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Towards The Synthesis Of Substituted Porphyrins By A Pyridyl Group Bearing A Reactive Functionality

Maya El Ojaimi, Benoit Habermeyer, Claude P. Gros, Jean-Michel Barbe

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Pyridyl-substituted porphyrins bearing a reactive functionality were prepared via Suzuki cross-coupling reactions and resulted in very good yields. These compounds are precursors of new porphyrin architectures able to coordinate two metals: one in the porphyrin core and the second around the pyridyl moiety. During the coupling reactions, a higher reactivity of a chloro picolyl group was evidenced compared to a bromo function on the same reacting molecule.