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Three-terminal Single-molecule Junctions Formed By Mechanically Controllable Break Junctions With Side Gating.
D. Xiang, Hyunhak Jeong, Dongku Kim, Takhee Lee, Yong-jin Cheng, Q. Wang, D. Mayer
Published 2013 · Materials Science, Medicine
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Molecules are promising candidates for electronic device components because of their small size, chemical tunability, and ability to self-assemble. A major challenge when building molecule-based electronic devices is forming reliable molecular junctions and controlling the electrical current through the junctions. Here, we report a three-terminal junction that combines both the ability to form a stable single-molecule junction via the mechanically controllable break junction (MCBJ) technique and the ability to shift the energy levels of the molecule by gating. Using a noncontact side-gate electrode located a few nanometers away from the molecular junction, the conductance of the molecule could be dramatically modulated because the electrical field applied to the molecular junction from the side gate changed the molecular electronic structure, as confirmed by the ab initio calculations. Our study will provide a new design for mechanically stable single-molecule transistor junctions fabricated by the MCBJ method.
This paper references
Transport properties of a single-molecule diode.
E. Loertscher (2012)
Shot noise suppression at room temperature in atomic-scale Au junctions.
P. J. Wheeler (2010)
Gap size dependent transition from direct tunneling to field emission in single molecule junctions.
D. Xiang (2011)
Statistical approach to investigating transport through single molecules.
E. Loertscher (2007)
A nanoelectromechanical single-atom switch.
C. A. Martin (2009)
Mechanical Control of Spin States in Spin-1 Molecules and the Underscreened Kondo Effect
J. J. Parks (2010)
The fabrication of sub-10 nm planar electrodes and their use for a molecule-based transistor
P. Visconti (2004)
Gated electronic currents modulation and designs of logic gates with single molecular field effect transistors
Yuqing Xu (2011)
The SAM, not the electrodes, dominates charge transport in metal-monolayer//Ga2O3/gallium-indium eutectic junctions.
W. Reus (2012)
Three-terminal devices to examine single-molecule conductance switching.
Z. Keane (2006)
Observation of molecular orbital gating
Hyunwook Song (2009)
Electronics using hybrid-molecular and mono-molecular devices
C. Joachim (2000)
Electronic excitations of a single molecule contacted in a three-terminal configuration.
E. A. Osorio (2007)
Benzenedithiol: a broad-range single-channel molecular conductor.
Young-sang Kim (2011)
Nucleation and growth of erbium clusters on amorphous carbon substrates. I. Cluster size and spatial distribution
H. Savaloni (1990)
Molecular electronics with single molecules in solid-state devices.
K. Moth-Poulsen (2009)
Controlling single-molecule conductance through lateral coupling of π orbitals.
I. Díez-Pérez (2011)
Sandwich-type gated mechanical break junctions.
C. A. Martin (2010)
Kondo resonance in a single-molecule transistor
W. Liang (2002)
Transverse field effects on DNA-sized particle dynamics.
M. Tsutsui (2009)
Vibrational spectroscopy of single-molecule junctions by direct current measurements
M. Tsutsui (2013)
Measurement of the conductance of a hydrogen molecule
R. H. M. Smit (2002)
The benzene molecule as a molecular resonant-tunneling transistor
M. Ventra (2000)
Conductance of a Molecular Junction
M. Reed (1997)
Single-molecule transport in three-terminal devices.
E. Osorio (2008)
Gate-controlled current and inelastic electron tunneling spectrum of benzene: a self-consistent study.
Y. Liang (2011)
Mechanically adjustable and electrically gated single-molecule transistors.
A. Champagne (2005)
Conductance and vibrational states of single-molecule junctions controlled by mechanical stretching and material variation.
Young-sang Kim (2011)
Experimental evidence for quantum interference and vibrationally induced decoherence in single-molecule junctions.
Stefan Ballmann (2012)
Molecular junctions bridged by metal ion complexes.
D. Xiang (2011)
Charge transport characteristics of diarylethene photoswitching single-molecule junctions.
Young-sang Kim (2012)
Field regulation of single-molecule conductivity by a charged surface atom
P. Piva (2005)
Chemical derivatization of an array of three gold microelectrodes with polypyrrole: Fabrication of a molecule-based transistor
H. White (1984)
Gate coupling to nanoscale electronics
S. S. Datta (2009)
Single-molecule junctions based on nitrile-terminated biphenyls: a promising new anchoring group.
