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Self-healable, Tough, And Ultrastretchable Nanocomposite Hydrogels Based On Reversible Polyacrylamide/montmorillonite Adsorption.

Guorong Gao, Gaolai Du, Yuanna Sun, Jun Fu
Published 2015 · Materials Science, Medicine

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Nanocomposite hydrogels with unprecedented stretchability, toughness, and self-healing have been developed by in situ polymerization of acrylamide with the presence of exfoliated montmorillonite (MMT) layers as noncovalent cross-linkers. The exfoliated MMT clay nanoplatelets with high aspect ratios, as confirmed by transmission electron microscopy (TEM) and X-ray diffraction (XRD) results, are well dispersed in the polyacrylamide matrix. Strong polymer/MMT interaction was confirmed by Fourier transform infrared spectroscopy (FTIR) and differential scanning calorimetry (DSC). The effective cross-link densities of these hydrogels are estimated in the range of 2.2-5.7 mol m(-3). Uniaxial tensile tests showed a very high fracture elongation up to 11 800% and a fracture toughness up to 10.1 MJ m(-3). Cyclic loading-unloading tests showed remarkable hysteresis, which indicates energy dissipation upon deformation. Residual strain after cyclic loadings could be recovered under mild conditions, with the recovery extent depending on clay content. A mechanism based on reversible desorption/adsorption of polymer chains on clay platelets surface is discussed. Finally, these nanocomposite hydrogels are demonstrated to fully heal by dry-reswell treatments.
This paper references
10.1021/MA300874N
Self-Reinforcement of PNIPAm–Laponite Nanocomposite Gels Investigated by Atom Force Microscopy Nanoindentation
Cuixia Lian (2012)
10.1002/ADMA.200600143
Polymer–Clay Nanocomposites Exhibiting Abnormal Necking Phenomena Accompanied by Extremely Large Reversible Elongations and Excellent Transparency
K. Haraguchi (2006)
10.1021/MA060568D
Necking Phenomenon of Double-Network Gels
Yang-Ho Na (2006)
10.1002/0471757128
Introduction to Physical Polymer Science: Sperling/Introduction to Physical Polymer Science, Fourth Edition
L. Sperling (2005)
10.1126/SCIENCE.1143176
Ultrastrong and Stiff Layered Polymer Nanocomposites
P. Podsiadlo (2007)
10.1016/J.EURPOLYMJ.2010.04.008
Porous nanocomposite hydrogel of vinyled montmorillonite-crosslinked maltodextrin-co-dimethylacrylamide as a highly stable polymer carrier for controlled release systems
M. Guilherme (2010)
10.1021/MA062929V
Polyacrylamide-clay nanocomposite hydrogels : Rheological and light scattering characterization
O. Okay (2007)
10.1021/BM050924K
Interaction and properties of highly exfoliated soy protein/montmorillonite nanocomposites.
P. Chen (2006)
10.1021/MA051979H
Small-angle neutron scattering study on uniaxially stretched poly(N-isopropylacrylamide)-clay nanocomposite Gels
M. Shibayama (2005)
10.1021/MZ300451R
Poly(vinyl alcohol) Hydrogel Can Autonomously Self-Heal
Hongji Zhang (2012)
10.1039/C2SM27233D
Synthetic and viscoelastic behaviors of silica nanoparticle reinforced poly(acrylamide) core–shell nanocomposite hydrogels
J. Yang (2013)
10.1002/anie.201004748
Artificial nacre-like bionanocomposite films from the self-assembly of chitosan-montmorillonite hybrid building blocks.
H. Yao (2010)
10.1126/science.1247811
“Nonswellable” Hydrogel Without Mechanical Hysteresis
Hiroyuki Kamata (2014)
Mechanical Properties and Structure of Polymer-Clay Nanocomposite Gels with High Clay Content. Macromolecules
K Haraguchi
10.1021/ja311463b
Direct measurement of electron transfer through a hydrogen bond between single molecules.
