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Photophysical Properties Of Metal Complexes

M. Ward
Published 2005 · Materials Science

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This review summarises developments in the photophysical properties of molecular metal complexes and their polynuclear and supramolecular assemblies for 2005. The huge increase in the popularity of this field (291 references included this year, compared to 145 last year) means that only the major high-impact journals have been covered. Particular highlights for the year (in the author’s opinion) include the following: single-molecule luminescence studies on very large multi-porphyrin oligomers containing up to 96 chromophores; achievement of exceptionally long near-IR luminescence lifetimes for lanthanide complexes using two quite different strategies; the demonstration of simultaneous multi-colour luminescence from metal complexes or complex assemblies using three different strategies; the detection of a picosecond-scale luminescence component from a simple [Ru(bpy)3]2+ derivative arising from a non-thermalised excited state; and generation of long-lived charge-separated states of up to 1 second in a donor-chromophore-acceptor triad. Areas of particularly strong interest have been the generation and evaluation of new dyes for solar cells, and intensely phosphorescent complexes [usually of Ir(III) and Pt(II)] for use in OLEDs.
This paper references
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Conformational control of excited-state dynamics in highly distorted Ru(II) polypyridyl complexes.
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Competitive Electron Transfer from the S2and S1Excited States of Zincmeso-Tetraphenylporphyrin to a Covalently Bound Pyromellitimide: Dependence on Donor−Acceptor Structure and Solvent
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Fine Tuning of MLCT States in New Mononuclear Complexes of Ruthenium(II) Containing Tris(1-pyrazolyl)methane, 2,2′-Bipyridine and Aromatic Nitrogen Heterocycles
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Steady-State and Time-Resolved Photophysical Studies on a Series of Gallium Phthalocyanine Monomers and Dimers
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Synthetic control of Pt...Pt separation and photophysics of binuclear platinum complexes.
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10.1021/IC035471B
Excited-state dynamics of fac-[ReI(L)(CO)3(phen)]+ and fac-[ReI(L)(CO)3(5-NO2-phen)]+ (L = imidazole, 4-ethylpyridine; phen = 1,10-phenanthroline) complexes.
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A dramatic elongation of the lifetime of charge-separated state by complexation with yttrium triflate in ferrocene-anthraquinone linked dyad.
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Role of the spacer in the singlet-singlet energy transfer mechanism (Förster vs Dexter) in cofacial bisporphyrins.
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Luminescent iridium(III)-terpyridine complexes: Interplay of ligand centred and charge transfer states
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Tetranuclear Polypyridyl Complexes of RuII and FeII: Synthesis, Electrochemical, Photophysical and Photochemical Behaviour
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Ligand-to-Diimine/Metal-to-Diimine Charge-Transfer Excited States of [Re(NCS)(CO)3(α-diimine)] (α-diimine = 2,2‘-bipyridine, di-iPr-N,N-1,4-diazabutadiene). A Spectroscopic and Computational Study
A. Rodríguez (2005)
10.1039/B508063K
Two-color luminescence from a tetranuclear Ir(III)/Ru(II) complex.
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10.1039/B404101C
A novel dinuclear cyclometalated iridium complex bridged with 1,4-bis[pyridine-2-yl]benzene: its structure and photophysical properties.
A. Tsuboyama (2004)
10.1002/EJIC.200500439
Synthesis, Crystal Structures and Photoluminescence of Mercury(II) Complexes with Two Homologous Novel Functional Rigid Ligands
H. Zhou (2005)
10.1021/IC048312G
Synthesis and luminescence properties of Cr(III) complexes with cyclam-type ligands having pendant chromophores, trans-[Cr(L)Cl(2)]Cl.
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10.1039/B502375K
Pt(II) mono-carbonyl complexes of a cyclometallating 2-(2'-thienyl)-(pyridinato-C,3N') ligand: nature and dynamics of the lowest excited state of the chloro- and thiolato-complexes.
Yurii A Kovelenov (2005)
10.1021/IC0508573
Synthesis and photophysical properties of meso-substituted bisporphyrins: comparative study of phosphorescence quenching for dioxygen sensing.
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Synthesis of Ru(II) complexes of N-heterocyclic carbenes and their promising photoluminescence properties in water.
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Syntheses, characterization, and luminescence of Pt II-M I (M = Cu, Ag, Au) heterometallic complexes by incorporating Pt(diimine)(dithiolate) with [M2(dppm)2]2+ (dppm = Bis(diphenylphosphino)methane).
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Structural studies of lanthanide ion complexes of pure gold, pure silver and mixed metal (gold-silver) dicyanides.
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Highly conjugated (polypyridyl)metal-(porphinato)zinc(II) compounds: long-lived, high oscillator strength, excited-state absorbers having exceptional spectral coverage of the near-infrared.
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Exciton-like energy collection in an oligothiophene wire end-capped by Ru- and Os-polypyridine chromophores.
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A high molar extinction coefficient sensitizer for stable dye-sensitized solar cells.
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Sensitization of near-infrared-emitting lanthanide cations in solution by tropolonate ligands.
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Push-pull effects and emission from ternary complexes of platinum(II), substituted terpyridines, and the strong-field cyanide ion.
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Femtosecond transient absorption anisotropy study on [Ru(bpy)3]2+ and [Ru(bpy)(py)4]2+. Ultrafast interligand randomization of the MLCT state.
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Two-photon uncaging of neurochemicals using inorganic metal complexes.
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A comparative study of water soluble 5,10,15,20-tetrakis(2,6-dichloro-3-sulfophenyl)porphyrin and its metal complexes as efficient sensitizers for photodegradation of phenols.
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Photocontrol of electron transfer from Zn-porphyrin to an axially bound stilbazole-pyromellitic diimide conjugate.
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Wavelength-dependent electron and energy transfer pathways in a side-to-face ruthenium porphyrin/perylene bisimide assembly.
