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Synthesis Of An Anionic Tridentate Phosphinoborate And Its Reaction Chemistry With Sn(II)

Alfred A. Barney, A. F. Heyduk, D. Nocera
Published 1999 · Chemistry

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Dichlorophenylborane reacts smoothly with [Li- (tmen)][CH2PPh2] in THF to afford, in good yields, the Li(tmen)+ salt of a novel monoanionic tridentate phosphinoborate, tris(diphenylphosphinomethyl)phenylborate; reaction of the ligand with SnCl2 produces tris(diphenylphosphinomethyl) phenylboratotin(II) chloride, which may be dehalogenated to give the η3 compound, {[PhB- (CH2PPh2)3]Sn}PF6, tris(diphenylphosphinomethyl)- phenylboratotin(II) hexafluorophosphate.
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