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Lithium Ferrite (α-LiFe5O8) Nanorod Based Battery-type Asymmetric Supercapacitor With NiO Nanoflakes As The Counter Electrode

J. William, I. M. Babu, G. Muralidharan
Published 2019 · Chemistry

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Over the past few decades, most of the work on electrochemical charge storage devices has been focused on the development of positive electrodes in the field of supercapacitors. Besides, the development of negative electrodes is very rare and also they deliver poor specific capacitance and hence more attention should be paid to the development of the same. The present study deals with the fabrication of a battery-type asymmetric supercapacitor (α-LiFe5O8//NiO) and examination of its electrochemical performance. Herein, a facile and cost-effective route was adopted to prepare α-LiFe5O8 nanorods and they demonstrate battery-type Faradaic behaviour with a Fe3 ↔ Fe0 quasi-conversion reaction in a negative potential window. In a three electrode cell, they exhibit a specific capacity of 999 C g−1 at 2 A g−1. Similarly, the nanoflakes of NiO electrodes exhibit Faradaic behaviour in a positive potential window, which results in an excellent specific capacity of 477 C g−1 at a specific current of 2 A g−1. The fabricated asymmetric supercapacitor device indicates a Faradaic nature of the energy storage process and it provides a specific capacity of 134 C g−1 at a specific current of 4 A g−1. Moreover, the asymmetric cell delivers a specific energy of 30 W h kg−1 at a specific power of 621 W kg−1. These appreciable features of the asymmetric supercapacitor are explained on the basis of the synergy between NiO and α-LiFe5O8.
This paper references
10.1016/J.APSUSC.2018.08.172
A high-performance pseudocapacitive electrode material for supercapacitors based on the unique NiMoO4/NiO nanoflowers
R. Xu (2019)
10.1021/ACS.IECR.6B04449
A Mesoporous High-Performance Supercapacitor Electrode Based on Polypyrrole Wrapped Iron Oxide Decorated Nanostructured Cobalt Vanadium Oxide Hydrate with Enhanced Electrochemical Capacitance
A. Maitra (2017)
10.1016/J.NANOEN.2018.12.031
Nanostructured ternary metal chalcogenide-based binder-free electrodes for high energy density asymmetric supercapacitors
Vimal Kumar Mariappan (2019)
10.1039/C7SE00350A
Energy efficiency: a critically important but neglected factor in battery research
A. Eftekhari (2017)
10.1016/J.ELECTACTA.2018.10.112
Hierarchical shell-core structures of concave spherical NiO nanospines@carbon for high performance supercapacitor electrodes
Panbo Liu (2019)
10.1039/C8RA09128E
Solvothermal synthesis of NiWO4 nanostructure and its application as a cathode material for asymmetric supercapacitors
Jinjun Tian (2018)
10.1039/C6RA23329E
Structural and CO2 capture analyses of the Li1+xFeO2 (0 ≤ x ≤ 0.3) system: effect of different physicochemical conditions
J. Gómez-García (2016)
10.1016/J.ELECTACTA.2018.07.101
Binder-free electro-synthesis of highly ordered nickel oxide nanoparticles and its electrochemical performance
T. Edison (2018)
10.1016/J.ELECTACTA.2018.10.202
Exploring Li-ion hopping behavior in zinc ferrite and promoting performance for flexible solid-state supercapacitor
M. Javed (2019)
10.1039/C8RA10232E
A general method to fabricate MoO3/C composites and porous C for asymmetric solid-state supercapacitors
Y. Jiang (2019)
10.1039/C3EE44164D
Pseudocapacitive oxide materials for high-rate electrochemical energy storage
V. Augustyn (2014)
10.1016/J.ENERGY.2017.01.098
Sliding-mode and Lyapunov function-based control for battery/supercapacitor hybrid energy storage system used in electric vehicles
Ziyou Song (2017)
10.1016/J.JPOWSOUR.2017.11.087
Flexible long-chain-linker constructed Ni-based metal-organic frameworks with 1D helical channel and their pseudo-capacitor behavior studies
K. Wang (2018)
10.1039/C6EE01871H
Bismuth oxide: a versatile high-capacity electrode material for rechargeable aqueous metal-ion batteries
W. Zuo (2016)
10.1016/J.MATLET.2018.11.136
Spongy structured α-Ni(OH)2: Facile and rapid synthesis for supercapattery applications
J. William (2019)
10.1039/c6cp08281e
Ni-CeO2 spherical nanostructures for magnetic and electrochemical supercapacitor applications.