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Excited states of nitro-polypyridine metal complexes and their ultrafast decay. Time-resolved IR Absorption, spectroelectrochemistry, and TD-DFT calculations of fac-[Re(Cl)(CO)3(5-nitro-1,10-phenanthroline)].
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Heteroleptic cyclometalated iridium(III) complexes displaying blue phosphorescence in solution and solid state at room temperature.
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Mechanism and Dynamics of Interligand Electron Transfer in fac-(Re(MQ + )(CO)3(dmb)) 2+ . An Ultrafast Time-Resolved Visible and IR Absorption, Resonance Raman, and Emission Study (dmb ) 4,4'-Dimethyl-2,2'-bipyridine, MQ + ) N-Methyl-4,4'-bipyridinium)
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Synthesis, structure, characterization, and photophysical studies of a new platinum terpyridyl-based triad with covalently linked donor and acceptor groups.
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Green photoluminescence from platinum(II) complexes bearing silylacetylide ligands.
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Synthesis, Structure, and Photophysical and Electrochemical Properties of Cyclometallated Iridium(III) Complexes with Phenylated Bipyridine Ligands
Marc Lepeltier (2005)
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Ultrafast Excited State Dynamics of Tri- and Hexaporphyrin Arrays
Ana Morandeira (2004)
10.1039/B417206J
Fluorescence studies of the intra-cellular distribution of zinc bis(thiosemicarbazone) complexes in human cancer cells.
A. Cowley (2005)
10.1039/B414031A
Ruthenium bis-terpyridine complexes connected to an oligothiophene unit for dry dye-sensitised solar cells.
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Tuning photoinduced energy- and electron-transfer events in subphthalocyanine-phthalocyanine dyads.
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Comparative study of ruthenium(II) tris(bipyridine) derivatives for electrochemiluminescence application.
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Solution-processible conjugated electrophosphorescent polymers.
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Synthesis and photophysics of a porphyrin-fullerene dyad assembled through Watson-Crick hydrogen bonding.
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Direct tyrosine oxidation using the MLCT excited states of rhenium polypyridyl complexes.
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Luminescent gold(III) alkynyl complexes: synthesis, structural characterization, and luminescence properties.
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Synthesis, Structure and Photoluminescent Studies of a Novel Supramolecular [Ag(phen)(CN)]·(phen) Complex
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Photocytotoxicity of a new Rh2(II,II) complex: increase in cytotoxicity upon irradiation similar to that of PDT agent hematoporphyrin.
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Visible light sensitisation of europium(III) luminescence in a 9-hydroxyphenal-1-one complex.
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Lanthanide luminescent switches: modulation of the luminescence of bis-macrocyclic based Tb(III) conjugates in water by H+, Na+ and K+.
T. Gunnlaugsson (2005)
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Synthesis and Luminescent Properties of Novel Europium(III) Heterocyclic β‐Diketone Complexes with Lewis Bases: Structural Analysis Using the Sparkle/AM1 Model
Rani Pavithran (2005)
10.1002/CHEM.200400598
A remarkable ligand orientational effect in osmium-atom-induced blue phosphorescence.
Jen-Kan Yu (2004)
10.1002/CHEM.200400888
Room-temperature phosphorescence and energy transfer in luminescent multinuclear platinum(II) complexes of branched alkynyls.
C. Tao (2005)
10.1021/JA046971M
Luminescent ruthenium(II)- and rhenium(I)-diimine wires bind nitric oxide synthase.
A. Dunn (2005)
10.1039/B412329H
pH dependent self-assembly of dimetallic lanthanide complexes.
S. Faulkner (2005)
10.1039/B508695G
Blue-to-green electrophosphorescence of iridium-based cyclometallated materials.
C. Mak (2005)
10.1021/IC050179K
Complexes of functionalized dipyrido[3,2-a:2',3'-c]-phenazine: a synthetic, spectroscopic, structural, and density functional theory study.
Natasha J. Lundin (2005)
10.1039/B508478D
Synthesis and photochemical characterization of a zinc phthalocyanine-zinc porphyrin heterotrimer and heterononamer.
Zhixin Zhao (2005)
10.1039/B313788K
A (bpy)2Ru-coordinated dehydro[12]annulene with exotopically fused diimine binding sites.
S. Ott (2004)
10.1021/IC048622Z
Syntheses and properties of emissive iridium(III) complexes with tridentate benzimidazole derivatives.
T. Yutaka (2005)
10.1021/IC050748O
(Fluoren-9-ylidene)methanedithiolato complexes of platinum: synthesis, reactivity, and luminescence.
J. Vicente (2005)
10.1039/B414929G
Boronic acid-substituted metal complexes: versatile building blocks for the synthesis of multimetallic assemblies.
Kathryn J. Arm (2005)
10.1021/IC049288+
Room temperature phosphorescence from ruthenium(II) complexes bearing conjugated pyrenylethynylene subunits.
D. Kozlov (2004)
10.1002/EJIC.200400533
A Theoretical Investigation of Substituent Effects on the Absorption and Emission Properties of a Series of Terpyridylplatinum(II) Acetylide Complexes
X. Liu (2005)
10.1021/JP045818B
Photochemically Reversible Luminescence Lifetime Switching in Metal−Organic Systems
Denis V. Kozlov and (2004)
10.1039/B316486C
Designing tridentate ligands for ruthenium(II) complexes with prolonged room temperature luminescence lifetimes.
Elaine A. Medlycott (2005)
10.1021/JA053048R
Unique emission from polymer based lanthanide alloys.
R. Shunmugam (2005)
10.1039/B506335C
Intramolecular excitation energy transfer in diarylurea-linked zinc porphyrin-anthracene dyads.
Masayuki Ezoe (2005)
10.1039/B506818E
Photophysical properties of binuclear ruthenium(ii) bis(2,2':6',2''-terpyridine) complexes built around a central 2,2'-bipyrimidine receptor.
A. Harriman (2005)
10.1021/IC050385S
Efficient red-emitting cyclometalated Iridium(III) complexes containing lepidine-based ligands.
