compensation in zeolites : A periodic DFT study of cationic gallium-oxide clusters in mordenite
E. Pidko (2008)
10.1007/BF02063835
Synthesis and studies of catalysts prepared by supporting Hf(CH2Ph)4 on SiO2 and Al2O3
S. A. Vasnetsov (1988)
Synthesis, Characterization, and Properties of Silica-Supported Trimethylphosphine Disiloxy Tantalum Hydride, (
J. Cazat (2001)
10.1016/J.JCAT.2015.01.021
The Cu–ZnO synergy in methanol synthesis from CO2, Part 1: Origin of active site explained by experimental studies and a sphere contact quantification model on Cu + ZnO mechanical mixtures
A. Valant (2015)
10.1016/0304-5102(78)85012-3
The ESR study of the state of Ti(III) ions in supported organotitanium catalysts for ethylene polymerization
N. G. Maksimov (1978)
10.1016/S0920-5861(96)00015-6
Effect of reductive and oxidative atmospheres on the propane aromatisation activity and selectivity of Ga/H-ZSM-5 catalysts
S. B. A. Hamid (1996)
10.1021/CS400508V
Metallacyclobutane Substitution and Its Effect on Alkene Metathesis for Propylene Production over W–H/Al2O3: Case of Isobutene/2-Butene Cross-Metathesis
K. Szeto (2013)
10.1002/JSSC.200500201
Hydride-based silica stationary phases for HPLC: fundamental properties and applications.
J. Pesek (2005)
10.1039/c0cc00007h
Non-oxidative coupling of methane catalysed by supported tungsten hydride onto alumina and silica-alumina in classical and H2 permeable membrane fixed-bed reactors.
K. C. Szeto (2010)
10.1002/QUA.20668
Activation of alkanes on zeolites: A DFT study of hydride abstraction and dehydrogenation on extra-framework aluminum species
C. Mota (2005)
GeO2) band structure, energy gaps. In Non-Tetrahedrally Bonded Elements and Binary Compounds
O. Madelung (1998)
10.1023/A:1015076629218
DFT study of the mechanism of alkane hydrogenolysis by transition metal hydrides. 1. Interaction of silica-supported zirconium hydrides with methane
L. Ustynyuk (2001)
10.1073/pnas.1220240110
Surface structural-chemical characterization of a single-site d0 heterogeneous arene hydrogenation catalyst having 100% active sites
L. A. Williams (2012)
10.1021/J100784A003
Kinetics of Ethylene Hydrogenation over Alumina
J. H. Sinfelt (1964)
10.1021/JA00754A082
Chemisorption of molecular hydrogen on zinc oxide
C. C. Chang (1971)
10.1016/S0920-5861(98)00488-X
Surface reactivity of MgO oxygen vacancies
G. Pacchioni (1999)
10.1002/anie.201600943
Indium Oxide as a Superior Catalyst for Methanol Synthesis by CO2 Hydrogenation.
O. Martin (2016)
10.1016/S1387-1609(00)01179-8
New reactions of C-C bond cleavage and formation catalysed by silica-supported tantalum and tungsten hydrides
O. Maury (2000)
10.1016/0021-9517(80)90353-X
Studies of the hydrogen held by solids *1XXV. The proton resonance from H2 adsorbed on alumina and molybdena-alumina catalysts
A. Cirillo (1980)
10.1007/B71137
II-VI and I-VII compounds, semimagnetic compounds
O. Madelung (1999)
10.1021/JA004008K
Interactions of Hydrogen with CeO2
K. Sohlberg (2001)
10.1021/CS200660V
Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions
V. Lyaskovskyy (2012)
10.1021/JP993108D
Surface Characterization and Functionalization of MCM-41 Silicas via Silazane Silylation
R. Anwander (2000)
10.1002/chem.201302484
A well-defined Pd hybrid material for the Z-selective semihydrogenation of alkynes characterized at the molecular level by DNP SENS.
Matthew P Conley (2013)
10.1002/CHIN.199201245
Chemistry of (Silica)zirconium Dihydride.
S. King (1992)
10.1021/OM050609E
Tantalum hydrides supported on MCM-41 mesoporous silica : Activation of methane and thermal evolution of the tantalum-methyl species
S. Soignier (2006)
10.1021/cr200346z
Hydrogen spillover. Facts and fiction.
R. Prins (2012)
10.1016/J.JCAT.2015.04.035
The Cu–ZnO synergy in methanol synthesis from CO2, Part 2: Origin of the methanol and CO selectivities explained by experimental studies and a sphere contact quantification model in randomly packed binary mixtures on Cu–ZnO coprecipitate catalysts
Céline Tisseraud (2015)
10.1021/J100722A008
Reactive silica. I. Formation of a reactive silica by the thermal collapse of the methoxy groups of methylated Aerosil
C. Morterra (1969)
10.1039/c3cc44939d
Parahydrogen-induced polarization (PHIP) in heterogeneous hydrogenation over bulk metals and metal oxides.
