Copper(i)-polymers And Their Photoluminescence Thermochromism Properties.
Rong-Yan Wang, Xiao Zhang, Jie-Hui Yu, Ji-qing Xu
Published 2019 · Chemistry, Medicine
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Under hydro(solvo)thermal conditions, four organic bidentate bridging N,N'-donor ligands 1,3-bis(2-methylimidazol-1-yl)propane (L1), 4,4'-di(1H-imidazol-1-yl)-1,1'-biphenyl (L2), 1,2-bis(2-methyl-1H-imidazol-1-ylmethyl)benzene (L3) and 5,6,7,8-tetrahydroquinoxaline (L4) were employed to react with CuBr/CuI, generating four 2-D layered copper(i)-polymer coordination polymer materials [Cu2Br2(L1)] 1, [CuI(L2)] 2, [CuI(L3)] 3 and [CuI(L4)0.5] 4. In 1-4, different Cu-X motifs are found: a cubic Cu4Br4 core in 1; a castellated Cu-I single chain in 2; a rhombic Cu2I2 core in 3; and a staircase-like Cu-I double chain in 4. The 2-D layer networks of 1-3 can all be simplified into a simple 44 topology (planar for 1 and 3; wave-like for 2), while the 2-D layer network of 4 has a 63 topology. The photoluminescence behaviors of 1-4 under a UV lamp suggest that 1 and 2 possess fluorescence thermochromism properties. Under the UV lamp, with the decrease in temperature, (i) 1 exhibits a yellow-to-red emission; (ii) 2 exhibits a yellow-to-green emission; (iii) 3 always emits green light; and (iv) 4 never emits light. These are further confirmed by their emission spectra. From 297 K to 77 K, the emission of 1 exhibits a large red shift from 561 nm to 623 nm; the emission of 2 exhibits a large blue shift from 571 nm to 515 nm; only a minor red shift is observed for the emission of 3; and no peaks appear in the emission spectra of 4. The crystal data of 1 and 2 at different temperatures have been collected for revealing the origination of their fluorescence thermochromism properties. Based on the above investigations, the effect of the rigidity/flexibility of the organic ligand on the fluorescence thermochromism properties of copper(i)-polymer coordination polymer materials is discussed. The quantum yields at 297 K and the photoluminescence lifetimes at 297 K and 77 K for 1-3 were also measured for better understanding their photoluminescence properties.
This paper references
Self-assembly of [Cu3I2]- or [CuI]n-based (n = 2, 4, and ∞) coordination polymers from unsymmetrical bis(pyridyl) and in situ ligands: syntheses, structures, and properties
Zhu-Yan Zhang (2014)
White luminescence achieved by a multiple thermochromic emission in a hybrid organic-inorganic compound based on 3-picolylamine and copper(i) iodide.
Francesco Farinella (2016)
Cu(I)-MOF: naked-eye colorimetric sensor for humidity and formaldehyde in single-crystal-to-single-crystal fashion.
Yang Yu (2014)
Interpenetrated Three-Dimensional Copper-Iodine Cluster-Based Framework with Enantiopure Porphyrin-like Templates.
Juan Liu (2016)
An organic-ligand-free thermochromic luminescent cuprous iodide trinuclear cluster: evidence for cluster centered emission and configuration distortion with temperature.
Shi-Li Li (2015)
Light and Heat Dually Responsive Luminescence in Organic Templated CdSO4-type Halogeno(cyano)cuprates with Disorder of Halogenide/Cyanide
Shi-Li Li (2017)
Photoluminescence Properties of Multinuclear Copper(I) Compounds.
Peter C Ford (1999)
Luminescence and Nonlinear Optical Properties in Copper(I) Halide Extended Networks.
Natasha Marie Khatri (2016)
Vapochromic luminescence and flexibility control of porous coordination polymers by substitution of luminescent multinuclear Cu(I) cluster nodes.
Takahiro Yokosuka-shi Hayashi (2015)
Dual luminescence in solid CuI(piperazine): hypothesis of an emissive 1-D delocalized excited state.
Lucia Maini (2015)
A white phosphorescent coordination polymer with Cu2I2 alternating units linked by benzo-18-crown-6.
Fengshou Wu (2014)
Cuprous Iodide Pseudopolymorphs Based on Imidazole Ligand and Their Luminescence Thermochromism
Zhixing Fu (2016)
A short history of SHELX.
George M. Sheldrick (2008)
Post-synthetic monovalent central-metal exchange, specific I2 sensing, and polymerization of a catalytic [3×3] grid of [Cu(II)5Cu(I)4L6]⋅(I)2⋅13 H2O.
Yi Feng Han (2013)
"Click-and-click"--hybridised 1,2,3-triazoles supported Cu(I) coordination polymers for azide-alkyne cycloaddition.