K. Thomas (2005)
10.1002/EJIC.200500335
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V. G. Vaidyanathan (2005)
10.1039/B402270J
Re(I) sensitised near-infrared lanthanide luminescence from a hetero-trinuclear Re2Ln array.
S. Pope (2004)
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Proton-driven self-assembled systems based on cyclam-cored dendrimers and [Ru(bpy)(CN)4]2-.
G. Bergamini (2004)
10.1021/JA044847X
Unusually high performance photovoltaic cell based on a [60]fullerene metal cluster-porphyrin dyad SAM on an ITO electrode.
Youn-Jaung Cho (2005)
10.1021/IC050115+
Crystal Structure and Luminescence of Lanthanide Monodentate Complexes [Ln(C4N4H6O)2(H2O)6]Cl3 and [Ln(C4N4H6O)2(H2O)3(NO3)3] (Ln = Tb or Eu)
G. Law (2005)
10.1021/IC049114S
Control of electron acceptor ability with ligands (L) in photoinduced electron transfer from zinc porphyrin or zinc phthalocyanine to [Ru3(mu3-O)(mu-CH3COO)6L3]+.
M. Itou (2005)
10.1021/IC0351038
Dyads containing iridium(III) bis-terpyridine as photoactive center: synthesis and electron transfer study.
E. Baranoff (2004)
10.1002/CHEM.200305308
Long-lived charge-separated state generated in a ferrocene-meso,meso-linked porphyrin trimer-fullerene pentad with a high quantum yield.
H. Imahori (2004)
10.1039/B410472M
Photophysical behavior and intramolecular energy transfer in Os(II) diimine complexes covalently linked to anthracene.
G. Balázs (2005)
10.1039/B509662F
Design, self-assembly, and photophysical properties of pentameric metallomacrocycles: [M5(N-hexyl[1,2-bis(2,2':6',2''-terpyridin-4-yl)]carbazole)5][M = Fe(II), Ru(II), and Zn(II)].
Seok-Ho Hwang (2005)
10.1021/IC050844P
Tuning the triplet energy levels of pyrazolone ligands to match the 5D0 level of europium(III).
M. Shi (2005)
10.1039/B506319A
External heavy-atom effect of gold in a supramolecular acid-base pi stack.
A. Mohamed (2005)
10.1039/B404820B
Photoinduced Ru-Yb energy transfer and sensitised near-IR luminescence in a coordination polymer containing co-crystallised [Ru(bipy)(CN)4]2- and Yb(III) units.
T. A. Miller (2004)
10.1002/EJIC.200300321
Linear Multinuclear RuII Photosensitizers
Simona Vaduvescu (2004)
10.1039/B503873A
Photoelectrochemical measurements of a heterosupramolecular system under visible light irradiation.
G. Wilson (2005)
10.1039/B503980K
A new europium chelate-based phosphorescence probe specific for singlet oxygen.
B. Song (2005)
10.1021/JA036579T
Gated electron transfer as a probe of the configurational dynamics of peptide-protein complexes.
L. Liu (2004)
10.1002/CHEM.200400990
Triplet-triplet energy transfer controlled by the donor-acceptor distance in rigidly held palladium-containing cofacial bisporphyrins.
S. Faure (2005)
10.1039/B308101J
Intramolecular charge separation in a hydrogen bonded tyrosine-ruthenium(II)-naphthalene diimide triad.
O. Johansson (2004)
10.1039/B306702E
Photoelectrochemical properties of supramolecular species containing porphyrin and ruthenium complexes on TiO(2) films.
A. Nogueira (2004)
10.1021/IC050085A
Photosensitizer in a molecular bowl: steric protection enhancing the photonuclease activity of copper(II) scorpionates.
S. Dhar (2005)
10.1021/IC034527Z
Intense fluorescence of metal-to-ligand charge transfer in [Pt(0)(binap)(2)] [binap = 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl].
Zainul Abedin-Siddique (2004)
10.1002/ANIE.200500031
Simultaneous observation of green multiphoton upconversion and red and blue NLO processes from polymeric terbium(III) complexes.
K. Wong (2005)
10.1016/J.ICA.2003.11.002
Photophysical properties, electronic and crystal structures of luminescent diphosphine digold(I)-pyridine-2-thiolate complexes
B. Tzeng (2004)
10.1002/ANIE.200460255
Self-assembly of cyclic metal-DNA nanostructures using ruthenium tris(bipyridine)-branched oligonucleotides.
Debbie Mitra (2004)
10.1021/IC050335N
Extending the nitrogen-heterosuperbenzene family: the spectroscopic, redox, and photophysical properties of "half-cyclized" N-1/2HSB and Its Ru(II) complex.
D. J. Gregg (2005)
10.1002/ANIE.200502009
Ion-coordinating sensitizer in solid-state hybrid solar cells.
H. Snaith (2005)
10.1021/IC049638S
Cu(I)(2,9-bis(trifluoromethyl)-1,10-phenanthroline)2+ complexes: correlation between solid-state structure and photoluminescent properties.
A. Kovalevsky (2004)
10.1016/J.CCR.2004.11.006
Metal-containing molecular rectangles: synthesis and photophysical properties
P. Thanasekaran (2005)
10.1002/ANIE.200462306
A metal-based lumophore tailored to sense biologically relevant oxometalates.
A. Peacock (2005)
10.1021/JA0448216
Ultrafast energy-electron transfer cascade in a multichromophoric light-harvesting molecular square.
A. Sautter (2005)
10.1002/CHEM.200500069
Excitation-energy migration in self-assembled cyclic zinc(II)-porphyrin arrays: a close mimicry of a natural light-harvesting system.
In-Wook Hwang (2005)
10.1002/CHEM.200500119
Metal-directed synthesis and photophysical studies of trinuclear v-shaped and pentanuclear x-shaped ruthenium and osmium metallorods and metallostars based upon 4'-(3,5-dihydroxyphenyl)-2,2':6',2''-terpyridine divergent units.