K. V. Kovtunov (2014)
10.1021/OM900258Q
Surface Organometallic Chemistry of Hf(CH2tBu)4 on Silica and Silica−Alumina: Reaction of the Resulting Grafted Hafnium Neopentyl with Dihydrogen
G. Tosin (2010)
10.1016/S0360-0564(08)60655-0
Oxidative Dehydrogenation of Light (C2 to C4) Alkanes
H. Kung (1994)
10.1002/(SICI)1521-3773(19980403)37:6<806::AID-ANIE806>3.0.CO;2-6
Catalytic Hydrogenolysis at Low Temperature and Pressure of Polyethylene and Polypropylene to Diesels or Lower Alkanes by a Zirconium Hydride Supported on Silica-Alumina: A Step Toward Polyolefin Degradation by the Microscopic Reverse of Ziegler-Natta Polymerization.
Véronique Dufaud (1998)
10.1021/JP9061797
Reduced and n-Type Doped TiO2: Nature of Ti3+ Species
C. D. Valentin (2009)
10.1063/1.3662860
First-principles study of Ge dangling bonds in GeO2 and correlation with electron spin resonance at Ge/GeO2 interfaces
M. Houssa (2011)
10.1021/LA970352S
Surface Color Centers on Calcium Oxide: An Electron Paramagnetic Resonance Investigation
M. Chiesa (1997)
10.1021/JP004627F
An ab Initio Study of Hydrogen Adsorption on ZnO(101̄0)
A. W. and (2001)
10.1016/0039-6028(91)90589-K
Step structure evolution on electrostatic neutral zinc oxide vicinal surfaces — studied by spot profile analysis — LEED
C. Kroll (1991)
10.1016/0021-9517(62)90022-2
The infrared spectrum of hydrogen chemisorbed on zinc oxide
R. P. Eischens (1962)
10.1103/PHYSREVB.79.205211
Band gap, electronic structure, and surface electron accumulation of cubic and rhombohedral In2O3
P. D. C. King (2009)
10.1039/C39820001256
The formation of adsorbed formaldehyde by the reaction of adsorbed carbon monoxide with hydrogen on magnesium oxide
G. Wang (1982)
10.1016/S0920-5861(96)00028-4
Structure and function of metal cations in light alkane reactions catalyzed by modified H-ZSM5
Joseph A. Biscardi (1996)
10.1002/chin.198028015
A VIBRATIONAL STUDY OF ZIRCONIUM TETRABOROHYDRIDE SUPPORTED ON ALUMINUM OXIDE. 1. INTERACTIONS WITH DEUTERIUM, DEUTERIUM OXIDE, AND WATER VAPOR
H. Evans (1980)
Molecular-Hydrogen Adsorbed Ionically
G. L. Griffin (1982)
10.1039/c2cp23269c
Ethylene polymerization on a SiH4-modified Phillips catalyst: detection of in situ produced α-olefins by operando FT-IR spectroscopy.
Caterina Barzan (2012)
10.1021/CS2002719
Highly Dispersed Pd-SBA15 Materials from Tris(tert-butoxy)siloxy Complexes of Pd(II)
Y. S. Choi (2011)
10.1002/ANIE.200701199
Direct transformation of ethylene into propylene catalyzed by a tungsten hydride supported on alumina: trifunctional single-site catalysis.
M. Taoufik (2007)
10.1021/JP8059486
A Density Functional Study of the Methanol Synthesis at an Oxygen Vacancy on the Polar ZnO(0001̅) Surface
Guido Rossmüller (2009)
10.1039/B404749D
Methane activation by silica-supported Zr(IV) hydrides: the dihydride [(triple bond)SiO)2ZrH2] is much faster than the monohydride [(triple bond)SiO)3ZrH].
C. Thieuleux (2004)
10.1021/JP1078899
The “Alkyl” and “Carbenium” Pathways of Methane Activation on Ga-Modified Zeolite BEA: 13C Solid-State NMR and GC-MS Study of Methane Aromatization in the Presence of Higher Alkane
M. V. Luzgin (2010)
10.1039/b923546a
Polymerization of racemic beta-butyrolactone using supported catalysts: a simple access to isotactic polymers.
Noureddine Ajellal (2010)
10.1002/chem.201405788
Well-defined single-site monohydride silica-supported zirconium from azazirconacyclopropane.