T. Nishino (2013)
10.1038/nature12806
Nanoparticle solutions as adhesives for gels and biological tissues
S. Rose (2014)
10.1039/C2SM27232F
Characterization of internal fracture process of double network hydrogels under uniaxial elongation
T. Nakajima (2013)
10.1021/MA034366I
Compositional effects on mechanical properties of Nanocomposite hydrogels composed of poly(N, N-dimethylacrylamide) and clay
K. Haraguchi (2003)
10.1021/MA052468Y
Mechanical Properties and Structure of Polymer−Clay Nanocomposite Gels with High Clay Content
K. Haraguchi (2006)
10.1016/J.CLAY.2007.07.006
Adsorption and binding of the transgenic plant proteins, human serum albumin, β-glucuronidase, and Cry3Bb1, on montmorillonite and kaolinite: Microbial utilization and enzymatic activity of free and clay-bound proteins
Theresa M. Fiorito (2008)
10.1002/PAT.1995.220061004
Functionalization of montmorillonite by acrylamide polymers containing side-chain ammonium cations
Luca Biasci (1995)
10.1021/am405708v
Thin, tough, pH-sensitive hydrogel films with rapid load recovery.
Sina Naficy (2014)
10.1016/0923-0467(93)85007-I
Introduction to physical polymer science
C. Buckley (1993)
10.1039/c3sm52272e
Multi-scale multi-mechanism design of tough hydrogels: building dissipation into stretchy networks.
X. Zhao (2014)
10.1016/0038-0717(82)90103-1
Adsorption and binding of amino acids on homoionic montmorillonite and kaolinite
T. Dashman (1982)
10.1039/B924290B
Why are double network hydrogels so tough
J. Gong (2010)
10.1246/BCSJ.20110201
Novel Developed Systems and Techniques Based on Double-Network Principle
Z. Wu (2011)
10.1038/PJ.2010.141
Synthesis and properties of soft nanocomposite materials with novel organic/inorganic network structures
K. Haraguchi (2011)
10.1021/MA401053C
Facile Fabrication of Tough Hydrogels Physically Cross-Linked by Strong Cooperative Hydrogen Bonding
G. Song (2013)
10.1021/MA062924Y
Large Strain Hysteresis and Mullins Effect of Tough Double-Network Hydrogels
R. E. Webber (2007)
10.1021/MA401838H
Increasing Cross-Linking Efficiency of Methacrylated Chondroitin Sulfate Hydrogels by Copolymerization with Oligo(Ethylene Glycol) Diacrylates
Anahita Khanlari (2013)
10.1002/marc.201300242
Self-healing in tough graphene oxide composite hydrogels.
J. Liu (2013)
10.1038/ncomms1521
Redox-responsive self-healing materials formed from host–guest polymers
M. Nakahata (2011)
10.1002/1521-4095(20020816)14:16<1120::AID-ADMA1120>3.0.CO;2-9
Nanocomposite Hydrogels: A Unique Organic–Inorganic Network Structure with Extraordinary Mechanical, Optical, and Swelling/De‐swelling Properties
K. Haraguchi (2002)
10.1016/J.CLAY.2013.07.006
Quantitative characterization of the solid acidity of montmorillonite using combined FTIR and TPD based on the NH3 adsorption system
D. Liu (2013)
10.1016/J.CLAY.2010.01.007
Current challenges in clay minerals for drug delivery
César Viseras (2010)
10.1021/CM0509328
Force Field for Mica-Type Silicates and Dynamics of Octadecylammonium Chains Grafted to Montmorillonite
H. Heinz (2005)
10.1021/MA102118B
Modification of Nancomposite Gels by Irreversible Rearrangement of Polymer/Clay Network Structure through Drying
Kazutoshi Haraguchi (2010)
10.1002/anie.201203063
Self-healing supramolecular gels formed by crown ether based host-guest interactions.
M. Zhang (2012)
10.1002/adma.201400179
Novel nanocomposite hydrogels consisting of layered double hydroxide with ultrahigh tensibility and hierarchical porous structure at low inorganic content.
Ziqiao Hu (2014)
10.1021/ES034856Q
Investigating the molecular interactions of oxytetracycline in clay and organic matter: insights on factors affecting its mobility in soil.
