Online citations, reference lists, and bibliographies.
Please confirm you are human
(Sign Up for free to never see this)
← Back to Search

Lithium Ferrite (α-LiFe5O8) Nanorod Based Battery-type Asymmetric Supercapacitor With NiO Nanoflakes As The Counter Electrode

J. William, I. M. Babu, G. Muralidharan
Published 2019 · Chemistry

Save to my Library
Download PDF
Analyze on Scholarcy
Over the past few decades, most of the work on electrochemical charge storage devices has been focused on the development of positive electrodes in the field of supercapacitors. Besides, the development of negative electrodes is very rare and also they deliver poor specific capacitance and hence more attention should be paid to the development of the same. The present study deals with the fabrication of a battery-type asymmetric supercapacitor (α-LiFe5O8//NiO) and examination of its electrochemical performance. Herein, a facile and cost-effective route was adopted to prepare α-LiFe5O8 nanorods and they demonstrate battery-type Faradaic behaviour with a Fe3 ↔ Fe0 quasi-conversion reaction in a negative potential window. In a three electrode cell, they exhibit a specific capacity of 999 C g−1 at 2 A g−1. Similarly, the nanoflakes of NiO electrodes exhibit Faradaic behaviour in a positive potential window, which results in an excellent specific capacity of 477 C g−1 at a specific current of 2 A g−1. The fabricated asymmetric supercapacitor device indicates a Faradaic nature of the energy storage process and it provides a specific capacity of 134 C g−1 at a specific current of 4 A g−1. Moreover, the asymmetric cell delivers a specific energy of 30 W h kg−1 at a specific power of 621 W kg−1. These appreciable features of the asymmetric supercapacitor are explained on the basis of the synergy between NiO and α-LiFe5O8.
This paper references
A high-performance pseudocapacitive electrode material for supercapacitors based on the unique NiMoO4/NiO nanoflowers
R. Xu (2019)
A Mesoporous High-Performance Supercapacitor Electrode Based on Polypyrrole Wrapped Iron Oxide Decorated Nanostructured Cobalt Vanadium Oxide Hydrate with Enhanced Electrochemical Capacitance
A. Maitra (2017)
Nanostructured ternary metal chalcogenide-based binder-free electrodes for high energy density asymmetric supercapacitors
Vimal Kumar Mariappan (2019)
Energy efficiency: a critically important but neglected factor in battery research
A. Eftekhari (2017)
Hierarchical shell-core structures of concave spherical NiO nanospines@carbon for high performance supercapacitor electrodes
Panbo Liu (2019)
Solvothermal synthesis of NiWO4 nanostructure and its application as a cathode material for asymmetric supercapacitors
Jinjun Tian (2018)
Structural and CO2 capture analyses of the Li1+xFeO2 (0 ≤ x ≤ 0.3) system: effect of different physicochemical conditions
J. Gómez-García (2016)
Binder-free electro-synthesis of highly ordered nickel oxide nanoparticles and its electrochemical performance
T. Edison (2018)
Exploring Li-ion hopping behavior in zinc ferrite and promoting performance for flexible solid-state supercapacitor
M. Javed (2019)
A general method to fabricate MoO3/C composites and porous C for asymmetric solid-state supercapacitors
Y. Jiang (2019)
Pseudocapacitive oxide materials for high-rate electrochemical energy storage
V. Augustyn (2014)
Sliding-mode and Lyapunov function-based control for battery/supercapacitor hybrid energy storage system used in electric vehicles
Ziyou Song (2017)
Flexible long-chain-linker constructed Ni-based metal-organic frameworks with 1D helical channel and their pseudo-capacitor behavior studies
K. Wang (2018)
Bismuth oxide: a versatile high-capacity electrode material for rechargeable aqueous metal-ion batteries
W. Zuo (2016)
Spongy structured α-Ni(OH)2: Facile and rapid synthesis for supercapattery applications
J. William (2019)
Ni-CeO2 spherical nanostructures for magnetic and electrochemical supercapacitor applications.
R. Murugan (2017)
Correction: Ultrathin porous NiO nanoflake arrays on nickel foam as an advanced electrode for high performance asymmetric supercapacitors
Shuxing Wu (2016)
Asymmetric supercapacitor based on vanadium disulfide nanosheets as a cathode and carbonized iron cations adsorbed onto polyaniline as an anode
M. N. Rantho (2018)
Ni@NiO Nanowires on Nickel Foam Prepared via "Acid Hungry" Strategy: High Supercapacitor Performance and Robust Electrocatalysts for Water Splitting Reaction.