Bilel Hamzaoui (2015)
10.1006/JCAT.1998.2177
Structure and Density of Active Zn Species in Zn/H-ZSM5 Propane Aromatization Catalysts☆
Joseph A. Biscardi (1998)
10.1080/03602457908065101
Supported Organometallic Catalysts for Olefin Polymerization
V. A. Zakharov (1979)
10.1039/C3CY00545C
Dynamic behaviour of tantalum hydride supported on silica or MCM-41 in the metathesis of alkanes
S. Soignier (2014)
10.1021/OM4012196
Facile and Efficient Synthesis of the Surface Tantalum Hydride (≡SiO)2TaIIIH and Tris-Siloxy Tantalum (≡SiO)3TaIII Starting from Novel Tantalum Surface Species (≡SiO)TaMe4 and (≡SiO)2TaMe3
Y. Chen (2014)
La2O3, ThO2, and ZrO2
T. Shishido (1978)
10.1021/JP030394R
Study of the Activation of C-H and H-H Chemical Bonds by the [ZnOZn]2+ Oxycation: Influence of the Zeolite Framework Geometry
Lamm Luis Antonio Barbosa (2003)
10.1016/0166-1280(94)03997-Y
Theoretical study of cluster models and molecular hydrogen interaction with SnO2 [110] surface
J. Martins (1995)
10.1021/CM0111534
SOMC@PMS. Surface Organometallic Chemistry at Periodic Mesoporous Silica†
R. Anwander (2001)
10.1021/JP910835K
Adsorbed Species of CO2 and H2 on Ga2O3 for the Photocatalytic Reduction of CO2
H. Tsuneoka (2010)
10.1023/A:1024026225712
The Sites of Molecular and Dissociative Hydrogen Adsorption in High-Silica Zeolites Modified with Zinc Ions. III DRIFT Study of H2 Adsorption by the Zeolites with Different Zinc Content and Si/Al Ratios in the Framework
V. B. Kazansky (2003)
10.1021/JP4036698
Dissociative Adsorption of Hydrogen on PdO(101) Studied by HRCLS and DFT
N. Martín (2013)
10.1039/C39950000991
Activation and functionalisation of the C–H bonds of methane and higher alkanes by a silica-supported tantalum hydride complex
Véronique Vidal (1995)
10.1016/0021-9517(85)90238-6
Infrared study of ZnO surface properties: CO adsorption and CO/D2 interaction at 77 K
G. Ghiotti (1985)
10.1021/JP3004773
DFT Study of CO2 Adsorption and Hydrogenation on the In2O3 Surface
Jing-yun Ye (2012)
10.1016/J.APCATA.2012.05.036
On catalyst activation and reaction mechanisms in propane aromatization on Ga/HZSM5 catalysts
V. Rodrigues (2012)
10.1016/0254-0584(88)90021-1
Catalysis by basic metal oxides
H. Hattori (1988)
10.1016/0021-9517(78)90289-0
Infrared study of ZnO surface. II. H2-CO interaaction at room temperature.
F. Boccuzzi (1978)
10.1021/OM5000858
C–H and C–C Activation of n-Butane with Zirconium Hydrides Supported on SBA15 Containing N-Donor Ligands: [(≡SiNH−)(≡SiX−)ZrH2], [(≡SiNH−)(≡SiX−)2ZrH], and[(≡SiN═)(≡SiX−)ZrH] (X = −NH–, −O−). A DFT Study
F. Pasha (2014)
10.1039/A906550D
Non-oxidative reactions of propane on Zn/Na-ZSM5
Joseph A. Biscardi (1999)
10.1021/JA051679F
Primary products and mechanistic considerations in alkane metathesis.
J. Basset (2005)
10.1002/ANIE.200462374
Active sites on oxide surfaces: ZnO-catalyzed synthesis of methanol from CO and H2.
M. Kurtz (2005)
10.1007/978-90-481-2309-4_11
Nanoporous Silica Matrices and Their Application in Synthesis of Nanostructures
V. Tertykh (2009)
10.1126/SCIENCE.276.5309.99
Metathesis of Alkanes Catalyzed by Silica-Supported Transition Metal Hydrides
Véronique Vidal (1997)
10.1016/0040-6090(94)90171-6
Electronic and crystallographic structure of γ-alumina thin films
B. Ealet (1994)
10.1021/JA953524L
Synthesis, Characterization, and Reactivity, in the C−H Bond Activation of Cycloalkanes, of a Silica-Supported Tantalum(III) Monohydride Complex: (⋮SiO)2TaIII−H
Véronique Vidal (1996)
10.1016/S0040-6090(01)01472-9
FTIR spectroscopy of hydrogen, carbon monoxide, and methane adsorbed and co-adsorbed on zinc oxide
D. Scarano (2001)
10.1016/S0920-5861(99)00047-4
Alkane dehydrogenation over supported chromium oxide catalysts
B. Weckhuysen (1999)
10.1021/CS200441E
Structure and Reactivity of Zn-Modified ZSM-5 Zeolites: The Importance of Clustered Cationic Zn Complexes
Smt Sami Almutairi (2012)
10.1016/J.SNB.2015.05.061
Sensing mechanism of SnO2(110) surface to H2: Density functional theory calculations
Yanping Chen (2015)
Studies of hydrogen held by solids--25. Proton resonance from Hâ adsorbed on alumina and molybdena/alumina catalysts
A. Cirillo (1980)
10.1016/J.CPLETT.2007.01.039
n-Type doping of TiO2 with atomic hydrogen-observation of the production of conduction band electrons by infrared spectroscopy
D. Panayotov (2007)
10.1063/1.4885546
Hydrogen activation, diffusion, and clustering on CeO₂(111): a DFT+U study.
D. Fernández-Torre (2014)
10.1039/C39910001589
Alkane activation by a highly electrophilic zirconium hydride complex supported on silica
F. Quignard (1991)
10.1039/c3dt51005k
Triisobutylaluminum: bulkier and yet more reactive towards silica surfaces than triethyl or trimethylaluminum.
Anthony Kermagoret (2013)
10.1021/JP910642P
Correlations between Dispersion, Acidity, Reducibility, and Propane Aromatization Activity of Gallium Species Supported on HZSM5 Zeolites
V. Rodrigues (2010)
10.1063/1.3126682
Methanol synthesis on ZnO(0001). I. Hydrogen coverage, charge state of oxygen vacancies, and chemical reactivity.
