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Gels Obtained By Colloidal Self-Assembly Of Amphiphilic Molecules

Paula Malo de Molina, M. Gradzielski
Published 2017 · Materials Science, Medicine

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Gelation in water-based systems can be achieved in many different ways. This review focusses on ways that are based on self-assembly, i.e., a bottom-up approach. Self-assembly naturally requires amphiphilic molecules and accordingly the systems described here are based on surfactants and to some extent also on amphiphilic copolymers. In this review we are interested in cases of low and moderate concentrations of amphiphilic material employed to form hydrogels. Self-assembly allows for various approaches to achieve gelation. One of them is via increasing the effective volume fraction by encapsulating solvent, as in vesicles. Vesicles can be constructed in various morphologies and the different cases are discussed here. However, also the formation of very elongated worm-like micelles can lead to gelation, provided the structural relaxation times of these systems is long enough. Alternatively, one may employ amphiphilic copolymers of hydrophobically modified water soluble polymers that allow for network formation in solution by self-assembly due to having several hydrophobic modifications per polymer. Finally, one may combine such polymers with surfactant self-assemblies and thereby produce interconnected hybrid network systems with corresponding gel-like properties. As seen here there is a number of conceptually different approaches to achieve gelation by self-assembly and they may even become combined for further variation of the properties. These different approaches are described in this review to yield a comprehensive overview regarding the options for achieving gel formation by self-assembly.
This paper references
10.1103/PHYSREVE.76.041505
Polymer-induced transient networks in water-in-oil microemulsions studied by small-angle x-ray and dynamic light scattering.
T. Blochowicz (2007)
10.1088/0953-8984/2/33/001
REVIEW ARTICLE: Statics and dynamics of worm-like surfactant micelles
M. Cates (1990)
10.1021/acs.langmuir.5b00817
Phase Behavior of Nonionic Microemulsions with Multi-end-capped Polymers and Its Relation to the Mesoscopic Structure.
Paula Malo de Molina (2015)
10.1021/J100180A086
Viscoelastic micellar solutions: microscopy and rheology
T. Clausen (1992)
10.1021/LA960512K
Vesicle and Cell Networks: Interconnecting Cells by Synthetic Polymers
W. Meier (1996)
10.1039/B817586A
Temperature and redox responsive hydrogels from ABA triblock copolymers prepared by RAFT polymerization
A. Vogt (2009)
10.1039/c1cc11428j
Thermo-switchable surfactant gel.
Z. Chu (2011)
10.1021/LA00013A013
Interaction of ABA block copolymers with ionic surfactants in aqueous solution
E. Hecht (1994)
10.1021/la802323x
Linear-to-branched micelles transition: a rheometry and diffusing wave spectroscopy (DWS) study.
C. Oelschlaeger (2009)
10.1021/BM034118U
Synthesis of biocompatible, stimuli-responsive, physical gels based on ABA triblock copolymers.
Yinghua Ma (2003)
10.1021/la303673a
Structure and dynamics of networks in mixtures of hydrophobically modified telechelic multiarm polymers and oil in water microemulsions.
Paula Malo de Molina (2012)
10.1021/la901189k
Origins of the viscosity peak in wormlike micellar solutions. 1. Mixed catanionic surfactants. A cryo-transmission electron microscopy study.
L. Ziserman (2009)
10.1021/MA0000677
End-Capped Associative Polymer Chains between Nanospheres: Attractions in Ideal Solutions
S. Bhatia (2000)
10.1021/LA9712395
Interactions between Nonionic Surfactant Micelles Introduced by a Telechelic Polymer. A Small Angle Neutron Scattering Study
J. Appell (1998)
10.1021/LA048194+
Vesicle--biopolymer gels: networks of surfactant vesicles connected by associating biopolymers.
J. Lee (2005)
10.1039/c5sm00677e
pH-Tunable wormlike micelles based on an ultra-long-chain "pseudo" gemini surfactant.
