Online citations, reference lists, and bibliographies.
← Back to Search

A Conducting Polymer Film Stronger Than Aluminum

G. Shi, S. Jin, G. Xue, C. Li
Published 1995 · Materials Science, Medicine

Save to my Library
Download PDF
Analyze on Scholarcy
Share
Polythiophene (Pth) was electrochemically deposited onto stainless steel substrate from freshly distilled boron fluoride-ethyl ether containing 10 millimoles of thiophene per liter. The free-standing Pth film obtained at an applied potential of 1.3 volts (versus Ag/AgCl) had a conductivity of 48.7 siemens per centimeter. Its tensile strength (1200 to 1300 kilograms per square centimeter) was greater than that of aluminium (1000 to 1100 kilograms per square centimeter). This Pth film behaves like a metal sheet and can be easily cut into various structures with a knife or a pair of scissors.
This paper references
10.1016/0022-0728(88)80208-0
Polymerisation of terthiophene at controlled doping level
R. M. Eales (1988)
10.1080/00268949008036043
Optimisation of the electrosynthesis of polythiophene and polyselenophene films
C. Chorro (1990)
10.1016/0379-6779(85)90031-1
Polypyrrole for use in information storage
W. Meyer (1985)
10.1016/0379-6779(87)90911-8
Polyaniline: Electrochemistry and application to rechargeable batteries
A. MacDiarmid (1987)
10.1149/1.2054906
Cracking and Spoiling of Oxide Scale from 304 Stainless Steel at High Temperatures
Y. Zhang (1994)
10.1149/1.2113587
Photoelectrochromic Properties of Polypyrrole‐Coated Silicon Electrodes
H. Yoneyama (1985)
Chem
A. Tsumura (1986)
10.1016/0022-0728(86)90264-0
A study of the conditions for the electrodeposition of polythiophen in acetonitrile
A. Downard (1986)
10.1021/J100201A001
Electrochemical and electric properties of vacuum-deposited poly(arylene)s: electrochemical activity, diode, and electroluminescence
T. Yamamoto (1992)
10.1103/PHYSREVLETT.50.1498
AsF5-Doped Polyparaphenylene: Evidence for Polaron and Bipolaron Formation
G. Crecelius (1983)
10.1021/MA00049A014
Conducting polymer blends : polypyrrole and poly(vinyl methyl ketone)
H. Wang (1992)
10.1016/0379-6779(89)90583-3
Polyaniline: Structural analysis and application for battery
Nakajima Tadashi (1989)
10.1016/0379-6779(88)90258-5
A study of the electropolymerization of thiophene
K. Tanaka (1988)
10.1021/J100236A010
Effect of dopant on the physicochemical and electrical properties of organic conducting polymers
G. Tourillon (1983)
This work was supported by the research foundation of the national key laboratory of coordination chemistry of Nanjing University
10.1021/JA00178A004
Potential dependence of the conductivity of highly oxidized polythiophenes, polypyrroles, and polyaniline: Finite windows of high conductivity
D. Ofer (1990)
10.1021/J100378A066
Electrochemically deposited polythiophene. 1. Ohmic drop compensation and the polythiophene paradox
M. Gratzl (1990)
10.1016/0022-0728(82)90015-8
New electrochemically generated organic conducting polymers
G. Tourillon (1982)
Soc
P. J. Nigrey (1979)
Petrissans
C Chorro (1990)
10.1016/S0022-0728(84)80199-0
Electrochemical doping of polythiophene in aqueous medium: Electrical properties and stability
G. Tourillon (1984)
10.1126/science.259.5097.957
Electrochemical Processing of Conducting Polymer Fibers
Shulong Li (1993)
10.1021/JA00464A012
Models for copper-containing proteins: structure and properties of novel five-coordinate copper(I) complexes.
R. R. Gagne (1977)
10.1021/J100254A028
Resistance of polyaniline films as a function of electrochemical potential and the fabrication of polyaniline-based microelectronic devices
E. Paul (1985)
10.1016/0379-6779(89)90531-6
The polythiophene paradox
B. Krische (1989)



