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Anionic Polymerization Of Activated Oxetane And Its Copolymerization With Ethylene Oxide For The Synthesis Of Amphiphilic Block Copolymers

Matthieu Gervais, Antoine Forens, Emmanuel Ibarboure, Stephane Carlotti

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The anionic polymerization of oxetane in toluene was achieved using a combination of tetraoctylammonium bromide and simple triisobutylaluminum. By its copolymerization with ethylene oxide, di- and triblock copolymers were prepared in one and two steps respectively.