Online citations, reference lists, and bibliographies.
← Back to Search

Origins Of Saccharide-dependent Hydration At Aluminate, Silicate, And Aluminosilicate Surfaces

B. J. Smith, A. Rawal, G. Funkhouser, L. Roberts, V. Gupta, J. Israelachvili, B. Chmelka
Published 2011 · Chemistry, Medicine

Save to my Library
Download PDF
Analyze on Scholarcy
Sugar molecules adsorbed at hydrated inorganic oxide surfaces occur ubiquitously in nature and in technologically important materials and processes, including marine biomineralization, cement hydration, corrosion inhibition, bioadhesion, and bone resorption. Among these examples, surprisingly diverse hydration behaviors are observed for oxides in the presence of saccharides with closely related compositions and structures. Glucose, sucrose, and maltodextrin, for example, exhibit significant differences in their adsorption selectivities and alkaline reaction properties on hydrating aluminate, silicate, and aluminosilicate surfaces that are shown to be due to the molecular architectures of the saccharides. Solid-state 1H, 13C, 29Si, and 27Al nuclear magnetic resonance (NMR) spectroscopy measurements, including at very high magnetic fields (19 T), distinguish and quantify the different molecular species, their chemical transformations, and their site-specific adsorption on different aluminate and silicate moieties. Two-dimensional NMR results establish nonselective adsorption of glucose degradation products containing carboxylic acids on both hydrated silicates and aluminates. In contrast, sucrose adsorbs intact at hydrated silicate sites and selectively at anhydrous, but not hydrated, aluminate moieties. Quantitative surface force measurements establish that sucrose adsorbs strongly as multilayers on hydrated aluminosilicate surfaces. The molecular structures and physicochemical properties of the saccharides and their degradation species correlate well with their adsorption behaviors. The results explain the dramatically different effects that small amounts of different types of sugars have on the rates at which aluminate, silicate, and aluminosilicate species hydrate, with important implications for diverse materials and applications.
This paper references
Molecular silicate and aluminate species in anhydrous and hydrated cements.
A. Rawal (2010)
In situ observation of the internal structure and composition of biomineralized Emiliania huxleyi calcite by solid-state NMR Spectroscopy.
Ronen Gertman (2008)
Early hydration and setting of oil well cement
J. Zhang (2010)
Nanostructure of calcium silicate hydrates in cements.
L. Skinner (2010)
The crystal structure of sucrose
C. Beevers (1952)
The calcium silicate hydrates
I. Richardson (2008)
Carboxylated molecules regulate magnesium content of amorphous calcium carbonates during calcification
D. Wang (2009)
Biochemical evolution. I. Polymerization On internal, organophilic silica surfaces of dealuminated zeolites and feldspars.
J. Smith (1998)
Natural products as corrosion inhibitor for metals in corrosive media — A review
P. B. Raja (2008)
Characterization of calcium aluminate phases in cements by 27 Al MAS NMR spectroscopy
J Skibsted (1993)
Liquid-phase catalytic processing of biomass-derived oxygenated hydrocarbons to fuels and chemicals.
J. Chheda (2007)
A realistic molecular model of cement hydrates
R. Pellenq (2009)
Characterization of calcium aluminate phases in cements by aluminum-27 MAS NMR spectroscopy
J. Skibsted (1993)
Composition and density of nanoscale calcium-silicate-hydrate in cement.
A. Allen (2007)
The Silicate-Mediated Formose Reaction: Bottom-Up Synthesis of Sugar Silicates
J. Lambert (2010)
Cement Chemistry (Academic
Hfw Taylor (1990)
Theory of the Stability of Lyophobic Colloids
J. Butler (1948)
Characterization of calcium aluminate phases in cements by 27Al MAS NMR spectroscopy
J Skibsted (1993)
Modelling one‐ and two‐dimensional solid‐state NMR spectra
D. Massiot (2002)
Observation of a Mesostructure in Calcium Silicate Hydrate Gels of Portland Cement.
Xu (1996)
Alkaline degradation of glucose: effect of initial concentration of reactants
B. Yang (1996)
A (2008) In situ observation of the internal structure and composition of biomineralized Emiliania huxleyi calcite by solid-state NMR spectroscopy
R Gertman (2008)
Protein (19)F NMR in Escherichia coli.
Conggang Li (2010)
Alkaline degradation of glucose
By Yang (1996)
Strong reversible Fe3+-mediated bridging between dopa-containing protein films in water
Hongbo Zeng (2010)
Sterns F (1952) The crystal structure of sucrose
C A Beevers