J. Kiss (2009)
10.1016/0304-5102(82)85040-2
Infrared study of the interaction between CO and H2 on ZnO: Mechanism and sites of formation of formyl species
J. Lavalley (1982)
10.1021/ja9531283
OXIDATIVE ELIMINATION OF H2 FROM CP'2U(MU -OH)2 TO FORM CP'2U(MU -O)2, WHERE CP' IS 1,3-(ME3C)2C5HI3 OR 1,3-(ME3SI)2C5H3
W. Lukens (1996)
10.1016/S0167-2991(06)81020-7
Chapter 1.6 Solid-phase hydrosilylation reactions with participation of modified silica surface
V. Tertykh (1996)
10.1021/JA0616736
Molecular understanding of alumina supported single-site catalysts by a combination of experiment and theory.
Jérôme Joubert (2006)
10.1039/F19898503569
Synergy between copper and zinc oxide during methanol synthesis. Transfer of activating species
R. Burch (1989)
10.1039/C2SC20434G
Room temperature activation of methane over Zn modified H-ZSM-5 zeolites: Insight from solid-state NMR and theoretical calculations
Jun Xu (2012)
10.1002/1521-3773(20000602)39:11<1962::AID-ANIE1962>3.0.CO;2-1
Low-Temperature Hydrogenolysis of Alkanes Catalyzed by a Silica-Supported Tantalum Hydride Complex, and Evidence for a Mechanistic Switch from Group IV to Group V Metal Surface Hydride Complexes
M. Chabanas (2000)
10.1016/0926-860X(95)00161-1
The role of sodium and structure on the catalytic behavior of alumina: I. Isopropanol dehydration activity
S. Srinivasan (1995)
10.1002/CHIN.198018008
Inelastic electron tunneling spectroscopy of zirconium tetraborohydride supported on aluminum oxide
H. Evans (1980)
10.1021/CS500057S
Defect Sites in H2-Reduced TiO2 Convert Ethylene to High Density Polyethylene without Activator
Caterina Barzan (2014)
10.1039/F19898503537
1H and 13C nuclear magnetic resonance investigations of the Cu/Zn/Al oxide methanol-synthesis catalyst
P. Dennison (1989)
10.1016/S0039-6028(01)01477-7
Periodic ab initio study of the hydrogenated rutile TiO2(1 1 0) surface
J. Leconte (2002)
Two Different Microcrystalline ZnO Powders
L G. (1993)
10.1063/1.4896053
Methanol synthesis on ZnO(0001¯). IV. Reaction mechanisms and electronic structure.
J. Frenzel (2014)
10.1021/acs.chemrev.5b00373
Surface Organometallic and Coordination Chemistry toward Single-Site Heterogeneous Catalysts: Strategies, Methods, Structures, and Activities.
C. Copéret (2016)
10.1063/1.2793184
Dangling-bond defects and hydrogen passivation in germanium
J. R. Weber (2007)
10.1016/S0166-9834(00)81228-2
Kinetics and mechanism of propan-2-OL decomposition on zinc oxide
K. C. Waugh (1986)
10.1039/FT9959104441
In situ FTIR studies of high-temperature adsorption of hydrogen on zirconia
A. Trunschke (1995)
10.1021/JA038486H
Molecular Understanding of the Formation of Surface Zirconium Hydrides upon Thermal Treatment under Hydrogen of [(=SiO)Zr(CH 2 tBU) 3 ] by Using Advanced Solid-State NMR Techniques
F. Rataboul (2004)
10.1021/JP500546R
Band Gap Engineering of SnO2 by Epitaxial Strain: Experimental and Theoretical Investigations
W. Zhou (2014)
10.1021/JP4006795
Methane Activation and Transformation on Ag/H-ZSM‑5 Zeolite Studied with Solid-State NMR
A. Gabrienko (2013)
10.1007/bf00533792
Magnetic anisotropy of cyclopropane and epoxide rings
R. M. Aminova (1967)
10.1021/JA01054A018
Di-.mu.-hydrido-bis(dicyclopentadienyltitanium(III)), a transition metal complex with a diborane-like double hydrogen bridge
J. Bercaw (1969)
boron hydrides, and other reactions, on the surface of boriaimpregnated aerosil
T. Matsuda (1970)
10.1021/JP302210Y
DFT Study of Hydrogen Adsorption On the Monoclinic WO3 (001) Surface
F. Wang (2012)
10.1016/S0926-860X(00)00752-3
Theoretical study of hydrogen dissociation on dialuminum oxide clusters and aluminum–silicon–oxygen clusters, as models of extraframework aluminum species and zeolite lattice
P. Lukinskas (2001)
10.1021/IC00084A021
Surface Organometallic Chemistry of Tin: Formation of the Grafted Organometallic Complex (.scharw.Si-O)2Sn(n-C4H9)2 by Reaction of H2Sn(n-C4H9)2 with the Surface of a Partially Dehydroxylated Silica
C. Nedez (1994)
10.1021/la901295d
Tantalum clusters supported on silica-alumina: influence of support composition and chemistry on cluster structure.
J. Sun (2009)
10.1002/ANIE.200702463
Water-promoted hydrocarbon activation catalyzed by binuclear gallium sites in ZSM-5 zeolite.
