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Controlling The Reproducibility Of Coulomb Blockade Phenomena For Gold Nanoparticles On An Organic Monolayer/silicon System.
L. Caillard, S. Sattayaporn, A-F Lamic-Humblot, S. Casale, P. Campbell, Y. Chabal, O. Pluchery
Published 2015 · Materials Science, Medicine
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Two types of highly ordered organic layers were prepared on silicon modified with an amine termination for binding gold nanoparticles (AuNPs). These two grafted organic monolayers (GOMs), consisting of alkyl chains with seven or 11 carbon atoms, were grafted on oxide-free Si(111) surfaces as tunnel barriers between the silicon electrode and the AuNPs. Three kinds of colloidal AuNPs were prepared by reducing HAuCl4 with three different reactants: citrate (Turkevich synthesis, diameter ∼16 nm), ascorbic acid (diameter ∼9 nm), or NaBH4 (Natan synthesis, diameter ∼7 nm). Scanning tunnel spectroscopy (STS) was performed in a UHV STM at 40 K, and Coulomb blockade behaviour was observed. The reproducibility of the Coulomb behavior was analysed as a function of several chemical and physical parameters: size, crystallinity of the AuNPs, influence of surrounding surfactant molecules, and quality of the GOM/Si interface (degree of oxidation after the full processing). Samples were characterized with scanning tunneling microscope, STS, atomic force microscope, Fourier transform infrared spectroscopy, x-ray photoelectron spectroscopy (XPS), and high resolution transmission electronic microscope. We show that the reproducibility in observing Coulomb behavior can be as high as ∼80% with the Natan synthesis of AuNPs and GOMs with short alkyl chains.
This paper references
Modifying electronic properties at the silicon-molecule interface using atomic tethers
C. Hacker (2010)
Toward metal-organic insulator-semiconductor solar cells, based on molecular monolayer self-assembly on n-Si
Rotem Har-lavan (2009)
Entropy production moment closures and effective transport coefficients
T. Christen (2014)
Controlled nucleation for the regulation of the particle size in monodisperse gold solutions
G. Frens (1973)
Observation of Coulomb staircase and negative differential resistance at room temperature by scanning tunneling microscopy
P. Radojkovic (1996)
Size control of gold nanocrystals in citrate reduction: the third role of citrate.
Xiaohui Ji (2007)
Alkyl Monolayers on Silicon Prepared from 1-Alkenes and Hydrogen-Terminated Silicon
M. R. Linford (1995)
Optimizing non-radiative energy transfer in hybrid colloidal-nanocrystal/silicon structures by controlled nanopillar architectures for future photovoltaic cells
O. Seitz (2012)
Single-electron logic device based on the binary decision diagram
N. Asahi (1997)
Biomolecule induced nanoparticle aggregation: effect of particle size on interparticle coupling.
S. Basu (2007)
Transformations of gold nanoparticles investigated using variable temperature high-resolution transmission electron microscopy.
N.P. Young (2010)
Spectroscopic evidence for nonradiative energy transfer between colloidal CdSe/ZnS nanocrystals and functionalized silicon substrates
H. Nguyen (2011)
CMOS-compatible fabrication of room-temperature single-electron devices.
Vishva Ray (2008)
1-octadecene monolayers on Si(111) hydrogen-terminated surfaces: Effect of substrate doping
C. Miramond (2004)
Ideal hydrogen termination of the Si (111) surface
G. Higashi (1990)
pH-Dependent gold nanoparticle self-organization on functionalized Si/SiO2 surfaces
S. Diegoli (2006)
Synthesis and Characterization of Crystalline and Amorphous Palladium Nanoparticles
W. Lu (2003)
Gold nanoparticles on oxide - free silicon - molecule interface for single electron phenomena
M. T. Nimmo (2013)
Formation, characterization, and chemistry of undecanoic acid-terminated silicon surfaces: patterning and immobilization of DNA.
R. Voicu (2004)
One-step selective chemistry for silicon-on-insulator sensor geometries.
O. Seitz (2011)
Scanning tunneling spectroscopy of gold nanoparticles: Influences of volatile organic vapors and particle core dimensions
L. Xu (2009)
Pluchery, O., Gold nanoparticles on oxide-free silicon-molecule interface for single electron phenomena
L. Caillard (2013)
Reduced Transition Metal Colloids: A Novel Family of Reusable Catalysts?
A. Roucoux (2003)
Energy-filtered cold electron transport at room temperature
Pradeep Bhadrachalam (2014)
A multiple-valued logic and memory with combined single-electron and metal-oxide-semiconductor transistors
H. Inokawa (2003)
Single-electron devices and their applications
K. Likharev (1999)
Well-defined carboxyl-terminated alkyl monolayers grafted onto H-Si(111): packing density from a combined AFM and quantitative IR study.