R. Murugan (2017)
10.1039/C6TA02005D
Correction: Ultrathin porous NiO nanoflake arrays on nickel foam as an advanced electrode for high performance asymmetric supercapacitors
Shuxing Wu (2016)
10.1016/J.ELECTACTA.2017.11.074
Asymmetric supercapacitor based on vanadium disulfide nanosheets as a cathode and carbonized iron cations adsorbed onto polyaniline as an anode
M. N. Rantho (2018)
10.1002/smll.201800294
Ni@NiO Nanowires on Nickel Foam Prepared via "Acid Hungry" Strategy: High Supercapacitor Performance and Robust Electrocatalysts for Water Splitting Reaction.
Haohao Sun (2018)
10.1016/j.jcis.2018.10.093
A novel synthesis of Fe7S8@Fe5Ni4S8 flower center/petal hierarchical nanostructure: Application as advance cathode material for high-performance supercapacitors.
M. Zhang (2019)
10.1007/S10947-008-0163-8
Refinement of LiFe5O8 crystal structure
A. I. Smolentsev (2008)
10.1016/J.CEJ.2019.03.190
Tuning MnO2 to FeOOH replicas with bio-template 3D morphology as electrodes for high performance asymmetric supercapacitors
K. Li (2019)
10.1021/am400012h
Supercapacitor studies on NiO nanoflakes synthesized through a microwave route.
S. Vijayakumar (2013)
10.1002/ADEM.201701116
In Situ Grown Iron Oxides on Carbon Nanofibers as Freestanding Anodes in Aqueous Supercapacitors
R. Pai (2018)
10.1016/J.MSSP.2013.09.002
Synthesis of NiO nanospheres with ultrasonic method for supercapacitors
Sun Wanhong (2014)
10.1039/C9TA00532C
Designing an asymmetric device based on graphene wrapped yolk–double shell NiGa2S4 hollow microspheres and graphene wrapped FeS2–FeSe2 core–shell cratered spheres with outstanding energy density
Akbar Mohammadi Zardkhoshoui (2019)
10.1007/s10854-018-0482-2
Carboxymethyl cellulose aided fabrication of flaky structured mesoporous β-Co(OH)2/C nanocomposite for supercapacitors
I. M. Babu (2018)
10.1155/2014/851705
Electrochemical Impedance Spectra of Dye-Sensitized Solar Cells: Fundamentals and Spreadsheet Calculation
Subrata K. Sarker (2014)
10.1016/J.APSUSC.2019.04.177
Carbon decorated octahedral shaped Fe3O4 and α-Fe2O3 magnetic hybrid nanomaterials for next generation supercapacitor applications
T. Arun (2019)
10.1149/2.0201505JES
To Be or Not To Be Pseudocapacitive
T. Brousse (2015)
10.1021/CM980241U
Low temperature synthesis of insertion oxides for lithium batteries
A. Manthiram (1998)
10.1016/S0167-2738(98)00556-6
Synthesis of the nanocrystalline α-LiFe5O8 in a solvothermal process
Bin Li (1999)
10.1016/J.MATLET.2018.12.117
Controllable synthesis of a NiO hierarchical microspheres/nanofibers composites assembled on nickel foam for supercapacitor
G. Xiaodi (2019)
10.1016/J.ELECTACTA.2018.06.087
Fluorinated graphene-supported Nickel-Cobalt-Iron nitride nanoparticles as a promising hybrid electrode for supercapacitor applications
M. Ishaq (2018)
10.1016/J.APSUSC.2018.04.147
Hybrid crumpled graphene supported Fe-Co binary oxides nanoparticles for aqueous asymmetric supercapacitors
Chongmin Lee (2018)
10.1088/1361-6463/AA9E44
2D nickel oxide nanosheets with highly porous structure for high performance capacitive energy storage
Z. Li (2018)
10.1016/J.APENERGY.2016.01.071
An on-line predictive energy management strategy for plug-in hybrid electric vehicles to counter the uncertain prediction of the driving cycle
Zeyu Chen (2017)
10.1038/s41598-016-0028-x
Ror2 signaling regulates Golgi structure and transport through IFT20 for tumor invasiveness
M. Nishita (2016)
10.1016/J.JALLCOM.2018.08.026