E. Constable (2005)
10.1021/JA047523H
Self-assembly of heterobimetallic d-f hybrid complexes: sensitization of lanthanide luminescence by d-block metal-to-ligand charge-transfer excited states.
S. Pope (2004)
10.1021/IC048810P
Engineering of a novel ruthenium sensitizer and its application in dye-sensitized solar cells for conversion of sunlight into electricity.
C. Klein (2005)
10.1021/JA044395O
Switching the redox mechanism: models for proton-coupled electron transfer from tyrosine and tryptophan.
M. Sjödin (2005)
10.1002/EJIC.200400114
Effect of Substitution of Methyl Groups on the Luminescence Performance of IrIII Complexes: Preparation, Structures, Electrochemistry, Photophysical Properties and Their Applications in Organic Light‐Emitting Diodes (OLEDs)
Sung-ouk Jung (2004)
10.1039/B510782B
Supramolecular click chemistry for the self-assembly of a stable Zn(II)-porphyrin-C60 conjugate.
Ali Trabolsi (2005)
10.1021/JP052954N
Structural changes upon photoexcitation into the metal-to-ligand charge-transfer state of [Cu(pqx)(PPh3)2]+ probed by resonance Raman spectroscopy and density functional theory.
M. Waterland (2005)
10.1021/IC0514593
Solid-state photochromic device based on nanocrystalline TiO2 functionalized with electron donor-acceptor species.
Matteo Biancardo (2005)
10.1002/CHEM.200500040
Surface-grafted multiporphyrin arrays as light-harvesting antennae to amplify photocurrent generation.
M. Morisue (2005)
10.1002/EJIC.200400443
Syntheses, Structures, and Luminescent Properties of [Bis(iminoalkyl)pyridine]cadmium(II) Complexes
R. Fan (2004)
10.1039/B411122B
A highly efficient redox chromophore for simultaneous application in a photoelectrochemical dye sensitized solar cell and electrochromic devices
A. Nogueira (2005)
10.1021/IC0487530
Blue luminescent 2-(2'-pyridyl)benzimidazole derivative ligands and their orange luminescent mononuclear and polynuclear organoplatinum(II) complexes.
Q. Liu (2005)
10.1021/IC0351848
Iridium cyclometalated complexes with axial symmetry. Synthesis and photophysical properties of a trans-biscyclometalated complex containing the terdentate ligand 2,6-diphenylpyridine.
M. Polson (2004)
10.1021/IC035143B
New lanthanide complexes for sensitized visible and near-IR light emission: synthesis, 1H NMR, and X-ray structural investigation and photophysical properties.
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10.1021/JA0482278
Photoinduced intramolecular electron transfer in ruthenium and osmium polyads: insights from theory.
I. Ciofini (2004)
10.1002/CHEM.200400032
Ruthenium complexes of easily accessible tridentate ligands based on the 2-aryl-4,6-bis(2-pyridyl)-s-triazine motif: absorption spectra, luminescence properties, and redox behavior.
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10.1021/IC0485965
Ruthenium(II) complexes of 1,12-diazaperylene and their interactions with DNA.
A. Chouai (2005)
10.1021/IC0351794
Structural characterization and luminescence behavior of a silver(I) 1D polymeric chain constructed via a Bridge with unusual 4,5-diazospirobifluorene and perchlorate.
C. Wang (2004)
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Effect of axial ligation or pi-pi-type interactions on photochemical charge stabilization in "two-point" bound supramolecular porphyrin-fullerene conjugates.
F. D’Souza (2005)
10.1021/IC050002Q
Mononuclear and dinuclear complexes of isoeilatin.
Sheba D. Bergman (2005)
10.1021/JA039727O
Structural and spectroscopic studies on Pt.Pt and pi-pi interactions in luminescent multinuclear cyclometalated platinum(II) homologues tethered by oligophosphine auxiliaries.
Wei Lu (2004)
10.1021/JA0345221
Efficient yellow electroluminescence from a single layer of a cyclometalated iridium complex.
J. Slinker (2004)
10.1021/IC049059N
Design of rhenium(I) polypyridine biotin complexes as a new class of luminescent probes for avidin.
K. Lo (2005)
10.1021/IC049166H
Luminescent platinum(II) dimers with a cyclometallating aryldiamine ligand.
Hershel Jude (2005)
10.1021/IC048573Q
Photoinduced electron transfer in platinum(II) terpyridinyl acetylide complexes connected to a porphyrin unit.
C. Monnereau (2005)
10.1002/CHEM.200500434
Interplay between intra- and interligand charge transfer with variation of the axial N-heterocyclic ligand in osmium(II) pyridylpyrazolate complexes: extensive color tuning by phosphorescent solvatochromism.
S. Li (2005)
10.1039/B415951A
Synthesis, photophysics, electrochemistry and metal ion-binding studies of rhenium(I) complexes with crown ether pendants: selective and specific binding properties for various metal ions
K. Wong (2005)
10.1039/B401302F
Pyrene-sensitised near-IR luminescence from ytterbium and neodymium complexes.
S. Faulkner (2004)
10.1021/IC050855I
Temperature dependent emission of hexarhenium(III) clusters [Re6(mu3-S)8X6]4- (X = Cl-, Br-, and I-): analysis by four excited triplet-state sublevels.
N. Kitamura (2005)
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Novel spectral and electrochemical characteristics of triphenylamine-bound zinc porphyrins and their intramolecular energy and electron transfer.
Chih-Wei Huang (2005)
10.1021/IC048261N
Synthesis, characterization, and photophysical properties of a free base and a biszinc(II) complex of 1,3-bisporphyrincalix[4]arene: evidence for "tunable intramolecular open and closed conformations".
Jean-Philipe Tremblay-Morin (2005)
10.1021/IC050901E
Unusual, bifurcated photoreactivity of a rhenium(I) carbonyl complex of triethynylphosphine.
