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Boryl Substituted Group 13 Metallylenes: Complexes With An Iron Carbonyl Fragment

Deepak Dange, Christian P. Sindlinger, Simon Aldridge, Cameron Jones

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The first examples of boryl substituted aluminylene and gallylene complexes (see picture, DAB = {(C6H3Pri2-2,6)NCH}2) have been prepared by reduction of boryl-group 13 dihalide compounds with K2[Fe(CO)4].