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The Boron–boron Triple Bond? A Thermodynamic And Force Field Based Interpretation Of The N-heterocyclic Carbene (NHC) Stabilization Procedure

R. Köppe, H. Schnöckel

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From thermodynamic and force constant discussion a new description of bonding of B2(NHC)2 (NHC = N-heterocyclic carbene C3N2H2(C6H3Pri2-2,6)2) as NHCBBNHC rather than NHC→BB←NHC is given.