Asymmetric supercapacitor based on cobalt hydroxide carbonate/GF composite and a carbonized conductive polymer grafted with iron (C-FP)
T. Masikhwa (2018)
10.1016/J.MICROMESO.2017.05.035
Spinel-structured FeCo2O4 mesoporous nanosheets as efficient electrode for supercapacitor applications
S. Mohamed (2017)
10.1016/J.JALLCOM.2018.12.100
Solar-charged pseudocapacitors: Simultaneous conversion and storage of solar energy in ZnO@NiO nanorod arrays
X. Zheng (2019)
10.1007/s11581-018-2771-4
Synthesis of hollow NiO nanostructures and their application for supercapacitor electrode
Xiaoshuang Wang (2018)
10.1039/C8TA07574C
Ni foam supported NiO nanosheets as high-performance free-standing electrodes for hybrid supercapacitors and Ni–Zn batteries
Q. Chen (2018)
10.1016/J.MATLET.2016.09.051
MOF-derived porous NiO nanoparticle architecture for high performance supercapacitors
Y. Han (2017)
10.1039/C9NR02555C
Temperature controlled diffusion of hydroxide ions in 1D channels of Ni-MOF-74 for its complete conformal hydrolysis to hierarchical Ni(OH)2 supercapacitor electrodes.
S. Zhang (2019)
10.1088/2053-1591/AB0A85
Shape-controlled rapid synthesis of magnetic nanoparticles and their morphological dependent magnetic and thermal studies for cancer therapy applications
G. Bharath (2019)
10.1016/J.JALLCOM.2018.09.185
Facile synthesis of NiO nanocubes for photocatalysts and supercapacitor electrodes
Wanting Sun (2019)
10.1016/j.jcis.2018.10.060
Fe3O4 nanospheres in situ decorated graphene as high-performance anode for asymmetric supercapacitor with impressive energy density.
Shuang Sheng (2019)
10.1021/acsomega.6b00384
NiO Nanoparticle Synthesis Using a Triblock Copolymer: Enhanced Magnetization and High Specific Capacitance of Electrodes Prepared from the Powder
S. Chatterjee (2017)
10.1039/C8SE00446C
Sonochemical synthesis of a 2D–2D MoSe2/graphene nanohybrid electrode material for asymmetric supercapacitors
Balakrishnan Kirubasankar (2019)
10.1016/J.MSSP.2019.02.024
The NiO electrode materials in electrochemical capacitor: A review
J. Zhao (2019)
10.1039/C8TA12396A
Nitrogen-doped graphene encapsulated cobalt iron sulfide as an advanced electrode for high-performance asymmetric supercapacitors
Yazan Al Haj (2019)
10.1149/2.0241803JES
A Few Atoms Thick Nickel–Cobalt Oxides Mesoporous Nanosheets and Their Arrays on Ni Foam for Supercapacitors with Ultra-Long Cycling Lifespan
H. Chen (2018)
10.1021/ja077651g
Synthesis of tetrahedral LiFeO2 and its behavior as a cathode in rechargeable lithium batteries.
A. R. Armstrong (2008)
10.1016/J.APENERGY.2016.02.026
Investigating adaptive-ECMS with velocity forecast ability for hybrid electric vehicles
C. Sun (2017)
10.1016/J.APSUSC.2016.08.072
Hybrid supercapacitor devices based on MnCo 2 O 4 as the positive electrode and FeMn 2 O 4 as the negative electrode
Sadayappan Nagamuthu (2016)
10.1016/J.ELECTACTA.2018.11.067
Low-cost fabrication of amorphous cobalt-iron-boron nanosheets for high-performance asymmetric supercapacitors
Meng Qingzhuo (2019)
10.1002/CELC.201800521
Asymmetric Supercapacitor Based on Chemically Coupled Hybrid Material of Fe2O3‐Fe3O4 Heterostructure and Nitrogen‐Doped Reduced Graphene Oxide
S. Mallick (2018)
10.1016/J.APSUSC.2016.09.128
Preparation of NiO nanoflakes under different calcination temperatures and their supercapacitive and optical properties
Jiangshan Zhao (2017)
10.1021/acsnano.8b01914
Energy Storage in Nanomaterials - Capacitive, Pseudocapacitive, or Battery-like?
