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Electric Conduction Properties Of Self-assembled Monolayer Films Of Ru Complexes With Disulfide/Phosphonate Anchors In A Au―(Molecular Ensemble)―(Au Nanoparticle) Junction
K. Terada, K. Kobayashi, Jiro Hikita, M. Haga
Published 2009 · Chemistry
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Electric conduction properties of SAM films of Ru complexes with disulfide or phosphonate anchors have been measured by Au-nanoparticle-assisted conducting probe atomic force microscopy. The I―V curves of these films were nonlinear, and the resistivities depend on the headgroups and the layered structure in ways that can be explained by the contact resistance and the insulating effect of the Zn―phosphonate interlayer in metal― molecule―metal junctions. Asymmetry in these films causes a rectification effect on the I―V response.
This paper references
Length dependence of charge transport in nanoscopic molecular junctions incorporating a series of rigid thiol-terminated norbornylogs.
Jeremy M. Beebe (2005)
Synthesis and structural characterization of a homologous series of divalent-metal phosphonates, MII(O3PR)•H2O and MII(HO3PR)2
Guang Cao (1988)
Characterization of conductance under finite bias for a self-assembled monolayer coated Au quantized point contact
T. Zheng (2006)
Electron transport properties of helical peptide dithiol at a molecular level: Scanning tunneling microscope study
K. Kitagawa (2006)
Light-powered electrical switch based on cargo-lifting azobenzene monolayers.
Violetta Ferri (2008)
Molecular conductance switch-on of single ruthenium complex molecules.
Kyoungja Seo (2008)
Molecular Transport Junctions: Clearing Mists
S. Lindsay (2007)
Contact chemistry and single-molecule conductance: a comparison of phosphines, methyl sulfides, and amines.
Y. S. Park (2007)
Electronic transport through ruthenium-based redox-active molecules in metal-molecule-metal nanogap junctions.
A. K. Mahapatro (2008)
Variability of conductance in molecular junctions.
J. Ulrich (2006)
Prospects and problems of single molecule information devices
Y. Wada (2000)
Synthesis and Proton-Coupled Electron-Transfer Reaction of Self-Assembled Monolayers of a Ruthenium(II) Complex Containing Tridentate 2,6-Bis(benzimidazol-2-yl)pyridine on a Gold Surface: Comparison of Acid/Base Chemistry with Bulk Solution Chemistry
M. Haga (2000)
Growth and characterization of metal(II) alkanebisphosphonate multilayer thin films on gold surfaces
H. C. Yang (1993)
Charge Transport and Scaling in Molecular Wires
A. Blum (2004)
Contact resistance in metal-molecule-metal junctions based on aliphatic SAMs: effects of surface linker and metal work function.
Jeremy M. Beebe (2002)
Electron Transport Properties of a Carotene Molecule in a Metal−(Single Molecule)−Metal Junction
Ganesh K. Ramachandran (2003)
Novel fabrication technologies of planar nano-gap electrodes for single molecule evaluation
Ken Tsutsui (2007)
Conductance of single 1,4-disubstituted benzene molecules anchored to Pt electrodes
M. Kiguchi (2007)
Probing charge transport of ruthenium-complex-based molecular wires at the single-molecule level.
K. Liu (2008)
Electron Transport in Molecular Wire Junctions
A. Nitzan (2003)
ENERGY LEVEL ALIGNMENT AND INTERFACIAL ELECTRONIC STRUCTURES AT ORGANIC/METAL AND ORGANIC/ORGANIC INTERFACES
H. Ishii (1999)
Single-molecule devices as scaffolding for multicomponent nanostructure assembly.
Xuefeng Guo (2007)
Azobenzenes as light-controlled molecular electronic switches in nanoscale metal-molecule-metal junctions.