E. Hensen (2007)
10.1016/S1381-1169(98)00077-6
Effects of structural defects and acid–basic properties on the activity and selectivity of isopropanol decomposition on nanocrystallite sol–gel alumina catalyst
J. Wang (1999)
10.1021/CR9411637
Incorporation of gallium into zeolites: syntheses, properties and catalytic application.
Rolf Fricke (2000)
10.1103/PHYSREVLETT.97.166803
Electronic structure of defect states in hydroxylated and reduced rutile TiO2(110) surfaces.
C. Di Valentin (2006)
10.1039/B110334B
Site selective hydroxylation of the MgO surface
O. Diwald (2002)
10.1002/ADSC.200800615
Highly Active and Recyclable Heterogeneous Iridium Pincer Catalysts for Transfer Dehydrogenation of Alkanes
Zheng Huang (2009)
10.1063/1.444241
Coadsorption studies of CO and H2 on ZnO
G. Griffin (1982)
compounds: Mechanistic studies
M.J.D. Low (1995)
cycloalkanes, of a silica-supported tantalum(III) monohydride complex: (SiO)2Ta(III)-H
L. T. Zhuravlev (1996)
10.1016/0039-6028(85)90064-0
Possibility of hydrogen-deuterium exchange at surface irregularities of MgO: An ab initio MO study
H. Fujioka (1985)
10.1002/cctc.200900111
Catalysis of Hydrosilylation by Well‐Defined Surface Rhodium Siloxide Phosphine Complexes
B. Marciniec (2009)
10.1039/DT9940001153
From synthesis to chemical reactivity of supported d0 complexes. Part 1. An in situ infrared spectroscopic study of silica-anchored zirconium hydrides
F. Quignard (1994)
10.1016/J.JCAT.2010.10.018
Dehydrogenation of propane over ZnMOR. Static and dynamic reaction energy diagram
Lubomir Benco (2011)
10.1021/JA00199A034
Solution homolytic bond dissociation energies of organotransition-metal hydrides
M. Tilset (1989)
10.1002/CHIN.201112220
Probing the Surfaces of Heterogeneous Catalysts by in situ IR Spectroscopy
C. Lamberti (2011)
10.1016/J.APCATA.2014.10.060
Solid base catalysts: fundamentals and their applications in organic reactions
H. Hattori (2015)
Adsorption of H/sub 2/ isotopes on ZnO: coverage induced ir frequency shifts and adsorbate geometry. Technical report
G. L. Griffin (1982)
10.1016/0304-5102(91)80004-M
Electrophilic activation of CH bonds of alkanes with supported Rh(H)(allyl) species revisited: reaction of H2 with a bis-allyl rhodium grafted to a silica surface
Pascal Dufour (1991)
10.1016/J.JALLCOM.2010.07.179
Thermodynamic properties of RhO2
K. Jacob (2010)
10.1021/JA00120A010
Surface Organometallic Chemistry of Inorganic Oxides: The Synthesis and Characterization of (.tplbond.SiO)Ta(:CHC(CH3)3)(CH2C(CH3)3)2 and (.tplbond.SiO)2Ta(:CHC(CH3)3)(CH2C(CH3)3)
V. Dufaud (1995)
10.1021/JP807864Z
Periodic Density Functional Theory Study of Propane Dehydrogenation over Perfect Ga2O3(100) Surface
Y. Liu (2008)
10.1021/CR000064S
Organometallic chemistry on silicon and germanium surfaces.
J. Buriak (2002)
10.1515/znb-2007-0712
Chemical Bonding in Metallic Rutile-type Oxides TO2 (T = Ru, Rh, Pd, Pt)
G. Demazeau (2007)
10.1021/JP101715J
Strong Kinetic Isotope Effect in the Dissociative Chemisorption of H2 on a PdO(101) Thin Film
C. Hakanoglu (2010)
10.1021/ar900203a
Metathesis of alkanes and related reactions.
Jean-Marie Basset (2010)
Interactions of hydrogen with CeO(2).
K. Sohlberg (2001)
10.1016/0925-4005(93)85212-S
Surface chemistry and electronic effects of H2 (D2) on pure SnO2 and Cr-doped SnO2
G. Ghiotti (1993)
10.1016/J.JCAT.2006.03.004
Characterization and reactivity of Ga+ and GaO+ cations in zeolite ZSM-5
Nj Neelesh Rane (2006)
10.1016/S0166-9834(00)82709-8
The reaction of propane over ZSM-5-H and ZSM-5-Zn zeolite catalysts
T. Mole (1985)
10.1039/C5CY00837A
Catalytic hydrogenation of liquid alkenes with a silica-grafted hydride pincer iridium(III) complex: support for a heterogeneous mechanism
Martino Rimoldi (2015)
10.1002/CPHC.200600598
A theoretical study of surface reduction mechanisms of CeO(2)(111) and (110) by H(2).