A. Faucheux (2006)
Mesoscopic phenomena in Au nanocrystal floating gate memory structure
K. Chan (2009)
Barrier height distribution and dipolar relaxation in metal-insulator-semiconductor junctions with molecular insulator: Ageing effects
A. Fadjie-Djomkam (2012)
Copper-metal deposition on self assembled monolayer for making top contacts in molecular electronic devices.
O. Seitz (2009)
Hybrid CMOS/Nanoelectronic Circuits: Opportunities and Challenges
K. Likharev (2008)
On the application potential of gold nanoparticles in nanoelectronics and biomedicine
Melanie Homberger (2010)
Gold nanoparticle-pentacene memory-transistors
Christophe Novembre (2008)
Preparation of colloidal gold.
C. Oliver (2010)
Si ejection and regrowth during the initial stages of Si(001) oxidation
D. Cahill (1992)
The adsorption of a substituted benzene, the ethynyl-trifluoro-toluene on Si(100)-2 × 1
F. Herzog (2011)
Wet chemical surface functionalization of oxide-free silicon
P. Thissen (2012)
The fabrication of single-electron transistors using dielectrophoretic trapping of individual gold nanoparticles.
S. Khondaker (2010)
Two-dimensional arrays of colloidal gold particles : A flexible approach to macroscopic metal surfaces
K. C. Grabar (1996)
Hybrids of organic molecules and flat, oxide-free silicon: high-density monolayers, electronic properties, and functionalization.
Y. Li (2012)
Carrier transport and sensitivity issues in heterojunction with intrinsic thin layer solar cells on N-type crystalline silicon: A computer simulation study
M. Rahmouni (2010)
Turkevich method for gold nanoparticle synthesis revisited.
J. Kimling (2006)
Catalyst-free functionalization for versatile modification of nonoxidized silicon structures.
S. R. Puniredd (2011)
Stabilization of gold nanoparticles by 6-mercaptopurine monolayers. Effects of the solvent properties.
Alfonso J. Viudez (2006)
Titanium silicide islands on atomically clean Si"100…: Identifying single electron tunneling effects
J. Tedesco (2010)
Surface charge influence on the surface plasmon absorbance of electroactive thiol-protected gold nanoparticles.
Xiaohu Qu (2004)
Transmission infrared spectroscopy of methyl- and ethyl-terminated silicon(111) surfaces.
L. Webb (2006)
A study of the nucleation and growth processes in the synthesis of colloidal gold
J. Turkevich (1951)
Controlled Deposition of Gold Nanoparticles on Well-Defined Organic Monolayer Grafted on Silicon Surfaces
D. Aureau (2010)
Size effect on the melting temperature of gold particles
Pa Buffat (1976)
Room temperature single electron transistor with two-dimensional array of Au–SiO2 core–shell nanoparticles
Y. Yang (2005)
Probing the intrinsic electrical properties of thin organic layers/semiconductor interfaces using an atomic-layer-deposited Al2O3 protective layer
Weina Peng (2012)
Room-temperature single-electron charging detected by electrostatic force microscopy.
A. Tekiel (2013)
Formation of single-electron-transistors using self-assembly of nanoparticle chains
Li-Chu Tsai (2010)
Visible to near-infrared sensitization of silicon substrates via energy transfer from proximal nanocrystals: further insights for hybrid photovoltaics.
Michael T. Nimmo (2013)
High-Resolution Synchrotron Photoemission Studies of the Electronic Structure and Thermal Stability of CH3- and C2H5-Functionalized Si(111) Surfaces
B. Jaeckel (2007)
Simulating hybrid circuits of single-electron transistors and field-effect transistors
G. Lientschnig (2003)
Anodic grafting of organic groups on the silicon surface
A. Teyssot (2002)
C. Joachim (2005)
Coulomb blockade and discrete energy levels in Au nanoparticles
D. Davidović (1998)
Sensing the charge state of single gold nanoparticles via work function measurements.
Yingjie Zhang (2015)
The birth of molecular electronics
J. Cuevas (2010)
Molecules on si: electronics with chemistry.
A. Vilan (2010)
In situ monitoring of the electronic properties and the pH stability of grafted Si(111)
D. Aureau (2010)
Adsorption of phenylacetylene on Si(100)-2 x 1: kinetics and structure of the adlayer.
O. Pluchery (2006)
Charge transport in nanoparticle assemblies.
Amir Zabet-Khosousi (2008)
Kinetics of Electrochemical Derivatization of the Silicon Surface by Grignards
S. Fellah (2002)
Gold nanoparticles on oxide-free silicon-molecule interface for single electron transport.
L. Caillard (2013)
Importance of monolayer quality for interpreting current transport through organic molecules: alkyls on oxide-free Si.
O. Seitz (2006)
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Ammonia modification of oxide-free Si(111) surfaces
T. P. Chopra (2016)
Static and dynamic electronic characterization of organic monolayers grafted on a silicon surface.
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