Sean E. Hightower (2005)
10.1021/IC050436L
Photophysical properties of Ru(II) bipyridyl complexes containing hemilabile phosphine-ether ligands.
Sarah E. Angell (2005)
10.1021/IC048623R
Electropolymerization of vinylbipyridine complexes of ruthenium(II) and osmium(II) in SiO2 sol-gel films.
J. Yang (2005)
10.1039/B506837A
Distance-independent photoinduced energy transfer over 1.1 to 2.3 nm in ruthenium trisbipyridine–fullerene assemblies
F. Chaignon (2005)
10.1021/IC048786F
Photophysical, spectroscopic, and computational studies of a series of Re(I) tricarbonyl complexes containing 2,6-dimethylphenylisocyanide and 5- and 6-derivatized phenanthroline ligands.
J. M. Villegas (2005)
10.1021/IC050960S
Efficient photoreduction process of [Ru3(mu3-O)(mu-CH3CO2)6L3]+ by electron-mediation via the viologen dication by excitation of a zinc porphyrin.
M. Otake (2005)
10.1039/B411341A
Complexes of substituted derivatives of 2-(2-pyridyl)benzimidazole with Re(I), Ru(II) and Pt(II): structures, redox and luminescence properties.
N. M. Shavaleev (2004)
10.1039/B407985J
Supramolecular complex composed of a covalently linked zinc porphyrin dimer and fulleropyrrolidine bearing two axially coordinating pyridine entities.
F. D’Souza (2004)
10.1021/IC0499291
[Ru(bpy)2(L)]Cl2: luminescent metal complexes that bind DNA base mismatches.
E. Rueba (2004)
10.1021/IC048247A
A new strategy for the improvement of photophysical properties in ruthenium(II) polypyridyl complexes. Synthesis and photophysical and electrochemical characterization of six mononuclear ruthenium(II) bisterpyridine-type complexes.
Maria Abrahamsson (2005)
10.1039/B400933A
Effect of the parent ligand on the photophysical properties of closely-coupled, binuclear ruthenium(II) tris(2,2'-bipyridine) complexes.
A. Benniston (2004)
10.1039/B413708F
A highly electroluminescent molecular square.
L. Zhang (2005)
10.1039/B417058J
Substituent effects of iridium complexes for highly efficient red OLEDs.
S. Okada (2005)
10.1039/B415021J
A luminescent Pt(II) complex with a terpyridine-like ligand involving a six-membered chelate ring.
Y. Hu (2005)
10.1039/B418362B
Photophysical study of a family of [Ru(phen)2(Me n dpq)]2+ complexes in different solvents and DNA: a specific water effect promoted by methyl substitution.
Karen O'Donoghue (2005)
10.1021/JA0401040
Long-range electron transfer across Peptide bridges: the transition from electron superexchange to hopping.
Rouba Abdel Malak (2004)
10.1039/B503315B
A novel class of phosphorescent gold(III) alkynyl-based organic light-emitting devices with tunable colour.
K. Wong (2005)
10.1039/B506310H
Red-light photosensitized cleavage of DNA by (l-lysine)(phenanthroline base)copper(II) complexes.
A. Patra (2005)
10.1021/JA030647U
Energy transfer followed by electron transfer in a supramolecular triad composed of boron dipyrrin, zinc porphyrin, and fullerene: a model for the photosynthetic antenna-reaction center complex.
F. D’Souza (2004)
10.1039/B503591K
Lanthanide luminescent mesomorphic complexes with macrocycles derived from diaza-18-crown-6
S. Suárez (2005)
10.1002/ANIE.200301762
Unusually slow charge recombination in molecular dyads.
A. Harriman (2004)
10.1002/CHEM.200400377
Vectorial electron relay at ITO electrodes modified with self-assembled monolayers of ferrocene-porphyrin-fullerene triads and porphyrin-fullerene Dyads for molecular photovoltaic devices.
H. Imahori (2004)
10.1021/IC035380E
Electron delocalization in a ruthenium(II) Bis(2,2':6',2' '-terpyridyl) complex.
A. Benniston (2004)
10.1039/B502553B
A pH-insensitive, ratiometric chemosensor for citrate using europium luminescence.
D. Parker (2005)
10.1021/JA034444H
Photophysical properties of ruthenium(II) polyazaaromatic compounds: a theoretical insight.
G. Pourtois (2004)
10.1039/B506575E
Low power upconversion using MLCT sensitizers.
Radiy R Islangulov (2005)
10.1021/IC034877L
Syntheses, Luminescence Behavior, and Assembly Reaction of Tetraalkynylplatinate(II) Complexes: Crystal Structures of [Pt(tBu3trpy)(C⋮CC5H4N)Pt(tBu3trpy)](PF6)3 and [Pt2Ag4(C⋮CC⋮CC6H4CH3-4)8(THF)4]
V. W. Yam (2004)
10.1021/IC050324U
Photophysical and electrochemical properties of heteroleptic tris-cyclometalated iridium(III) complexes.
Kenneth Dedeian (2005)
10.1039/B406958G
High efficiency mer-iridium complexes for organic light-emitting diodes.
Cheng-Hsien Yang (2004)
10.1039/b316176e
Eu(III)-cyclen-phen conjugate as a luminescent copper sensor: the formation of mixed polymetallic macrocyclic complexes in water.
T. Gunnlaugsson (2004)
10.1021/IC049277G
Iridium cyclometalated complexes with axial symmetry: time-dependent density functional theory investigation of trans-bis-cyclometalated complexes containing the tridentate ligand 2,6-diphenylpyridine.
M. Polson (2005)
10.1016/J.CCR.2005.06.021
Photophysics and structure of selected lanthanide compounds
P. Gawryszewska (2005)
10.1002/ANIE.200462762
Reversible self-organization of semisynthetic zinc chlorins into well-defined rod antennae.
Valerie Huber (2005)
10.1039/B409989C
Synthesis and luminescence studies of mono- and C3-symmetric, tris(ligand) complexes of Sm(III), Y(III) and Eu(III) with sulfur-bridged binaphtholate ligands.