H. Chen (2007)
10.1016/S0022-3093(00)00084-3
Interaction of H2 with strained rings at the silica surface from ab initio calculations
N. López (2000)
10.1021/JP070677+
The Activation of H2 by Zeolitic Zn(II) Cations
Lamm Luis Antonio Barbosa (2007)
10.1063/1.1523897
Assignment of the complex vibrational spectra of the hydrogenated ZnO polar surfaces using QM/MM embedding
S. A. French (2003)
10.1201/9781315138862-9
How to methanol synthesis
椿 範立 (2006)
10.1627/jpi.47.67
Solid Base Catalysts : Generation, Characterization, and Catalytic Behavior of Basic Sites
H. Hattori (2004)
10.1039/C5CY00330J
Review: monoclinic zirconia, its surface sites and their interaction with carbon monoxide
Sonja Kouva (2015)
10.1021/CS401116P
Propylene hydrogenation and propane dehydrogenation by a single-site Zn2+ on silica catalyst
Neil M. Schweitzer (2014)
10.1039/FT9969204669
An FTIR study of surface ceria hydroxy groups during a redox process with H2
Ahmed Badri (1996)
10.1016/0021-9517(89)90271-6
Fourier transform-infrared spectroscopic study of the adsorption of hydrogen on chromia and on some metal chromites
G. Busca (1989)
10.1021/JP065911V
Activation of light alkanes over zinc species stabilized in ZSM-5 zeolite : A comprehensive DFT study
E. Pidko (2007)
10.1021/ar500375j
Frustrated Lewis pairs: from concept to catalysis.
D. Stephan (2015)
10.1021/ja00528a007
A vibrational study of zirconium tetraborohydride supported on aluminum oxide. 2. Interactions with ethylene, propylene, and acetylene
H. E. Evans (1980)
10.1016/0039-6028(80)90067-9
Characterization of hydrogen species on TiO2 by electron-stimulated desorption☆
M. Knotek (1980)
10.1016/0926-860X(92)80336-B
Effects of pretreatments on state of gallium and aromatization activity of gallium/ZSM-5 catalysts
K. M. Dooley (1992)
10.1016/S0021-9614(05)80132-6
THE STANDARD ENTHALPY OF FORMATION OF IN2O3
E. Cordfunke (1991)
10.1021/JA028059O
Energy transfer on the MgO surface, monitored by UV-induced H2 chemisorption.
M. Sterrer (2003)
10.1021/ja407902g
Bipodal surface organometallic complexes with surface N-donor ligands and application to the catalytic cleavage of C-H and C-C bonds in n-butane.
A. Bendjeriou-Sedjerari (2013)
10.1515/ZNB-1959-1111
Notizen: Some New Transition Metal π-Cyclopentadienyl Hydrides
M. L. H. Green (1959)
10.1016/S0166-9834(00)80384-X
Factors affecting the selectivity of the aromatization of light alkanes on modified ZSM-5 catalysts
M. Scurrell (1988)
10.1021/JP970050Z
Mobility of Surface Species on Oxides. 2. Isotopic Exchange of D2 with H of SiO2, Al2O3, ZrO2, MgO, and CeO2: Activation by Rhodium and Effect of Chlorine
Dominique Martin and (1997)
10.1006/JCAT.2002.3741
Hydroxyl Groups on γ-Alumina Surfaces: A DFT Study
M. Digne (2002)
10.1016/J.CATTOD.2006.05.062
Plate-like zinc oxide microcrystals: Synthesis and characterization of a material active toward hydrogen adsorption
D. Scarano (2006)
10.1021/J100845A036
Hydrogenation of ethylene by zinc oxide. II. Mechanism and active sites
A. Dent (1969)
10.1039/c002031c
FTIR spectroscopy and thermodynamics of CO and H(2) adsorbed on gamma-, delta- and alpha-Al(2)O(3).
E. N. Gribov (2010)
10.1002/chem.200800174
Mononuclear ruthenium hydride species versus ruthenium nanoparticles: the effect of silane functionalities on silica surfaces.
Romain Berthoud (2008)
10.1002/anie.201201000
Unprecedented reversible redox process in the ZnMFI-H2 system involving formation of stable atomic Zn(0).
A. Oda (2012)
10.1039/C39930000042
Surface-supported group 5 metal organometallic compounds for catalytic arene hydrogenation
Robert D. Profilet (1993)
10.1002/ANGE.201603172
Titelbild: Indium Oxide as a Superior Catalyst for Methanol Synthesis by CO2 Hydrogenation (Angew. Chem. 21/2016)
O. Martin (2016)
10.1023/B:CATL.0000004107.24576.1C
DFT Cluster Modeling of Molecular and Dissociative Hydrogen Adsorption on Zn2+ Ions with Distant Placing of Aluminum in the Framework of High-Silica Zeolites
A. A. Shubin (2003)
10.1246/CL.1985.507
PREPARATIONS OF TiO2-ATTACHED Rh CATALYSTS AND THEIR CATALYSIS
Y. Iwasawa (1985)
10.1039/F19848001039
Reaction of adsorbed carbon monoxide with hydrogen on magnesium oxide
G. Wang (1984)
10.1006/JCAT.1993.1079
The Chemical State of Gallium in Working Alkane Dehydrocyclodimerization Catalysts. In situ Gallium K-Edge X-Ray Absorption Spectroscopy
G. Meitzner (1993)
10.1002/ANIE.200604158
Homologation of propane catalyzed by oxide-supported zirconium dihydride and dialkyl complexes.