This paper is referenced by
Comparative Assessment of Effectiveness of Calcium Silicate Dispersions Produced Using Sucrose and Lactose as Components of Composite Cement Binder
Evgeny A. Shoshin (2021)
Physicochemical properties of silicate-calcium micro-filler obtained by thermolysis of calcium hydrosilicates stabilized with sucrose
E. Shoshin (2018)
Impact of Temperature Rising Inhibitor on hydration kinetics of cement paste and its mechanism
H. Zhang (2018)
Advances in characterizing and understanding the microstructure of cementitious materials
P. Monteiro (2019)
Nanophase Formation of Portland Cement in the Presence of Disaccharides
Y. Ivaschenko (2016)
Sorbitol Minimizes Calcium Carbonate Scale Generation While Maintaining the Disinfection Effect of Heated Scallop-Shell Powder for Fresh Produce.
Yuri Nomoto (2018)
Comprehensive multiphase NMR spectroscopy: basic experimental approaches to differentiate phases in heterogeneous samples.
D. Courtier-Murias (2012)
In-situ reaction of the very early hydration of C3A-gypsum-sucrose system by Micro-Raman spectroscopy
S. Martínez-Ramírez (2016)
Influence of maltodextrin retarder on the hydration kinetics and mechanical properties of Portland cement
L. Lei (2020)
Influence of bound water layer on the viscosity of oxide nanopowder suspensions
Simge Çınar (2015)
Effect of a liquid-type temperature rise inhibitor on cement hydration
Yu Yan (2021)
Applications of high-resolution 1H solid-state NMR.
S. Brown (2012)
Effect of a novel starch-based temperature rise inhibitor on cement hydration and microstructure development
Yu Yan (2020)
Inhibition mechanisms of steel slag on the early-age hydration of cement
S. Zhuang (2021)
Reactions and surface interactions of saccharides in cement slurries.
Benjamin J Smith (2012)
Chemistry of chemical admixtures
Giulia Gelardi (2016)
Study of the Hydrosilicate Phases Formation Process of Portland Cement with Disaccharide Additives
E. Shoshin (2020)
Hydration and rheology control of concrete for digital fabrication: Potential admixtures and cement chemistry
Delphine Marchon (2018)
The effect of pressure on tricalcium silicate hydration at different temperatures and in the presence of retarding additives
A. Jupe (2012)
Impact of chemical admixtures on cement hydration
Delphine Marchon (2016)
Advances in understanding ye'elimite-rich cements
Mohsen Ben Haha (2019)
Robust production of sustainable concrete through the use of admixtures and in-transit concrete management systems
E. Bérodier (2018)
Retarders' effects on some properties of class G cement cured at 80°C
T. Pyatina (2014)
Local water diffusivity as a molecular probe of surface hydrophilicity
Jinsuk Song (2014)
Measurement and modeling needs for microstructure and reactivity of next-generation concrete binders
J. Bullard (2017)
Influences of Dilute Organic Adsorbates on the Hydration of Low-Surface-Area Silicates.
Rahul P. Sangodkar (2015)
A force field for tricalcium aluminate to characterize surface properties, initial hydration, and organically modified interfaces in atomic resolution.
R. K. Mishra (2014)
Understanding calcium carbonate crystallization processes and the effects of saccharide surface interactions
K. Brune (2016)
Recent Advances in NMR Studies of Carbohydrates
S. Buda (2016)
Rheological behavior of oxide nanopowder suspensions
Simge Çınar (2013)
Role of Potassium Permanganate-Based Solutions in Controlling the Galvanic Corrosion at Al-Co Interface
U. Lagudu (2013)
Structure-forming processes of cement composites, modified by sucrose additions
T. Shepelenko (2016)
See more
Semantic Scholar Logo Some data provided by SemanticScholar