L. Natrajan (2004)
10.1021/JA038763K
Structural control of the excited-state dynamics of bis(dipyrrinato)zinc complexes: self-assembling chromophores for light-harvesting architectures.
I. Sazanovich (2004)
10.1021/IC049750Q
Luminescent ruthenium(II) polypyridine biotin complexes: synthesis, characterization, photophysical and electrochemical properties, and avidin-binding studies.
K. Lo (2004)
10.1021/JA053814U
Control of photochemical, photophysical, electrochemical, and photocatalytic properties of rhenium(I) complexes using intramolecular weak interactions between ligands.
H. Tsubaki (2005)
10.1002/CHEM.200401287
Influence of pH on the photochemical and electrochemical reduction of the dinuclear ruthenium complex, [(phen)2Ru(tatpp)Ru(phen)2)Cl4, in water: proton-coupled sequential and concerted multi-electron reduction.
N. R. de Tacconi (2005)
10.1021/IC048951R
Synthesis and luminescent properties of novel lanthanide(III) beta-diketone complexes with nitrogen p,p'-disubstituted aromatic ligands.
Anna Bellusci (2005)
10.1002/CHEM.200500106
Luminescent platinum(II) terpyridyl complexes: effect of counter ions on solvent-induced aggregation and color changes.
V. W. Yam (2005)
10.1021/IC0507058
Observation of electroluminescence at room temperature from a ruthenium(II) bis-terpyridine complex and its use for preparing light-emitting electrochemical cells.
H. Bolink (2005)
10.1002/ANIE.200462382
Efficient two-photon-sensitized luminescence of a europium(III) complex.
Li-Min Fu (2005)
10.1002/EJIC.200401008
A Ruthenium(II)‐Complexed Rotaxane Whose Ring Incorporates a 6,6′‐Diphenyl‐2,2′‐bipyridine: Synthesis and Light‐Driven Motions
J. Collin (2005)
10.1039/B500849B
Metal-to-ligand charge-transfer sensitisation of near-infrared emitting lanthanides in trimetallic arrays M2Ln (M=Ru, Re or Os; Ln=Nd, Er or Yb).
S. Pope (2005)
10.1021/IC0498438
Ruthenium(II) dipyridoquinoxaline-norbornene: synthesis, properties, crystal structure, and use as a ROMP monomer.
A. Rezvani (2004)
10.1021/JA044097R
Temperature-induced switching of the mechanism for intramolecular energy transfer in a 2,2':6',2' '-Terpyridine-based Ru(II)-Os(II) trinuclear array.
A. Benniston (2005)
10.1021/JA047446Q
Photochromic and luminescence switching properties of a versatile diarylethene-containing 1,10-phenanthroline ligand and its rhenium(I) complex.
V. W. Yam (2004)
10.1021/IC049266N
Synthesis, photophysics, and optical limiting of platinum(II) 4'-tolylterpyridyl arylacetylide complexes.
Fengqi Guo (2005)
10.1021/JA048655D
Diastereoselective formation of chiral tris-cyclometalated iridium (III) complexes: characterization and photophysical properties.
Christine Schaffner-Hamann (2004)
10.1021/JA0441864
Dramatic increases in the lifetime of the Er3+ ion in a molecular complex using a perfluorinated imidodiphosphinate sensitizing ligand.
Gaetano Mancino (2005)
10.1039/B313526H
The triplet excited state of ruthenium(II) bis(2,2′:6′,2″-terpyridine): Comparison between experiment and theory
A. Amini (2004)
10.1039/B400513A
Elucidating excited state electronic structure and intercomponent interactions in multicomponent and supramolecular systems.
W. Browne (2005)
10.1021/JP051009W
Photoexcitation in Cu(I) and Re(I) complexes containing substituted dipyrido[3,2-a:2',3'-c]phenazine: a spectroscopic and density functional theoretical study.
P. J. Walsh (2005)
10.1002/CHEM.200401064
Heteroditopic ligand accommodating a fused phenanthroline and a schiff base cavity as molecular spacer in the study of electron and energy transfer.
Y. Pellegrin (2005)
10.1021/JA042232U
Charge separation and efficient light energy conversion in sensitized mesoscopic solar cells based on binary ionic liquids.
P. Wang (2005)
10.1039/b406851c
Tuning iridium(III) phenylpyridine complexes in the "almost blue" region.
P. Coppo (2004)
10.1039/B507114C
Water soluble luminescent platinum terpyridine complexes with glycosylated acetylide and arylacetylide ligands: photoluminescent properties and cytotoxicities.
Dik-Lung Ma (2005)
10.1021/IC051210L
Pyridylporphyrin metallacycles with a slipped cofacial geometry: spectroscopic, X-ray, and photophysical characterization.
E. Iengo (2005)
10.1021/JA044561S
A trimetallic mixed Ru(II)/Fe(II) terpyridyl complex with a long-lived excited state in solution at room temperature.
Sujoy Baitalik (2004)
10.1002/ANIE.200461953
White-light emission from an assembly comprising luminescent iridium and europium complexes.
P. Coppo (2005)
10.1039/B405114A
Electronic and photophysical properties of a novel phenol bound dinuclear ruthenium complex: evidence for a luminescent mixed valence state.
T. Keyes (2004)
10.1021/JA0491634
Complexed nitrogen heterosuperbenzene: the coordinating properties of a remarkable ligand.
S. Draper (2004)
10.1002/EJIC.200300677
Synthesis, Structures and Luminescent Properties of σ-Alkynyl Complexes of Orthomercuriated Schiff Bases
W. Wong (2004)
10.1039/B416575F
Lanthanide 8-hydroxyquinoline-based podates with efficient emission in the NIR range.
D. Imbert (2005)
10.1002/CHEM.200400829
Gold liquid crystals displaying luminescence in the mesophase and short F...F interactions in the solid state.
