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Electrochemical Properties Of Electropolymerized Poly(1-pyrenamine) Films

N. Oyama, Kazuhiko Hirabayashi, T. Ohsaka
Published 1986 · Chemistry

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The electropolymerization of 1-pyrenamine (PA) in an acetonitrile solution led to the polymeric film formation on electrode surfaces. The chemical, spectroscopic, electrical and electrochemical characterization of the resulting poly(1-pyrenamine) (PPA) films was carried out. The number-average molecular weight of the PPA film, measured by gel permeation chromatography, was 1.8×103, corresponding to the degree of the polymerization of ca. 8. The PPA films were polymer-anion composites which contained ca. 0.3 anions (e.g., BF4−) per repeating aromatic unit, which is considered to be composed of three PA molecules. The oxidized form of the PPA film displayed the ESR response. The g factor was 2.0082 and the concentration of radical in the PPA film was determined to be 4.8×1019 e−g−1. The conductivities of the PPA films in the dry state at 300 K were in the range 10−11–10−10 S cm−1. The PPA film was electroactive in an aqueous solution as well as in a non-aqueous solution. The cyclic voltammetric responses de...
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