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Elasticity Of Compressed Emulsions.

Mason, Bibette, Weitz
Published 1995 · Materials Science, Medicine

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The elastic shear modulus of monodisperse emulsions is shown to exhibit a universal dependence on droplet volume fraction f when scaled by the Laplace pressure of the droplets, increasing as fs f2f c d, where fc 0.635, the value of random close packing of solid spheres. Surprisingly the osmotic pressure required to compress the emulsions to increase f is nearly the same as the shear modulus over a large range of volume fraction, while the bulk osmotic modulus differs significantly. Models based on the structural disorder of the emulsions are discussed to account for these data.
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