A. Mishchenko (2011)
Nanomechanical oscillations in a single-C60 transistor
H. Park (2000)
Transport through metallic nanogaps in an in-plane three-terminal geometry
A. Mangin (2009)
Measurement and control of single molecule conductance
N. Tao (2005)
Gating of a Molecular Transistor: Electrostatic and Conformational
A. Ghosh (2002)
Microfabrication of a Mechanically Controllable Break Junction in Silicon
C. Zhou (1995)
Single-electron transistor of a single organic molecule with access to several redox states
S. Kubatkin (2003)
Measurement of Single Molecule Conductance: Benzenedithiol and Benzenedimethanethiol
X. Xiao (2004)
A theoretical study of molecular conduction: IV. A three-terminal molecular device.
T. Shimazaki (2007)
Conductance switching and vibrational fine structure of a [2 x 2] Co(II)(4) gridlike single molecule measured in a three-terminal device.
E. Osorio (2010)
Molecular junctions based on aromatic coupling.
S. Wu (2008)
Large gate modulation in the current of a room temperature single molecule transistor.
B. Xu (2005)
Electron transport through molecules: Gate-induced polarization and potential shift
S. Ke (2005)
Novel cruciform structures as model compounds for coordination induced single molecule switches.
Sergio Grunder (2010)
The fabrication and characterization of adjustable nanogaps between gold electrodes on chip for electrical measurement of single molecules.
Jing-Hua Tian (2010)
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Doping-induced negative differential conductance enhancement in single-molecule junction
Z. Li (2019)
Recent progress in the development of molecular-scale electronics based on photoswitchable molecules
Xianhui Huang (2020)
Advance of Mechanically Controllable Break Junction for Molecular Electronics
L. Wang (2017)
Non-equilibrium tunneling through Au–C 20 –Au molecular bridge using density functional theory–non-equilibrium Green function approach
M. Kaur (2016)
Single-molecule junctions for molecular electronics
Yuki Komoto (2016)
Research Update: Molecular electronics: The single-molecule switch and transistor
K. Sotthewes (2014)
High thermopower of mechanically stretched single-molecule junctions
M. Tsutsui (2015)
Solution-Processable Carbon Nanoelectrodes for Single-Molecule Investigations.
J. Zhu (2016)
Lateral scaling and positioning effects of top-gate electrodes on single-molecule field-effect transistors.
Yuqing Xu (2019)
Towards Rectifying Performance at the Molecular Scale
G. Zhang (2017)
Direct mapping of electrical noise sources in molecular wire-based devices
Duckhyung Cho (2017)
Photoswitching Molecular Junctions: Platforms and Electrical Properties.
Young-sang Kim (2020)
Stabilization of Pristine Low Resistive State in a Ruthenium(II)‐Polymer of a Hexadentate Schiff Base Ligand: Synthesis, Characterization, and Application as Non‐Volatile Memory Device
D. Oberoi (2020)
Robust Pt-based nanogap electrodes with 10 nm scale ultrafine linewidth
Y. Y. Choi (2019)
Morphology pursuance in C20 fullerene molecular junction: ab initio implementation
M. Kaur (2017)
Thermal and Thermoelectric Properties of Molecular Junctions
Kun Wang (2020)
First principle approach to elucidate transport properties through l-glutamic acid-based molecular devices using symmetrical electrodes
Gaurav Sikri (2020)
Controlled covalent binding of antiferromagnetic tetramanganese complexes to carbon nanotubes
R. Frielinghaus (2015)
Electrostatic control of thermoelectricity in molecular junctions.
Young-sang Kim (2014)
Molecular Electronics: A Brief Overview of the Status of the Field
J. M. Ruitenbeek (2016)
Noise characterization of metal-single molecule contacts
D. Xiang (2015)
Molecular Orbital Gating Surface-Enhanced Raman Scattering.
Chenyang Guo (2018)
A quantum circuit rule for interference effects in single-molecule electrical junctions.
David Zsolt Manrique (2015)
Environmental Control of Charge Transport through Single-Molecule Junctions
B. Capozzi (2015)
Negative Differential Resistance and Hysteresis in Self‐Assembled Nanoscale Networks with Tunable Molecule‐to‐Nanoparticle Ratios
Anusha Venkataraman (2020)
Spectroscopic interrogation and charge transport properties of molecular transistors
Inho Jeong (2019)
Time Evolution in Open Quantum Systems - From Exciton Dynamics to Charge Transport
Hasan Abdur Rahman (2019)
Conductance through single biphenyl molecules: symmetric and asymmetric coupling to electrodes
Karthiga Kanthasamy (2015)
Fast sensitive amplifier for two-probe conductance measurements in single molecule break junctions.
T. K. Johnson (2017)
Negative differential resistance observation in complex convoluted fullerene junctions
Milanpreet Kaur (2018)See more