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One-step Dip Coating Of Zwitterionic Sulfobetaine Polymers On Hydrophobic And Hydrophilic Surfaces.
Harihara S. Sundaram, X. Han, Ann K. Nowinski, Jean-Rene Ella-Menye, Collin Wimbish, P. Marek, K. Senecal, S. Jiang
Published 2014 · Materials Science, Medicine
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Zwitterionic sulfobetaine polymers with a catechol chain end (DOPA-PSB) were applied to a variety of hydrophobic polymer sheets and fibers. In addition, a silica surface was tested as a representative hydrophilic substrate. The polymer-coated surfaces showed significantly lower fouling levels than uncoated controls. Because of the anti-polyelectrolyte nature of sulfobetaine zwitterionic polymers, the effect of salt concentration on the coating solutions and the quality of the polymer coating against fouling are studied. The coating method involves only water-based solutions, which is compatible with most surfaces and is environmentally friendly. To demonstrate the versatility of the reported method, we evaluated the fouling levels of the polymer coating on commonly used polymeric surfaces such as polypropylene (PP), polydimethylsiloxane (PDMS), polystyrene (PS), nylon, polyvinyl chloride (PVC), and poly(methyl methacrylate) (PMMA).
This paper references
Polymer brushes––surface immobilized polymers
Stephen G. Boyes (2004)
Non-toxic antifouling strategies
Chelsea M Magin (2010)
Polymer brushes: surface-immobilized macromolecules
B. Zhao (2000)
Surface-grafted zwitterionic polymers as platforms for functional supported phospholipid membranes
M. Santonicola (2012)
Photocurable Amphiphilic Perfluoropolyether/Poly(ethylene glycol) Networks for Fouling-Release Coatings
Y. Wang (2011)
Surveying for Surfaces that Resist the Adsorption of Proteins
R. Chapman (2000)
Ultralow fouling and functionalizable surface chemistry based on a zwitterionic polymer enabling sensitive and specific protein detection in undiluted blood plasma.
Hana Vaisocherová (2008)
Superlow fouling sulfobetaine and carboxybetaine polymers on glass slides.
Z. Zhang (2006)
Mussel-Inspired Adhesives and Coatings.
B. P. Lee (2011)
Ultra low fouling zwitterionic polymers with a biomimetic adhesive group.
Guozhu Li (2008)
Understanding Marine Mussel Adhesion
Heather G. Silverman (2007)
Molecular simulation study of water interactions with oligo (ethylene glycol)-terminated alkanethiol self-assembled monolayers.
J. Zheng (2004)
Adaptive hydrophobic and hydrophilic interactions of mussel foot proteins with organic thin films
J. Yu (2013)
Phase behavior of poly(sulfobetaine methacrylate)-grafted silica nanoparticles and their stability in protein solutions.
Z. Dong (2011)
Pursuing "zero" protein adsorption of poly(carboxybetaine) from undiluted blood serum and plasma.
W. Yang (2009)
Reversibly switchable polymer with cationic/zwitterionic/anionic behavior through synergistic protonation and deprotonation
Harihara S. Sundaram (2014)
Physical, chemical, and chemical-physical double network of zwitterionic hydrogels.
Z. Zhang (2008)
Fluorinated amphiphilic polymers and their blends for fouling-release applications: the benefits of a triblock copolymer surface.
Harihara S. Sundaram (2011)
Modification of polysulfone with phospholipid polymer for improvement of the blood compatibility. Part 1. Surface characterization.
K. Ishihara (1999)
Single-molecule mechanics of mussel adhesion
H. Lee (2006)
Chain dimensions and surface characterization of superhydrophilic polymer brushes with zwitterion side groups
M. Kobayashi (2013)
Ultra-low fouling and functionalizable zwitterionic coatings grafted onto SiO2 via a biomimetic adhesive group for sensing and detection in complex media.
Norman D. Brault (2010)
Effects of cloud-point grafting, chain length, and density of PEG layers on competitive adsorption of ocular proteins.
P. Kingshott (2002)
Advances in nonfouling materials: perspectives for the food industry.
Tiphaine Mérian (2012)
Phosphorylcholine-based polymers and their use in the prevention of biofouling.
Zwitterionic polymers exhibiting high resistance to nonspecific protein adsorption from human serum and plasma.
J. Ladd (2008)
Zwitterionic hydrogels implanted in mice resist the foreign-body reaction
Lei Zhang (2013)
Self-assembled organic monolayers: model systems for studying adsorption of proteins at surfaces
K. L. Prime (1991)
Development of robust biocompatible silicone with high resistance to protein adsorption and bacterial adhesion.
W. Lin (2011)
Protein resistance of titanium oxide surfaces modified by biologically inspired mPEG-DOPA.
J. Dalsin (2005)
Surface grafted sulfobetaine polymers via atom transfer radical polymerization as superlow fouling coatings.