This paper is referenced by
10.1016/J.POLYMER.2009.08.039
Synthesis and application of conducting graft copolymer with viable processability
Youyi Xia (2009)
10.1016/S1388-2481(99)00109-5
LOW POTENTIAL ELECTROPOLYMERIZATION OF THIOPHENE AT A COPPER OXIDE ELECTRODE
X. Wang (1999)
10.1016/J.ELECTACTA.2008.03.049
Electrosyntheses of free-standing and highly conducting polyselenophene films in an ionic liquid
B. Dong (2008)
10.1016/J.ELECTACTA.2013.10.021
Solubility controlled electropolymerisation and study of the impact of regioregularity on the spectroelectrochemical properties of thin films of poly(3-octylthiophenes)
T. Jarosz (2014)
10.1016/J.MATERRESBULL.2012.11.092
Enhancement of the efficiency of dye-sensitized solar cell with multi-wall carbon nanotubes/polypyrrole composite counter electrodes prepared by electrophoresis/electrochemical polymerization
Jun Luo (2013)
10.1002/PI.2321
Electrochemical polymerization of phenanthrene in mixed electrolytes of boron trifluoride diethyl etherate and concentrated sulfuric acid
Weiqiang Zhou (2008)
10.1002/POLA.21572
Electrosyntheses of high‐quality freestanding poly(fluorene‐co‐3‐methylthiophene) films with tunable fluorescence properties
Z. Wei (2006)
10.1016/S0040-6090(02)01118-5
Raman spectroscopic studies on the structural changes of electrosynthesized polythiophene films during the heating and cooling processes
Feng'en Chen (2003)
10.1021/ACSMACROLETT.5B00937
Electropolymerized Polythiophenes Bearing Pendant Nitroxide Radicals
Fei Li (2016)
10.1016/J.POLYMER.2006.10.027
Electrochemical polymerisation of thiophene derivative induced by Lewis acid: Electrosynthesis of poly[(R)-(−)-2-(3′-thienyl)ethyl-(3′,5″-dinitrobenzoyl)-α-phenylglycinate]
A. Ribeiro (2006)
10.1039/C3RA42786B
Electrochemical investigation of free-standing polypyrrole–silver nanocomposite films: a substrate free electrode material for supercapacitors
Ashutosh Kumar Singh (2013)
10.1016/S0040-6090(98)00957-2
A study of electrochemical copolymerization of 3-butylthiophene and 3-bromothiophene
L. Zhou (1998)
10.1080/00945710009351774
Preparation, Spectroscopy and Electrochemistry of New Heteropolynuclear Complexes of Tetraaza[14]Annulene Derivatives
W. Zhang (2000)
10.1039/C6RA27538A
Highly oriented lamellar polyaniline films via electrochemical polymerization and post-growth annealing
Suna Fan (2017)
10.1016/S0379-6779(99)00010-7
An investigation of the electropolymerization of terthiophene in boron fluoride–ethyl ether
Donghui Zhang (1999)
10.1002/chem.201803246
C3-C3' and C6-C6' Oxidative Couplings of Carbazoles.
M. Li (2019)
10.1016/J.JELECHEM.2012.10.033
Multielectrochromic copolymers of 3,4-ethylenedioxythiophene and naphthalene prepared via electropolymerization in boron trifluoride diethyl etherate
Tao Yijie (2013)
10.1016/S0379-6779(97)80065-3
Synthesis of free-standing poly(3,4-ethylenedioxythiophene) conducting polymer films on a pilot scale
H. Yamato (1996)
Preparation and Characterization of Polyaniline (PANI)-Platinum Nanocomposite
Kumar Neeraj (2015)
10.1016/S0032-3861(97)00323-6
Crystalline polythiophene film prepared by electrochemical polymerization of thiophene at a nickel electrode
C. Li (1997)
10.1016/S0022-0728(01)00632-5
Low potential electrochemical polymerization of 3-chlorothiophene in mixed electrolytes of boron trifluoride diethyl etherate and trifluoroacetic acid
J. Xu (2001)
10.1039/B417446A
Synthesis of a carboxyl-containing conducting oligomer and non-covalent sidewall functionalization of single-walled carbon nanotubes
X. Wu (2005)
10.1023/A:1023953018024
Electrochemical fabrication of polythiophene film coated metallic nanowire arrays
J. Zhang (2003)
10.1016/J.EURPOLYMJ.2005.02.027
Electrosyntheses of freestanding poly (3-(4-fluorophenyl)thiophene) films in boron trifluoride diethyl etherate
L. Shen (2005)
10.1002/CJOC.201100567
Soluble and Green-light-emitting Oligo(9-fluorenylideneacetic acid): Electrosynthesis and Characterization
Bao-yang Lu (2012)
10.1016/J.EURPOLYMJ.2005.10.014
Low potential electrosyntheses of free-standing polyfluorene films in boron trifluoride diethyl etherate
J. Xu (2006)
10.1016/J.MATLET.2010.10.087
Ammonia gas sensor based on PPy/ZnSnO3 nanocomposites
P. Song (2011)
10.1002/APP.36670
Novel redox-active polycarbazole-functionalized polycatechol network films produced by controlled electropolymerization
Yao Huang (2012)
10.1016/J.ELECTACTA.2005.04.043
Electrochemical fabrication of neuron-type networks based on crystalline oligopyrene nanosheets
G. Lu (2005)
10.1021/ACS.MACROMOL.5B01821
Thiophene-Based Microporous Polymer Networks via Chemical or Electrochemical Oxidative Coupling
Alex Palma-Cando (2015)
10.1039/d0sc05061j
Interfacial growth of free-standing PANI films: toward high-performance all-polymer supercapacitors
F. Zhong (2021)
10.1016/J.MATCHEMPHYS.2014.04.037
Doping behaviour of electrochemically generated model bithiophene meta-substituted star shaped oligomer
P. Ledwon (2014)
See more
Semantic Scholar Logo Some data provided by SemanticScholar