Y. Gogotsi (2018)
10.1155/2014/501016
Phenotypic Characterization of Transgenic Miscanthus sinensis Plants Overexpressing Arabidopsis Phytochrome B
Ok-Jin Hwang (2014)
10.1039/C8CE01639A
Amorphous FeOOH nanorods and Co3O4 nanoflakes as binder-free electrodes for high-performance all-solid-state asymmetric supercapacitors
Qingyu Liao (2019)
10.1016/J.ELECOM.2015.07.022
Appropriate methods for evaluating the efficiency and capacitive behavior of different types of supercapacitors
Ann Laheäär (2015)
10.1016/J.RSER.2016.11.126
Battery charge equalization controller in electric vehicle applications: A review
M. Hoque (2017)
10.1016/j.jcis.2017.04.022
Moderated surface defects of Ni particles encapsulated with NiO nanofibers as supercapacitor with high capacitance and energy density.
Y. Zhang (2017)
10.1038/s41598-019-41446-0
Synthesis of Ag/NiO Honeycomb Structured Nanoarrays as the Electrode Material for High Performance Asymmetric Supercapacitor Devices
Sadayappan Nagamuthu (2019)
10.1016/J.IJHYDENE.2017.09.115
Hierarchical mesoporous Cox Ni1−xO as advanced electrode material for hybrid supercapacitors
K. K. Purushothaman (2017)
10.1016/J.MSSP.2014.02.027
Nanostructured nickel oxide ultrafine nanoparticles: Synthesis, characterization, and supercapacitive behavior
A. Barani (2014)
10.1016/J.JALLCOM.2015.01.252
Size-dependent capacitance of NiO nanoparticles synthesized from Ni-based coordination polymer precursors with different crystallinity
K. Wang (2015)
10.1515/CORRREV.1994.12.3-4.305
Passivation and Hydrogen Evolution Studies on Iron in Alkali Solutions
M. Jayalakshmi (1994)
10.1002/ADEM.201800207
Zirconium Alloys for Orthopaedic and Dental Applications
A. Mehjabeen (2018)
10.1016/J.JPOWSOUR.2019.05.056
Two dimensional famatinite sheets decorated on reduced graphene oxide: A novel electrode for high performance supercapacitors
Vimal Kumar Mariappan (2019)
10.1016/J.MATCHEMPHYS.2018.12.044
Microwave assisted fabrication of l-Arginine capped α-Ni(OH)2 microstructures as an electrode material for high performance hybrid supercapacitors
J. William (2019)
10.1016/J.JALLCOM.2017.10.171
MOF–derived hollow double–shelled NiO nanospheres for high–performance supercapacitors
M. Wu (2018)
10.1016/J.JALLCOM.2017.04.197
An investigation of ultrathin nickel-iron layered double hydroxide nanosheets grown on nickel foam for high-performance supercapacitor electrodes
Y. Lu (2017)
10.1039/C6TA11001K
Urchin-like NiCo2O4 hollow microspheres and FeSe2 micro-snowflakes for flexible solid-state asymmetric supercapacitors
C. Ji (2017)
10.1039/C9TA02678A
Multivalent metal ion hybrid capacitors: a review with a focus on zinc-ion hybrid capacitors
Liubing Dong (2019)
10.1088/1361-6528/ab0685
Novel mesoporous electrode materials for symmetric, asymmetric and hybrid supercapacitors.
Jayesh Cherusseri (2019)
10.1016/J.JPOWSOUR.2015.06.107
Fast ultrasound-assisted synthesis of Li 2 MnSiO 4 nanoparticles for a lithium-ion battery
Chahwan Hwang (2015)



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