J. Mativetsky (2008)
Fabrication and functions of surface nanomaterials based on multilayered or nanoarrayed assembly of metal complexes
M. Haga (2007)
Comparison of Electronic Transport Measurements on Organic Molecules
Adi Salomon (2003)
A new generation of metal string complexes: structure, magnetism, spectroscopy, theoretical analysis, and single molecular conductance of an unusual mixed-valence linear [Ni5]8+ complex.
I. P. Liu (2007)
Currents through single molecular junction of Au/hexanedithiolate/Au measured by repeated formation of break junction in STM under UHV: effects of conformational change in an alkylene chain from gauche to trans and binding sites of thiolates on gold.
M. Fujihira (2006)
Effect of anchoring groups on single-molecule conductance: comparative study of thiol-, amine-, and carboxylic-acid-terminated molecules.
F. Chen (2006)
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K. Hanson (2012)
Simultaneous bridge-localized and mixed-valence character in diruthenium radical cations featuring diethynylaromatic bridging ligands.
M. Fox (2011)
Click Chemistry and Nitrogen‐Containing Heterocycles Formed in Surface Functionalization Reactions
Y. Chen (2019)
Multimolecular assemblies on high surface area metal oxides and their role in interfacial energy and electron transfer.
J. Wang (2018)
Surface junction effects on the electron conduction of molecular wires.
Tomochika Kurita (2010)
Increasing the Open-Circuit Voltage of Dye-Sensitized Solar Cells via Metal-Ion Coordination.
Omotola O. Ogunsolu (2017)
Photophysical characterization of a chromophore/water oxidation catalyst containing a layer-by-layer assembly on nanocrystalline TiO2 using ultrafast spectroscopy.
Stephanie E. Bettis (2014)
Energy and Electron Transfer Cascade in Self-Assembled Bilayer Dye-Sensitized Solar Cells.
Omotola O. Ogunsolu (2016)
Light Harvesting and Charge Separation in a π-Conjugated Antenna Polymer Bound to TiO2
Gyu Leem (2014)
Elucidating the Energy- and Electron-Transfer Dynamics of Photon Upconversion in Self-Assembled Bilayers
T. Dilbeck (2017)
Phosphonate-Derivatized Porphyrins for Photoelectrochemical Applications.
A. Nayak (2016)
Modulating Electron Transfer Dynamics at Dye–Semiconductor Interfaces via Self-Assembled Bilayers
J. Wang (2015)
Photophysical Characterization of Chromophore/water Oxidation Catalyst Containing Layer-by-layer Assembly on Nanocrystalline TiO
Stephanie E. Bettis (2014)
Metal ion mediated electron transfer at dye-semiconductor interfaces.
J. Wang (2017)
Metal ion linked multilayers on mesoporous substrates: Energy/electron transfer, photon upconversion, and more
Alex J. Robb (2020)
Photon upconversion and photocurrent generation via self-assembly at organic-inorganic interfaces.
S. Hill (2015)
Self-Assembled Bilayers on Nanocrystalline Metal Oxides: Exploring the Non-Innocent Nature of the Linking Ions.
J. Wang (2017)
Recent advances in the application triplet–triplet annihilation-based photon upconversion systems to solar technologies
J. Pedrini (2017)
Synthesis and photophysical characterization of porphyrin and porphyrin–Ru(II) polypyridyl chromophore–catalyst assemblies on mesoporous metal oxides
A. Nayak (2014)
Integrated Photon Upconversion Solar Cell via Molecular Self-Assembled Bilayers
S. Hill (2016)
Mono- and dinuclear osmium N,N'-di- and tetraphenylbipyridyls and extended bipyridyls. Synthesis, structure and electrochemistry.
Miguel A Esteruelas (2013)
Harnessing Molecular Photon Upconversion in a Solar Cell at Sub-solar Irradiance: Role of the Redox Mediator.
S. Hill (2017)
Harnessing molecular photon upconversion at sub-solar irradiance using dual sensitized self-assembled trilayers
T. Dilbeck (2017)
Examining the role of acceptor molecule structure in self-assembled bilayers: surface loading, stability, energy transfer, and upconverted emission.
Y. Zhou (2018)