Pankaj Kulshrestha (2004)
10.1039/C2SM27515E
Self-healing hydrogels formed in catanionic surfactant solutions
G. Akay (2013)
10.1016/J.COLSURFA.2008.02.019
Removal of methylene blue from aqueous solution using chitosan-g-poly(acrylic acid)/montmorillonite superadsorbent nanocomposite
L. Wang (2008)
10.1039/C2JM32541A
Tough and highly stretchable graphene oxide/polyacrylamide nanocomposite hydrogels
Ruiqiong Liu (2012)
10.1038/nature11409
Highly stretchable and tough hydrogels
Jeong-Yun Sun (2012)
10.1002/MARC.200600159
A Novel Highly Resilient Nanocomposite Hydrogel with Low Hysteresis and Ultrahigh Elongation
M. Zhu (2006)
10.1016/J.POLYMER.2012.10.015
Structure optimization of self-healing hydrogels formed via hydrophobic interactions
D. C. Tuncaboylu (2012)
Nanocomposite Hydrogels : AUnique OrganicInorganic Network Structure with Extraordinary Mechanical , Optical , and Swelling / Deswelling Properties
K. Haraguchi (2002)
10.1021/MA400447J
Time Dependence of Dissipative and Recovery Processes in Nanohybrid Hydrogels
S. Rose (2013)
10.1002/ADFM.201401989
Dipole–Dipole and H‐Bonding Interactions Significantly Enhance the Multifaceted Mechanical Properties of Thermoresponsive Shape Memory Hydrogels
Y. Zhang (2015)
10.1016/J.POLYMER.2008.09.021
Network chain density and relaxation of in situ synthesized polyacrylamide/hectorite clay nanocomposite hydrogels with ultrahigh tensibility
Lijun Xiong (2008)
10.1073/pnas.1201122109
Rapid self-healing hydrogels
A. Phadke (2012)
10.1039/c2cc34701f
Multivalent H-bonds for self-healing hydrogels.
J. Cui (2012)
10.1002/adma.201205321
Preorganized hydrogel: self-healing properties of supramolecular hydrogels formed by polymerization of host-guest-monomers that contain cyclodextrins and hydrophobic guest groups.
T. Kakuta (2013)
10.1002/marc.201100248
Self-healing in nanocomposite hydrogels.
K. Haraguchi (2011)



This paper is referenced by
10.1039/C6RA01074A
Synthesis of a self-healable and pH responsive hydrogel based on an ionic polymer/clay nanocomposite
Sovan Lal Banerjee (2016)
10.1080/09205063.2020.1775760
Mechanical strong stretchable conductive multi-stimuli-responsive nanocomposite double network hydrogel as biosensor and actuator
Y. Chen (2020)
10.1021/acsomega.8b01691
Na-Montmorillonite-Dispersed Sustainable Polymer Nanocomposite Hydrogel Films for Anticancer Drug Delivery
R. Kouser (2018)
10.1039/C8PY00644J
A crown-ether-based moldable supramolecular gel with unusual mechanical properties and controllable electrical conductivity prepared by cation-mediated cross-linking
Jae-hyeon Park (2018)
10.1016/j.polymertesting.2019.106300
Biohydrogel from unsaturated polyesteramide: Synthesis, properties and utilization as electrolytic medium for electrochemical supercapacitors
G. Ruano (2020)
10.5772/64138
Hydrogels with Self-Healing Attribute
L. Zhang (2016)
10.1002/adhm.201900670
Natural Polymer-Based Hydrogels with Enhanced Mechanical Performances: Preparation, Structure, and Property.
Ziting Bao (2019)
10.1039/C5RA12423A
Fabrication of poly(β-cyclodextrin-co-citric acid)/bentonite clay nanocomposite hydrogel: thermal and absorption properties
A. Heydari (2015)
10.1016/J.POLYMERTESTING.2018.05.025
Fully physical double network hydrogels with high strength, rapid self-recovery and self-healing performances
D. Wei (2018)
10.1039/c9tc04853g
Stretchable, compressible, self-healable carbon nanotube mechanically enhanced composite hydrogels with high strain sensitivity
Chenguang Pan (2020)
10.1039/c7sm02005h
Hybrid pectin-Fe3+/polyacrylamide double network hydrogels with excellent strength, high stiffness, superior toughness and notch-insensitivity.