Haohao Sun (2018)
A novel synthesis of Fe7S8@Fe5Ni4S8 flower center/petal hierarchical nanostructure: Application as advance cathode material for high-performance supercapacitors.
M. Zhang (2019)
Refinement of LiFe5O8 crystal structure
A. I. Smolentsev (2008)
Tuning MnO2 to FeOOH replicas with bio-template 3D morphology as electrodes for high performance asymmetric supercapacitors
K. Li (2019)
Supercapacitor studies on NiO nanoflakes synthesized through a microwave route.
S. Vijayakumar (2013)
In Situ Grown Iron Oxides on Carbon Nanofibers as Freestanding Anodes in Aqueous Supercapacitors
R. Pai (2018)
Synthesis of NiO nanospheres with ultrasonic method for supercapacitors
Sun Wanhong (2014)
Designing an asymmetric device based on graphene wrapped yolk–double shell NiGa2S4 hollow microspheres and graphene wrapped FeS2–FeSe2 core–shell cratered spheres with outstanding energy density
Akbar Mohammadi Zardkhoshoui (2019)
Carboxymethyl cellulose aided fabrication of flaky structured mesoporous β-Co(OH)2/C nanocomposite for supercapacitors
I. M. Babu (2018)
Electrochemical Impedance Spectra of Dye-Sensitized Solar Cells: Fundamentals and Spreadsheet Calculation
Subrata K. Sarker (2014)
Carbon decorated octahedral shaped Fe3O4 and α-Fe2O3 magnetic hybrid nanomaterials for next generation supercapacitor applications
T. Arun (2019)
To Be or Not To Be Pseudocapacitive
T. Brousse (2015)
Low temperature synthesis of insertion oxides for lithium batteries
A. Manthiram (1998)
Synthesis of the nanocrystalline α-LiFe5O8 in a solvothermal process
Bin Li (1999)
Controllable synthesis of a NiO hierarchical microspheres/nanofibers composites assembled on nickel foam for supercapacitor
G. Xiaodi (2019)
Fluorinated graphene-supported Nickel-Cobalt-Iron nitride nanoparticles as a promising hybrid electrode for supercapacitor applications
M. Ishaq (2018)
Hybrid crumpled graphene supported Fe-Co binary oxides nanoparticles for aqueous asymmetric supercapacitors
Chongmin Lee (2018)
2D nickel oxide nanosheets with highly porous structure for high performance capacitive energy storage
Z. Li (2018)
An on-line predictive energy management strategy for plug-in hybrid electric vehicles to counter the uncertain prediction of the driving cycle
Zeyu Chen (2017)
Ror2 signaling regulates Golgi structure and transport through IFT20 for tumor invasiveness
M. Nishita (2016)
Asymmetric supercapacitor based on cobalt hydroxide carbonate/GF composite and a carbonized conductive polymer grafted with iron (C-FP)
T. Masikhwa (2018)
Spinel-structured FeCo2O4 mesoporous nanosheets as efficient electrode for supercapacitor applications
S. Mohamed (2017)
Solar-charged pseudocapacitors: Simultaneous conversion and storage of solar energy in ZnO@NiO nanorod arrays
X. Zheng (2019)
Synthesis of hollow NiO nanostructures and their application for supercapacitor electrode
Xiaoshuang Wang (2018)
Ni foam supported NiO nanosheets as high-performance free-standing electrodes for hybrid supercapacitors and Ni–Zn batteries
Q. Chen (2018)
MOF-derived porous NiO nanoparticle architecture for high performance supercapacitors
Y. Han (2017)
Temperature controlled diffusion of hydroxide ions in 1D channels of Ni-MOF-74 for its complete conformal hydrolysis to hierarchical Ni(OH)2 supercapacitor electrodes.
S. Zhang (2019)
Shape-controlled rapid synthesis of magnetic nanoparticles and their morphological dependent magnetic and thermal studies for cancer therapy applications
G. Bharath (2019)
Facile synthesis of NiO nanocubes for photocatalysts and supercapacitor electrodes
Wanting Sun (2019)
Fe3O4 nanospheres in situ decorated graphene as high-performance anode for asymmetric supercapacitor with impressive energy density.