Lu Jiang (2013)
Five Cu(I) and Zn(II) clusters and coordination polymers of 2-pyridyl-1,2,3-triazoles: synthesis, structures and luminescence properties
Shi-Qiang Bai (2015)
An unusual copper(I) halide-based metal-organic framework with a cationic framework exhibiting the release/adsorption of iodine, ion-exchange and luminescent properties.
Bingjing Xin (2013)
Cu(I) Coordination Polymers as the Green Heterogeneous Catalysts for Direct C-H Bonds Activation of Arylalkanes to Ketones in Water with Spatial Confinement Effect.
Xingle Wang (2017)
Aminotroponiminato(chloro)germylene stabilized copper(I) iodide complexes: synthesis and structure.
Dhirendra Singh Yadav (2014)
Dinuclear Cu(I) complexes of pyridyl-diazadiphosphetidines and aminobis(phosphonite) ligands: synthesis, structural studies and antiproliferative activity towards human cervical, colon carcinoma and breast cancer cells.
Aijaz Rashid (2014)
Ligand Coordination Site-Directed Assembly of Copper(I) Iodide Complexes of ((Pyridyl)-1-pyrazolyl)pyridine
Jun-Chi Li (2016)
A porous copper-organic framework with intersecting channels and gas adsorption properties.
Zhenzhen Xue (2017)
Reversible Crystal Transformations and Luminescence Vapochromism by Fast Guest Exchange in Cu(I) Coordination Polymers.
Hyunjin Park (2017)
Polyrotaxane frameworks containing N,N′,N′′-(4,4′,4′′-nitrilotris(4,1-phenylene))triisonicotinamide: structural and luminescent properties
Biing-Chiau Tzeng (2013)
Copper(I) complexes based on five-membered P^N heterocycles: structural diversity linked to exciting luminescence properties.
Daniel M Zink (2013)
Copper(I) coordination polymers of 2,2'-dipyridylamine derivatives: syntheses, structures, and luminescence.
Jia Ni (2012)
A Series of Multifunctional Metal-Organic Frameworks Showing Excellent Luminescent Sensing, Sensitization, and Adsorbent Abilities.
Fei-Yan Yi (2015)
A novel 3-D photoluminescent cuprous chloride polymer based on bifunctional imidazolate/tetrazolate bridges.
Qiuling Tang (2017)
Photochemical and photophysical properties of tetranuclear and hexanuclear clusters of metals with d10 and s2 electronic configurations
Peter C Ford (1993)
Structure, Dynamics, and Photophysics in the Copper(I) Iodide–Tetrahydrothiophene System
Kylie M. Henline (2014)
Two low-dimensional Schiff base copper(I/II) complexes: synthesis, characterization and catalytic activity for degradation of organic dyes
Xu-Jia Hong (2014)
Assembly of photoluminescent [CunIn] (n = 4, 6 and 8) clusters by clickable hybrid [N,S] ligands
Shi-Qiang Bai (2015)
A dual-emitting Cu6-Cu2-Cu6 cluster as a self-calibrated, wide-range luminescent molecular thermometer.
Junhao Wang (2014)
Copper(I) halides: A versatile family in coordination chemistry and crystal engineering
Rong Hua Peng (2010)
Cuprous Halide Complexes of a Variable Length Ligand: Helices, Cluster Chains, and Nets Containing Large Solvated Channels
William James Gee (2013)
Use of the oxime–oximato binding mode to stabilise mixed valence copper iodide polymer networks using dipyridyl ketone oxime ligands
Victoria J. Argyle (2014)
Thermochromic and mechanochromic luminescence umpolung in isostructural metal-organic frameworks based on Cu6I6 clusters.
Mahesh Subhashrao Deshmukh (2015)
Copper(I)-iodide based coordination polymers: bifunctional properties related to thermochromism and PMMA-doped polymer film materials
Yang Song (2015)
Halide impact on emission of mononuclear copper(I) complexes with pyrazolylpyrimidine and triphenylphosphine.
Katerina A. Vinogradova (2014)
Non-Phase-Transition Luminescence Mechanochromism of a Copper(I) Coordination Polymer.
Eunjin Kwon (2017)
Luminescent mixed ligand copper(I) clusters (CuI)n(L)m (L=pyridine, piperidine): thermodynamic control of molecular and supramolecular species☆
Margherita Vitale (2001)
1'-(Diphenylphosphino)-1-cyanoferrocene: a simple ligand with complicated coordination behavior toward copper(I).
Karel Škoch (2014)
Transition metal coordination polymers based on tetrabromoterephthalic and bis(imidazole) ligands: Syntheses, structures, topological analysis and photoluminescence properties
Xiaowei Zhang (2015)
Simultaneous Luminescent Thermochromism, Vapochromism, Solvatochromism, and Mechanochromism in a C3-Symmetric Cubane [Cu4I4P4] Cluster without Cu-Cu Interaction.
Kai Yang (2016)
Tetranuclear Copper(I) Iodide Complexes: A New Class of X-ray Phosphors.