R. Niu (2017)
10.1016/j.carbpol.2018.03.039
Self-healable tough supramolecular hydrogels crosslinked by poly-cyclodextrin through host-guest interaction.
Tingting Cai (2018)
10.1016/J.CARBPOL.2019.114977
Stretchable, tough, self-recoverable, and cytocompatible chitosan/cellulose nanocrystals/polyacrylamide hybrid hydrogels.
Weijuan Huang (2019)
10.1002/POLB.24728
Strong and tough hydrogels crosslinked by multi‐functional polymer colloids
Jun Fu (2018)
10.1016/j.ijbiomac.2019.01.099
Highly mechanical properties nanocomposite hydrogels with biorenewable lignin nanoparticles.
Y. Chen (2019)
10.1039/d0tb02029j
Shape memory effect and rapid reversible actuation of nanocomposite hydrogels with electrochemically controlled local metal ion coordination and crosslinking.
Yang Cong (2020)
10.1016/J.CEJ.2018.02.009
Sustained heparin release actuator achieved from thermal and water activated shape memory hydrogels containing main-chain LC units
Huilong Guo (2018)
10.1039/C7RA08272J
A high modulus hydrogel obtained from hydrogen bond reconstruction and its application in vibration damper
Longxiang Zhu (2017)
10.1016/j.polymer.2020.122319
Super tough, ultra-stretchable, and fast recoverable double network hydrogels physically crosslinked by triple non-covalent interactions
L. Zhou (2020)
10.1073/pnas.1821617116
Helical nanofiber yarn enabling highly stretchable engineered microtissue
Y. Li (2019)
10.1039/C7TB02028G
Bilayered polyurethane/dipole-dipole and H-bonding interaction reinforced hydrogels as thermo-responsive soft manipulators.
H. Jia (2017)
10.1039/C6TB00583G
Tough and responsive oppositely charged nanocomposite hydrogels for use as bilayer actuators assembled through interfacial electrostatic attraction.
Shuhui Liu (2016)
10.1016/j.clay.2019.105347
Fabrication of a sustained release delivery system for pesticides using interpenetrating polyacrylamide/alginate/montmorillonite nanocomposite hydrogels
Furui He (2019)
10.1021/ACS.MACROMOL.8B01496
A Tough and Stiff Hydrogel with Tunable Water Content and Mechanical Properties Based on the Synergistic Effect of Hydrogen Bonding and Hydrophobic Interaction
X. Zhang (2018)
10.1002/ADEM.201600272
One‐Pot Fabrication of a Novel Agar‐Polyacrylamide/Graphene Oxide Nanocomposite Double Network Hydrogel with High Mechanical Properties
P. Zhu (2016)
10.1016/j.ijbiomac.2017.10.104
Self-healing and tough hydrogels with physically cross-linked triple networks based on Agar/PVA/Graphene.
Navid Samadi (2018)
10.1021/acsami.7b15843
Semicrystalline Hydrophobically Associated Hydrogels with Integrated High Performances.
D. Wei (2018)
10.1039/C7RA00317J
Enhancing the self-recovery and mechanical property of hydrogels by macromolecular microspheres with thermal and redox initiation systems
C. Huang (2017)
10.1039/d0qm00857e
Visible-light-induced scission and rapid healing of polyurethane elastomers based on photoswitchable hexaarylbiimidazole units
Xiang Shili (2021)
10.1016/J.POLYMER.2020.123042
Mechanical enhancement of hydrophobically associating hydrogels by solvent-regulated phase separation
Wei Cui (2020)
10.1016/j.colsurfb.2017.11.021
Drug-eluting silicone hydrogel for therapeutic contact lenses: Impact of sterilization methods on the system performance.
R. Galante (2018)
10.1021/acsami.8b08873
Extremely Stretchable, Stable, and Durable Strain Sensors Based on Double-Network Organogels.
Haoxiang Zhang (2018)
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