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(PhC(NtBu)2Al)2(SiH2)4 Six-membered Heterocycle: Comparable In Structure To Cyclohexane

Jiancheng Li, Mingdong Zhong, Helena Keil, Hongping Zhu, Regine Herbst-Irmer, Dietmar Stalke, Sriman De, Debasis Koley, Herbert W. Roesky

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A (PhC(NtBu)2Al)2(SiH2)4 centrosymmetric six-membered heterocycle (LAl)2(SiH2)4 (L = PhC(NtBu)2) with chair conformation is prepared by reacting disilylene LSi–SiL with alane AlH3·NEtMe2. It is comparable in structure to cyclohexane containing four Si and two Al atoms as a core.