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Reactions Of Oxygen And Sulphur Anions With Oxazolidine And Thiazolidine Derivatives Of 2-mesyloxymethylglyceraldehyde Acetonide

George Just, Bong Young Chung, Sunggak Kim, Gerald Rosebery, Phillip Rossy

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Reactions of the oxazolidine (2) and thiazolidine (3) derivatives of 2-mesyloxymethylglyceraldehyde acetonide with oxygen and sulphur anions are described. Whereas oxazolidine formation does not protect the aldehyde function against nucleophilic attack, the thiazolidine group is completely inert to these nucleophiles.