Shuang Sheng (2019)
NiO Nanoparticle Synthesis Using a Triblock Copolymer: Enhanced Magnetization and High Specific Capacitance of Electrodes Prepared from the Powder
S. Chatterjee (2017)
Sonochemical synthesis of a 2D–2D MoSe2/graphene nanohybrid electrode material for asymmetric supercapacitors
Balakrishnan Kirubasankar (2019)
The NiO electrode materials in electrochemical capacitor: A review
J. Zhao (2019)
Nitrogen-doped graphene encapsulated cobalt iron sulfide as an advanced electrode for high-performance asymmetric supercapacitors
Yazan Al Haj (2019)
A Few Atoms Thick Nickel–Cobalt Oxides Mesoporous Nanosheets and Their Arrays on Ni Foam for Supercapacitors with Ultra-Long Cycling Lifespan
H. Chen (2018)
Synthesis of tetrahedral LiFeO2 and its behavior as a cathode in rechargeable lithium batteries.
A. R. Armstrong (2008)
Investigating adaptive-ECMS with velocity forecast ability for hybrid electric vehicles
C. Sun (2017)
Hybrid supercapacitor devices based on MnCo 2 O 4 as the positive electrode and FeMn 2 O 4 as the negative electrode
Sadayappan Nagamuthu (2016)
Low-cost fabrication of amorphous cobalt-iron-boron nanosheets for high-performance asymmetric supercapacitors
Meng Qingzhuo (2019)
Asymmetric Supercapacitor Based on Chemically Coupled Hybrid Material of Fe2O3‐Fe3O4 Heterostructure and Nitrogen‐Doped Reduced Graphene Oxide
S. Mallick (2018)
Preparation of NiO nanoflakes under different calcination temperatures and their supercapacitive and optical properties
Jiangshan Zhao (2017)
Energy Storage in Nanomaterials - Capacitive, Pseudocapacitive, or Battery-like?
Y. Gogotsi (2018)
Phenotypic Characterization of Transgenic Miscanthus sinensis Plants Overexpressing Arabidopsis Phytochrome B
Ok-Jin Hwang (2014)
Amorphous FeOOH nanorods and Co3O4 nanoflakes as binder-free electrodes for high-performance all-solid-state asymmetric supercapacitors
Qingyu Liao (2019)
Appropriate methods for evaluating the efficiency and capacitive behavior of different types of supercapacitors
Ann Laheäär (2015)
Battery charge equalization controller in electric vehicle applications: A review
M. Hoque (2017)
Moderated surface defects of Ni particles encapsulated with NiO nanofibers as supercapacitor with high capacitance and energy density.
Y. Zhang (2017)
Synthesis of Ag/NiO Honeycomb Structured Nanoarrays as the Electrode Material for High Performance Asymmetric Supercapacitor Devices
Sadayappan Nagamuthu (2019)
Hierarchical mesoporous Cox Ni1−xO as advanced electrode material for hybrid supercapacitors
K. K. Purushothaman (2017)
Nanostructured nickel oxide ultrafine nanoparticles: Synthesis, characterization, and supercapacitive behavior
A. Barani (2014)
Size-dependent capacitance of NiO nanoparticles synthesized from Ni-based coordination polymer precursors with different crystallinity
K. Wang (2015)
Passivation and Hydrogen Evolution Studies on Iron in Alkali Solutions
M. Jayalakshmi (1994)
Zirconium Alloys for Orthopaedic and Dental Applications
A. Mehjabeen (2018)
Two dimensional famatinite sheets decorated on reduced graphene oxide: A novel electrode for high performance supercapacitors
Vimal Kumar Mariappan (2019)
Microwave assisted fabrication of l-Arginine capped α-Ni(OH)2 microstructures as an electrode material for high performance hybrid supercapacitors
J. William (2019)
MOF–derived hollow double–shelled NiO nanospheres for high–performance supercapacitors
M. Wu (2018)
An investigation of ultrathin nickel-iron layered double hydroxide nanosheets grown on nickel foam for high-performance supercapacitor electrodes
Y. Lu (2017)
Urchin-like NiCo2O4 hollow microspheres and FeSe2 micro-snowflakes for flexible solid-state asymmetric supercapacitors
C. Ji (2017)
Multivalent metal ion hybrid capacitors: a review with a focus on zinc-ion hybrid capacitors
Liubing Dong (2019)
Novel mesoporous electrode materials for symmetric, asymmetric and hybrid supercapacitors.
Jayesh Cherusseri (2019)
Fast ultrasound-assisted synthesis of Li 2 MnSiO 4 nanoparticles for a lithium-ion battery
Chahwan Hwang (2015)

This paper is referenced by
Semantic Scholar Logo Some data provided by SemanticScholar