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Nature And Strength Of Intrinsic Cation–anion Interactions Of 1-alkyl-3-methylimidazolium Hexafluorophosphate Clusters

H. A. Roy, M. T. Rodgers

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The nature of the intrinsic binding interactions and energetics of binding in (Cnmim:PF6) ion pairs and [2Cnmim:PF6]+ clusters for n = 2–8 are elucidated via synergistic TCID and computational approaches.