Z. Zhang (2006)
Mussel-Inspired Surface Chemistry for Multifunctional Coatings
H. Lee (2007)
Surface Hydration: Principles and Applications Toward Low-fouling/nonfouling Biomaterials
Shenfu Chen (2010)
Advances in polymers for anti-biofouling surfaces
S. Krishnan (2008)
Chain dimensions in free and immobilized brush states of polysulfobetaine in aqueous solution at various salt concentrations
Yuki Terayama (2011)
Photoiniferter-Mediated Polymerization of Zwitterionic Carboxybetaine Monomers for Low-Fouling and Functionalizable Surface Coatings
Jordan E Krause (2011)
Phase behaviour and solution properties of sulphobetaine polymers
D. Schulz (1986)
Adhesion of mussel foot protein-3 to TiO2 surfaces: the effect of pH.
J. Yu (2013)
An New Avenue to Nonfouling Materials
S. Chen (2008)
Functionalizable and ultra-low fouling zwitterionic surfaces via adhesive mussel mimetic linkages.
C. Gao (2010)
Effect of the intramolecular charge separation distance on the solution properties of betaines and sulfobetaines
J. Weers (1991)
Adsorption of proteins onto surfaces containing end-attached oligo(ethylene oxide): a model system using self-assembled monolayers
K. Prime (1993)
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Constructing safe and durable antibacterial textile surfaces using a robust graft-to strategy via covalent bond formation
L. He (2016)
Bioinspired Anti-fouling Coating on Hydrophobic Surfaces
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Highly efficient antibacterial surface grafted with a triclosan-decorated poly(N-hydroxyethylacrylamide) brush.
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Pseudopeptide polymer coating for improving biocompatibility and corrosion resistance of 316L stainless steel
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Investigation of Antifouling Properties of Surfaces Featuring Zwitterionic α-Aminophosphonic Acid Moieties.
Natalie M Wagner (2015)
Simple Coatings to Render Polystyrene Protein Resistant
Marcelle Hecker (2018)
Synthesis, Assembly, and Applications of Hybrid Nanostructures for Biosensing.
S. Zhang (2017)
Enhancing antifouling property of PVA membrane by grafting zwitterionic polymer via SI-ATRP method
M. Cui (2020)
Biomimetic Anchors for Antifouling Polymer Brush Coatings
Dicky Pranantyo (2017)
Mussel-mimicking sulfobetaine-based copolymer with metal tunable gelation, self-healing and antibacterial capability
M. Mrlík (2017)
Synthesis of catechol and zwitterion-bifunctionalized poly(ethylene glycol) for the construction of antifouling surfaces
L. Xu (2016)
Preparation and characterizations of poly(2-methyl-2-oxazoline) based antifouling coating by thermally induced immobilization.
Longchao Bai (2014)
Covalent Grafting of Antifouling Phosphorylcholine-Based Copolymers with Antimicrobial Nitric Oxide Releasing Polymers to Enhance Infection-Resistant Properties of Medical Device Coatings.
Qiao-hong Liu (2017)
Developing Low Fouling Peptides and Zwitterionic Materials for Biomedical Applications
Ann K. Nowinski (2015)
The synthesis and protein resistance of amphiphilic PDMS-b-(PDMS-g-cysteine) copolymers
Yufeng Lei (2017)
Facile fabrication of highly omniphobic and self-cleaning surfaces based on water mediated fluorinated nanosilica aggregation
C. Wei (2016)
PLL–Poly(HPMA) Bottlebrush-Based Antifouling Coatings: Three Grafting Routes
Esther Roeven (2020)
Dopamine-assisted immobilization of partially hydrolyzed poly(2-methyl-2-oxazoline) for antifouling and biocompatible coating
C. Pan (2015)
Conjugation of Hyaluronic Acid onto Surfaces via the Interfacial Polymerization of Dopamine to Prevent Protein Adsorption.
Renliang Huang (2015)
Toward Anti-icing and De-icing Surfaces: Effects of Surface Topography and Temperature
Golrokh Heydari (2016)
Zwitterionic surface grafting of epoxylated sulfobetaine copolymers for the development of stealth biomaterial interfaces.
Ying-Nien Chou (2016)
Engineering surfaces using photopolymerization to improve cochlear implant materials
Braden L Leigh (2018)
2D MXenes for Electromagnetic Shielding: A Review
Aamir Iqbal (2020)
Mussel-inspired one-step modification of a porous structured surface with self-cleaning properties for oil sorption
Si Pengxiang (2015)
Photo-responsive bio-inspired adhesives: facile control of adhesion strength via a photocleavable crosslinker
Minkyu Kim (2017)
Mixed polymer brushes with integrated antibacterial and antifouling properties
Yanhong Fu (2019)
Tannic acid-inspiration and post-crosslinking of zwitterionic polymer as a universal approach towards antifouling surface
Shengqiu Chen (2018)
A high efficiency approach for a titanium surface antifouling modification: PEG-o-quinone linked with titanium via electron transfer process.
Songtao Liu (2014)
Anti-fouling Medical Coatings
J. Li (2017)
Low-fouling electrospun PLLA films modified with zwitterionic poly(sulfobetaine methacrylate)-catechol conjugates.
W. Yang (2016)
Direct synthesis of well-defined zwitterionic cyclodextrin polymers via atom transfer radical polymerization
J. Diget (2019)
Preparation and characterization of protein-resistant hydrogels for soft contact lens applications via radical copolymerization involving a zwitterionic sulfobetaine comonomer
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