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Phosphine-free Chiral Metal Catalysts For Highly Effective Asymmetric Catalytic Hydrogenation.

Y. He, Q. Fan
Published 2010 · Chemistry, Medicine

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In addition to the brilliant chiral phosphorus metal catalysts, chiral phosphine-free metal complexes find increasing application as catalysts for asymmetric hydrogenation. In this account, two types of chiral phosphine-free ligands, N-heterocyclic carbene-based C,N-ligands and diamine-based N,N-ligands, in the homogeneous asymmetric hydrogenation of prochiral ketones, imines and quinolines are reviewed.
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