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Enhanced CH3OH Selectivity In CO2 Hydrogenation Using Cu-based Catalysts Generated Via SOMC From GaIII Single-sites

Erwin Lam, Gina Noh, Ka Wing Chan, Kim Larmier, Dmitry Lebedev, Keith Searles, Patrick Wolf, Olga V. Safonova, Christophe Copéret

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CuGax alloy nanoparticles supported on SiO2 can be obtained by surface organometallic chemistry. This catalyst is active and selective for the hydrogenation of CO2 to CH3OH, related to the formation of an optimal interface between Cu and GaIIIOx.