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Organocatalytic Atropo- And E/Z-selective Michael Addition Reaction Of Ynones With α-amido Sulfones As Sulfone-type Nucleophile

Nan Zhang, Tingting He, Yidong Liu, Shan Li, Yu Tan, Lei Peng, Dongmei Li, Chunhui Shan, Hailong Yan

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We describe herein the first enantioselective organocatalytic Michael addition reaction of α-amido sulfones to ynones to access axially chiral styrenes.