Kaplan Kirakci (2017)
Luminescent Cu4I4-Cu3(Pyrazolate)3 Coordination Frameworks: Postsynthetic Ligand Substitution Leads to Network Displacement and Entanglement.
Shun-Ze Zhan (2017)
Reversible interconversion between luminescent isomeric metal-organic frameworks of [Cu(4)I(4)(DABCO)(2)] (DABCO=1,4-diazabicyclo[2.2.2]octane).
Dario Braga (2010)
A Triazolyl-Pyridine-Supported CuI Dimer: Tunable Luminescence and Fabrication of Composite Fibers.
Shi-Qiang Bai (2015)
New copper(I) iodides with bisimidazole molecules: Synthesis, structural characterization and photoluminescence property
Rong-Yan Wang (2017)
A mechanochemical route toward the rational, systematic, and cost-effective green synthesis of strongly luminescent copper iodide based hybrid phosphors
Wei Liu (2017)
Application of photoelectron spectroscopy to molecular properties. Part 43. Photoelectronic study of the flash vacuum pyrolysis (FVP) of Meldrum's acid derivatives: PE spectra of (alkoxymethylene)- and [(alkylthio)methylene]ketenes
Françoise Chuburu (1991)
Di-pyridyl organic cation directed hybrid cuprous halogenides: syntheses, crystal structures and photochromism and photocatalysis.
Xiao-Wu Lei (2017)
Two heterovalent copper–organic frameworks with multiple secondary building units: high performance for gas adsorption and separation and I2 sorption and release
Shuo Yao (2016)
Metal complexes with bis(2-pyridyl)diselenoethers: structural chemistry and catalysis
Roberta Cargnelutti (2015)
Constructing heterometallic frameworks with highly connected topology based on edge-to-edge hexanuclear lanthanide clusters
Wei-hui Fang (2014)
Photophysical studies in solution of the tetranuclear copper(I) clusters Cu4I4L4 (L = pyridine or substituted pyridine)
Kevin R. Kyle (1991)
Luminescent [Cu₄I₄] aggregates and [Cu₃I₃]-cyclic coordination polymers supported by quinolyl-triazoles.
Shi-Qiang Bai (2015)
Four d10 metal coordination polymers based on bis(2-methyl imidazole) spacers: syntheses, interpenetrating structures and photoluminescence properties
Li-ping Xue (2014)
Syntheses and structures of three heterometallic coordination polymers derived from 4-pyridin-3-yl-benzoic acid
Wei-hui Fang (2014)
Mechanochromic and thermochromic luminescence of a copper iodide cluster.
Sandrine Perruchas (2010)
Solvent‐Dependent Iodoargentate Hybrids: Syntheses, Structural Diversity, Thermochromism, and Photocatalysis
Tanlai Yu (2015)
Capture of volatile iodine by newly prepared and characterized non-porous [CuI]n-based coordination polymers
Abbas Tarassoli (2017)
Synthesis of Halide-Modulated Cuprous(I) Coordination Polymers with Mechanochromic and Photocatalytic Properties.
Lan-Xia Hu (2017)
Two isomeric [Cu4I4] luminophores: solvothermal/mechanochemical syntheses, structures and thermochromic luminescence properties
Shuai Yuan (2014)
Reactant ratio-modulated six new copper(I)–iodide coordination complexes based on diverse [CumIm] aggregates and biimidazole linkers: syntheses, structures and temperature-dependent luminescence properties
Shuai Yuan (2013)
Luminescent MTN-type cluster-organic framework with 2.6 nm cages.
Yao Kang (2012)
3D Inorganic Cuprous Iodide Open-Framework Templated by In Situ N-Methylated 2,4,6-Tri(4-pyridyl)-1,3,5-triazine
Ai-Huan Sun (2017)
Cu3I7 trimer and Cu4I8 tetramer based cuprous iodide polymorphs for efficient photocatalysis and luminescent sensing: unveiling possible hierarchical assembly mechanism.
Shi-Li Li (2014)
Symmetrically Related Construction and Optical Properties of Two Noncentrosymmetric 3D Iodides of d(10) Cation (Cu(+), Ag(+)) Based on the N-Benzylpyridinium and Its Supramolecular Interactions.
Yanrong Qiao (2015)
Stereochemically Dependent Synthesis of Two Cu(I) Cluster-Based Coordination Polymers with Thermochromic Luminescence.
Si Si Zhao (2017)
Synthesis and Crystal Structures of Coordination Complexes Containing Cu2 I2 Units and Their Application in Luminescence and Catalysis.
Huaixia Zhao (2013)
Luminescence thermochromism of two entangled copper-iodide networks with a large temperature-dependent emission shift.
Di Sun (2013)
A multi-metal-cluster MOF with Cu4I4 and Cu6S6 as functional groups exhibiting dual emission with both thermochromic and near-IR character
Xiao-Chen Shan (2013)
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Jianfang Li (2019)
A Chained Iodocuprate(I) and its Photoluminescence Behavior
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