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Directed Nickel-catalyzed 1,2-dialkylation Of Alkenyl Carbonyl Compounds

Joseph Derosa, Vincent A. van der Puyl, Van T. Tran, Mingyu Liu, Keary M. Engle

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A substrate-directed approach to couple alkylzinc nucleophiles, alkyl halide electrophiles, and non-conjugated alkenes under nickel catalysis is described.