C. Thieuleux (2007)
10.1126/science.1219831
The Active Site of Methanol Synthesis over Cu/ZnO/Al2O3 Industrial Catalysts
M. Behrens (2012)
10.1016/J.JCAT.2013.11.005
Synthesis and characterization of HY zeolite-supported rhodium carbonyl hydride complexes
A. Vityuk (2014)
10.1016/J.JCAT.2008.03.019
Hydrogen on polycrystalline β-Ga2O3: Surface chemisorption, defect formation, and reactivity
W. Jochum (2008)
10.1002/ADSC.200600436
Silica‐Alumina‐Supported, Tungsten‐Based Heterogeneous Alkane Metathesis Catalyst: Is it Closer to a Silica‐ or an Alumina‐Supported System?
E. L. Roux (2007)
10.1021/AC00193A013
Synthesis and characterization of a hydride-modified porous silica material as an intermediate in the preparation of chemically bonded chromatographic stationary phases
J. E. Sandoval (1989)
10.1039/B401853B
Unusual localization of zinc cations in MFI zeolites modified by different ways of preparation
V. Kazansky (2004)
by periodical density functional theory
J. A. Biscardi (2003)
10.1021/JA00768A005
INFRARED STUDIES OF ISOTOPE EFFECTS FOR HYDROGEN ADSORPTION ON ZINC OXIDE.
R. J. Kokes (1972)
10.1021/OM020376G
Synthesis, Characterization, and Reactivity of the Highly Unsaturated Silica-Supported Trisiloxy Tantalum: (⋮SiO)3Ta(III)
G. Saggio (2002)
10.1016/0039-6028(82)90056-5
Interaction of CO, CO2 and O2 with nonpolar, stepped and polar Zn surfaces of ZnO
W. Cheng (1982)
10.1016/S1381-1169(03)00327-3
Silica-supported rhodium hydrides stabilized by triisopropylphosphine
S. Scott (2003)
10.1063/1.467404
An ab initio molecular orbital study on adsorption at the MgO surface. II. Site dependence of hydrogen chemisorption on the (MgO)4,6,8 clusters
K. Sawabe (1994)
10.1021/CS5011508
Unique Reaction Path in Heterogeneous Catalysis: The Concerted Semi-Hydrogenation of Propyne to Propene on CeO2
M. García-Melchor (2014)
10.1021/J100097A008
Theoretical Study on the Molecular and Dissociative Adsorptions of H2 on a ZrO2 Surface
H. Nakatsuji (1994)
10.1016/J.CATTOD.2011.01.017
Reactivity of Hydrogen and Methanol on (001) Surfaces of WO3, ReO3, WO3/ReO3 and ReO3/WO3
S. Ling (2011)
10.1021/JA952718Y
SURFACE ORGANOMETALLIC CHEMISTRY ON METALS. EVIDENCE FOR A SURFACE-STABILIZED GERMYLENE, RH2GE(AD)(H)Y/SIO2 (AD = ADAMANTYL) OBTAINED BY A CONTROLLED REACTION BETWEEN RH/SIO2 AND (AD)GEH3
M. Taoufik (1996)
10.1021/OM0496380
Synthesis, Structure, and Alkyne Reactivity of a Dimeric (Carbene)copper(I) Hydride
N. Mankad (2004)
10.1021/JP993214F
H2Cracking at SiO2Defect Centers
M. Vitiello (2000)
10.1007/S11244-008-9043-X
Gamma-alumina: An Active Support to Obtain Immobilized Electron Poor Zr Complexes
J. Joubert (2008)
10.1021/JA00528A006
A VIBRATIONAL STUDY OF ZIRCONIUM TETRABOROHYDRIDE SUPPORTED ON ALUMINUM OXIDE. 1. INTERACTIONS WITH DEUTERIUM, DEUTERIUM OXIDE, AND WATER VAPOR
H. E. Evans (1980)
10.1002/ANIE.200460982
Cross-metathesis of propane and methane: a catalytic reaction of C-C bond cleavage of a higher alkane by methane.
D. Soulivong (2004)
10.1021/JP022384G
Influence of Zeolite Framework Geometry Structure on the Stability of the [ZnOZn]2+ Cluster by Periodical Density Functional Theory
Lamm Luis Antonio Barbosa (2003)
10.1016/J.CHEMPHYS.2005.08.051
The structure of low-index surfaces of β-Ga2O3
V. Bermúdez (2006)
10.1021/JP0641841
Heterolytic Splitting of H2 and CH4 on γ-Alumina as a Structural Probe for Defect Sites
Jérôme Joubert (2006)
10.1039/F19878301237
Ultraviolet–visible reflectance studies of hydrogen adsorption and CO–H2 interaction at MgO and CaO surfaces
E. Garrone (1987)
10.1021/J100845A035
Hydrogenation of ethylene by zinc oxide. I. Role of slow hydrogen chemisorption
A. Dent (1969)
10.1524/zpch.1983.137.2.173
Spectroscopic Study of the Interaction of H2 with MgO—CoO Solid Solutions
A. Zecchina (1983)
10.1039/C1SC00073J
Molecular nature of support effects in single-site heterogeneous catalysts: silicavs.alumina
Fernando Rascón (2011)
10.1002/anie.201004310
Heteronuclear NMR correlations to probe the local structure of catalytically active surface aluminum hydride species on γ-alumina.