R. Bayón (2005)
10.1021/IC0482436
Long-lived near-infrared luminescent lanthanide complexes of imidodiphosphinate "shell" ligands.
Andrew P. Bassett (2005)
10.1021/JA048118T
Light-harvesting macroring accommodating a tetrapodal ligand based on complementary and cooperative coordinations.
Yusuke Kuramochi (2004)
10.1021/JA048983D
Unexpected change in charge transfer behavior in a cobalt(II) porphyrin-fullerene conjugate that stabilizes radical ion pair states.
L. R. Sutton (2004)
10.1021/JA042141X
Rationale for kinetic heterogeneity of ultrafast light-induced electron transfer from Ru(II) complex sensitizers to nanocrystalline TiO2.
Bernard Wenger (2005)
10.1021/JA052467L
Combined experimental and DFT-TDDFT computational study of photoelectrochemical cell ruthenium sensitizers.
M. Nazeeruddin (2005)
10.1021/IC049056A
Dinuclear zinc(II) complexes of tetraiminodiphenol macrocycles and their interactions with carboxylate anions and amino acids. Photoluminescence, equilibria, and structure.
Bula Dutta (2005)
10.1002/ANIE.200502231
An efficient design for the rigid assembly of four bidentate chromophores in water-stable highly luminescent lanthanide complexes.
Nicholas P. Chatterton (2005)
10.1002/EJIC.200400531
Structural and photophysical characterisation of fac-[tricarbonyl(chloro)- (5,6-epoxy-1,10-phenanthroline)rhenium(I)]
A. Martí (2005)
10.1039/B415711G
High-efficiency red electrophosphorescence based on neutral bis(pyrrole)-diimine platinum(II) complex.
Hai-Feng Xiang (2005)
10.1021/JA0469333
Development of a zinc ion-selective luminescent lanthanide chemosensor for biological applications.
K. Hanaoka (2004)
10.1002/ANIE.200500392
The structural and functional roles of rhodium(II)-rhodium(II) dimers in multinuclear ruthenium(II) complexes.
M. Cooke (2005)
10.1021/IC049459A
Synthesis and photochemical properties of a novel iron-sulfur-nitrosyl cluster derivatized with the pendant chromophore protoporphyrin IX.
C. L. Conrado (2004)
10.1021/JA00132A004
EXAFS, EPR, and Electronic Absorption Spectroscopic Study of the .alpha. Metallo Subunit of CO Dehydrogenase from Clostridium thermoaceticum
J. Xia (1995)
10.1039/B411686K
Adduct formation by photo-induced electron transfer between photo-oxidising Ru(II) complexes and tryptophan.
Etienne Gicquel (2004)
10.1002/EJIC.200400750
Synthesis, Structure, and Luminescent Properties of Guanidinate-Based Terbium Complexes
Xing'an Pang (2005)
10.1039/B411365A
Photoinduced oxidation of [Mn(L)3]2+ and [Mn2O2(L)4]3+ (L = 2,2′-bipyridine and 4,4′-dimethyl-2,2′-bipyridine) with the [Ru(bpy)3]2+/-aryl diazonium salt system
Carole Baffert (2005)
10.1021/JA048091D
Intensely luminescent gold(I)-silver(I) cluster complexes with tunable structural features.
Q. Wang (2004)
10.1021/IC051033O
Photophysical and structural impact of phosphorylated anions associated to lanthanide complexes in water.
L. Charbonnière (2005)
10.1039/B312524F
Unusual photophysical switching in a Ru(II) diimine DNA probe caused by amide functionalisation.
Karen O'Donoghue (2004)
10.1039/B403743J
A fluorescent chemosensor for Zn(II). Exciplex formation in solution and the solid state.
A. Bencini (2004)
10.1021/IC0483895
Structure and emission properties of Er3Q9 (Q = 8-quinolinolate).
F. Artizzu (2005)
10.1021/IC050512K
Structural and photophysical properties of coordination networks combining [Ru(bipy)(CN)4]2- anions and lanthanide(III) cations: rates of photoinduced Ru-to-lanthanide energy transfer and sensitized near-infrared luminescence.
G. Davies (2005)
10.1021/IC048875S
Syntheses and crystal structures of dinuclear complexes containing d-block and f-block luminophores. Sensitization of NIR luminescence from Yb(III), Nd(III), and Er(III) centers by energy transfer from Re(I)- and Pt(II)-bipyrimidine metal centers.
N. M. Shavaleev (2005)
10.1039/B506907F
Strongly luminescent binuclear aluminium chelate with polymer-like molecular packing and solution-processibility.
J. Qiao (2005)
10.1039/B510611G
Synthesis and time-resolved fluorimetric application of a europium chelate-based phosphorescence probe specific for singlet oxygen
B. Song (2005)
10.1021/IC050078M
Preparations and characterizations of bichromophoric systems composed of a ruthenium polypyridine complex connected to a difluoroborazaindacene or a zinc phthalocyanine chromophore.
F. Odobel (2005)
10.1021/JP052877W
Efficient light harvesting by using green Zn-porphyrin-sensitized nanocrystalline TiO2 films.
Q. Wang (2005)
10.1039/B414855J
Polynuclear complexes of a dissociative excited state formed in the [Ru(bpy)2(CN)2]-HgCl2 system.
Andrea Fodor-Kardos (2005)
10.1039/B508382F
Photophysical properties of Pr(III) and Er(III) complexes of poly(pyrazolyl)borates.
G. Davies (2005)
10.1002/CHEM.200305485
Synthesis, characterization and photochromic studies of spirooxazine-containing 2,2'-bipyridine ligands and their rhenium(I) tricarbonyl complexes.
Chi-Chiu Ko (2004)
10.1021/IC0492587
A heterobimetallic ruthenium(II)-copper(II) donor-acceptor complex as a chemodosimetric ensemble for selective cyanide detection.
C. Chow (2004)
10.1039/B415464A
A binaphthyl-containing Eu(III) complex and its interaction with human serum albumin: a luminescence study.
