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An Electrochemical Coulomb Staircase: Detection Of Single Electron-Transfer Events At Nanometer Electrodes

F. Fan, A. J. Bard
Published 1997 · Chemistry

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The current-potential curve at a 2.8-nanometer-radius electrode immersed in a solution containing micromolar concentrations of a redox couple, [(trimethylammonio)methyl] ferrocene (Cp 2 FeTMA + )/Cp 2 FeTMA 2+ , shows discrete steps (a coulomb staircase) representing single electron-transfer events. Discrete potential steps are also found in the current-time curve as the electrode potential relaxes back to equilibrium after a coulostatic potential step.
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