E. Mazoyer (2010)
10.1246/BCSJ.51.3641
Hydrogenation and Dehydrogenation of 4-Isopropenyl-1-methylcyclohexene Catalyzed by MgO, CaO, La2O3, ThO2, and ZrO2
Y. Tanaka (1978)
10.1023/A:1019118823908
A density functional theory study of hydrogen recombination and hydrogen-deuterium exchange on Ga/H-ZSM-5
N. Gonzales (1999)



This paper is referenced by
10.1039/d0cy00779j
Unmodified bulk alumina as an efficient catalyst for propane dehydrogenation
Peng-Zhao Wang (2020)
10.1002/CHIN.201641232
Isolated Surface Hydrides: Formation, Structure, and Reactivity
C. Copéret (2016)
10.1016/S1872-2067(16)62571-8
Identification of active sites for hydrogenation over Ru/SBA-15 using in situ Fourier-transform infrared spectroscopy
H. Shen (2017)
10.1038/s41560-019-0491-2
Fuels and energy carriers from single-site catalysts prepared via surface organometallic chemistry
C. Copéret (2019)
10.1021/ACS.CHEMMATER.7B00188
Reagent-Free Electrophoretic Synthesis of Few-Atom-Thick Metal Oxide Nanosheets
Hou Cheng-yi (2017)
10.1021/ACS.ORGANOMET.7B00544
Supported Single-Site Ti(IV) on a Metal–Organic Framework for the Hydroboration of Carbonyl Compounds
Zhiyuan Huang (2017)
10.1039/c7sc00713b
Molecular heterogeneous catalysts derived from bipyridine-based organosilica nanotubes for C–H bond activation† †Electronic supplementary information (ESI) available: Experimental details, material characterization data, catalytic measurement details. See DOI: 10.1039/c7sc00713b Click here for addit
S. Zhang (2017)
10.1016/j.cattod.2019.10.035
A CHA zeolite supported Ga-oxo cluster for partial oxidation of CH4 at room temperature
Shunsaku Yasumura (2020)
10.1016/J.JCAT.2019.04.035
Bimetallic Pt-Sn nanocluster from the hydrogenolysis of a well-defined surface compound consisting of [(AlO)Pt(COD)Me] and [(AlO)SnPh3] fragments for propane dehydrogenation
Zhikang Xu (2019)
10.1016/J.APCATB.2018.10.006
WOx domain size, acid properties and mechanistic aspects of glycerol hydrogenolysis over Pt/WOx/ZrO2
W. Zhou (2019)
10.1039/c6sc05178b
Silica-supported isolated gallium sites as highly active, selective and stable propane dehydrogenation catalysts† †Electronic supplementary information (ESI) available: Experimental details, material characterization data, catalytic measurement details and crystallographic details. CCDC 1499756. For
Keith Searles (2017)
10.1016/j.apcatb.2020.119169
The mechanism of photodriven oxidation of CO over anatase and rutile TiO2 investigated from the hydrogen adsorption behavior
Z. Wang (2020)
10.1007/s10562-017-2107-4
Surface Organometallic Chemistry: Paving the Way Beyond Well-Defined Supported Organometallics and Single-Site Catalysis
C. Copéret (2017)
10.1039/d0sc03858j
Effects of ruthenium hydride species on primary amine synthesis by direct amination of alcohols over a heterogeneous Ru catalyst
Yusuke Kita (2020)
10.1080/01614940.2020.1787771
The hydrogen spillover effect. A misunderstanding story
M. M. Bettahar (2020)
10.1002/cssc.201801890
Neutron Scattering Investigations of Hydride Species in Heterogeneous Catalysis.
Felipe Polo-Garzon (2019)
10.1016/J.JCAT.2018.04.012
Quality control for Ziegler-Natta catalysis via spectroscopic fingerprinting
Paul D. Pletcher (2018)
10.1002/ANGE.201702387
Eine Brücke zwischen industriellen und wohldefinierten Trägerkatalysatoren
C. Copéret (2018)
10.1021/ACS.CHEMMATER.7B03306
Characterization of Silicon Nanocrystal Surfaces by Multidimensional Solid-State NMR Spectroscopy
Michael P. Hanrahan (2017)
10.1021/acsomega.8b02410
Breaking H2 with CeO2: Effect of Surface Termination
O. Matz (2018)
10.1002/anie.201702387
Bridging the Gap between Industrial and Well-Defined Supported Catalysts.
C. Copéret (2018)
10.1016/S1872-2067(19)63360-7
State-of-the-art catalysts for direct dehydrogenation of propane to propylene
Z. Hu (2019)
10.1021/jacs.7b05492
Direct Neutron Spectroscopy Observation of Cerium Hydride Species on a Cerium Oxide Catalyst.
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10.1021/ACS.JPCC.7B06361
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10.1021/JACS.6B08705
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D. Estes (2016)
10.1002/anie.201907117
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10.3390/nano9091199
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10.1016/j.cattod.2019.12.015
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10.1039/c9cp01873e
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10.1016/J.JCAT.2016.11.029
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10.1002/adma.201902757
Complex Hydrides for Energy Storage, Conversion, and Utilization.
Teng He (2019)
10.1002/cctc.201701993
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