J. Hamblin (2005)
10.1039/B511157A
Conformational and photophysical studies on porphyrin-containing donor-bridge-acceptor compounds. Charge separation in micellar nanoreactors.
Víctor Martínez-Junza (2005)
10.1021/IC030324Z
Photoswitchable luminescence of rhenium(i) tricarbonyl diimines.
O. Wenger (2004)
10.1002/EJIC.200300918
Conformational Effects on the Photoinduced Energy Transfer in a Star‐Shaped Pentaporphyrin with Nucleosidic Linkers
L. Flamigni (2004)
10.1039/B507154B
Photophysics of ruthenium polypyridyl complexes formed with lacunary polyoxotungstates with iron addenda.
M. Seery (2005)
10.1021/JA0565727
A chiral luminescent Au16 ring self-assembled from achiral components.
Shu-Yan Yu (2005)
10.1021/IC049659M
Rhenium-to-benzoylpyridine and rhenium-to-bipyridine MLCT excited states of fac-[Re(Cl)(4-benzoylpyridine)(2)(CO)(3)] and fac-[Re(4-benzoylpyridine)(CO)(3)(bpy)](+): a time-resolved spectroscopic and spectroelectrochemical study.
M. Busby (2004)
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Synthesis and properties of the elusive ruthenium(II) complexes of 4'-cyano-2,2':6',2' '-terpyridine.
J. Wang (2005)
10.1021/JP0366320
Picosecond Relaxation of 3MLCT Excited States of [Re(Etpy)(CO)3(dmb)]+ and [Re(Cl)(CO)3(bpy)] as Revealed by Time-Resolved Resonance Raman, UV−vis, and IR Absorption Spectroscopy
D. J. Liard (2004)
10.1021/IC050596X
Binuclear wirelike dimers based on ruthenium(II)-bipyridine units linked by ethynylene-oligothiophene-ethynylene bridges.
A. Barbieri (2005)
10.1002/CHEM.200401158
Tuning the decay time of lanthanide-based near infrared luminescence from micro- to milliseconds through d-->f energy transfer in discrete heterobimetallic complexes.
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Synthesis, characterization, physicochemical, and photophysical studies of redox switchable NIR dye derived from a ruthenium-dioxolene-porphyrin system.
D. A. Jose (2005)
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A highly emissive Cu2N2 diamond core complex supported by a [PNP]- ligand.
S. Harkins (2005)
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Effect of surface immobilization on intramolecular and intermolecular electron transfer in a chromophore-donor-acceptor assembly.
M. Sykora (2005)
10.1021/JP0479670
[Ru(bpy)2dppz]2+ Light-switch mechanism in protic solvents as studied through temperature-dependent lifetime measurements
M. K. Brennaman (2004)
10.1039/B509234E
Synthesis of a new pair of fluorescence resonance energy transfer donor and acceptor dyes and its use in a protease assay.
E. K. Kainmüller (2005)
10.1039/b404742g
Fullerohelicates: a new class of fullerene-containing supermolecules.
F. Cardinali (2004)
10.1021/IC0513336
Remote and adjacent excited-state electron transfer at TiO2 interfaces sensitized to visible light with Ru(II) compounds.
F. Liu (2005)
10.1021/IC050098O
Synthesis, structure, spectroscopic properties, and photochemistry of homo- and heteropolynuclear copper(I) complexes bridged by the 2,5-bis(2-pyridyl)pyrazine ligand.
T. Tsubomura (2005)
10.1039/B416293E
Luminescent complexes of Re(I) and Ru(II) with appended macrocycle groups derived from 5,6-dihydroxyphenanthroline: cation and anion binding.
T. Lazarides (2005)
10.1002/EJIC.200401043
Luminescence from Lanthanide(3+) Ions in Solution
Anders Døssing (2005)
10.1021/IC050044E
Luminescent transition metal complexes as sensors: structural effects on pH response.
B. Higgins (2005)
10.1039/B507196H
The elusive phosphorescence of pyrromethene-BF2 dyes revealed in new multicomponent species containing Ru(II)-terpyridine subunits.
M. Galletta (2005)
10.1039/B407291J
A pseudo-rotaxane based on an iridium(III)–copper(I) dyad
E. Baranoff (2004)
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[60]fullerene-stoppered porphyrinorotaxanes: pronounced elongation of charge-separated-state lifetimes.
K. Li (2004)
10.1002/EJIC.200500593
Intense Near‐Infrared Luminescence of a Mesomorphic Ionic Liquid Doped with Lanthanide β‐Diketonate Ternary Complexes
L. Puntus (2005)
10.1021/IC051062Z
Primary photoinduced processes in bimetallic dyads with extended aromatic bridges. tetraazatetrapyridopentacene complexes of ruthenium(II) and osmium(II).
C. Chiorboli (2005)
10.1021/JP0360319
Using Three-Pulse Femtosecond Spectroscopy to Probe Ultrafast Triplet Energy Transfer in Zinc meso-Tetraarylporphyrin-Perylene-3,4-dicarboximide Dyads
R. Hayes (2004)
10.1021/IC035334E
Photochromic dithienylethene derivatives containing Ru(II) or Os(II) metal units. Sensitized photocyclization from a triplet state.
Ron T. F. Jukes (2004)
10.1039/B503794H
Platinum(II) 1,10-phenanthroline complexes of acetylides containing redox-active groups.
U. Siemeling (2005)
10.1021/JA052880T
Inter-ligand energy transfer and related emission change in the cyclometalated heteroleptic iridium complex: facile and efficient color tuning over the whole visible range by the ancillary ligand structure.
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10.1039/B502353J
Molecular photosensors of self-assembled monolayers: electron acceptor–photosensitizer dyad on an ITO surface
Kyung-Hee Hyung (2005)
10.1021/JP045637+
Comparison of the photophysical properties of osmium(II) bis(2,2':6',2' '-terpyridine) and the corresponding ethynylated derivative.
A. Benniston (2005)
10.1002/CHEM.200401150
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