Y. Feng (2015)
10.1088/1742-5468/2006/05/P05005
Bridging interactions due to telechelic linkers balanced by screened Coulombic repulsions
G. Porte (2006)
10.1021/MA001772I
Shear Thickening in Aqueous Solutions of Hydrocarbon End-Capped Poly(ethylene oxide)
S. X. Ma (2001)
10.1039/C3SM27698H
Complexes of oppositely charged polyelectrolytes and surfactants – recent developments in the field of biologically derived polyelectrolytes
Leonardo Chiappisi (2013)
10.1021/ACS.MACROMOL.6B00959
Self-Diffusion of Associating Star-Shaped Polymers
Shengchang Tang (2016)
Synthesis and Characterization of Star-Shaped PLLA−PEO Block Copolymers with Temperature-Sensitive Sol−Gel Transition Behavior. Macromolecules
S. Y. Park (2001)
10.1016/J.JCIS.2005.03.040
A novel viscoelastic system from a cationic surfactant and a hydrophobic counterion.
R. Abdel-Rahem (2005)
10.1140/epje/e2006-00010-y
The immunity of polymer-microemulsion networks
Guy Hed (2006)
10.1021/MA800623D
Asymmetric End-Capped Poly(ethylene oxide). Synthesis and Rheological Behavior in Aqueous Solution
Chantal Rufier (2008)
10.1016/0927-7757(96)03557-1
Interactions between modified hydroxyethyl cellulose (HEC) and surfactants
U. Kästner (1996)
10.1122/1.550391
The rheology of solutions of associating polymers: Comparison of experimental behavior with transient network theory
T. Annable (1993)
10.1016/S1359-0294(97)80088-X
Associative polymers in aqueous solution
M. Winnik (1997)
10.1039/B517840A
Yield stress and thixotropy: on the difficulty of measuring yield stresses in practice.
P. Moller (2006)
The Aqueous Phase Behavior of Surfactants
R. Laughlin (1994)
10.1073/pnas.1015862108
pH-induced metal-ligand cross-links inspired by mussel yield self-healing polymer networks with near-covalent elastic moduli
Niels Holten-Andersen (2011)
10.1007/s00396-013-3036-4
Multiple-stimulus-responsive hydrogels of cationic surfactants and azoic salt mixtures
D. Wang (2013)
10.1002/anie.201403192
Activation energies control the macroscopic properties of physically cross-linked materials.
Eric A. Appel (2014)
10.1016/J.JCIS.2006.09.023
Novel viscoelastic systems from cationic surfactants and hydrophobic counter-ions: influence of surfactant chain length.
R. Abdel-Rahem (2007)
10.1021/JA021298R
Strings of vesicles: flow behavior in an unusual type of aqueous gel.
F. Menger (2003)
10.1021/la803304z
Nonlinear rheology of surfactant wormlike micelles bridged by telechelic polymers.
H. Tabuteau (2009)
10.1039/FD9950100319
Gels from surfactant solutions with densely packed multilamellar vesicles.
H. Hoffmann (1995)
10.1021/LA000317C
Percolation in a Model Transient Network: Rheology and Dynamic Light Scattering†
E. Michel (2000)
New liposome gels by self organization of vesicles and intelligent polymers
K. Dice (2002)
10.1016/0370-1573(80)90041-1
Surfactant-water liquid crystal phases
G. Tiddy (1980)
10.1021/MA010789D
Synthesis and Characterization of Star-Shaped PLLA-PEO Block Copolymers with Temperature-Sensitive Sol-Gel Transition Behavior
S. Y. Park (2001)
10.1039/C2PY20126G
One-step RAFT synthesis of well-defined amphiphilic star polymers and their self-assembly in aqueous solution
C. Herfurth (2012)
10.1051/JP2:1993106
Preparation of monodisperse multilayer vesicles of controlled size and high encapsulation ratio.
O. Diat (1993)
10.1021/JP990980D
Swollen Micelles Plus Hydrophobically Modified Hydrosoluble Polymers in Aqueous Solutions: Decoration versus Bridging. A Small Angle Neutron Scattering Study
M. Filali (1999)
10.1063/1.1747424
Statistical Mechanics of Swelling of Network Structures
P. J. Flory (1950)
10.1039/F29767201525
Theory of self-assembly of hydrocarbon amphiphiles into micelles and bilayers
J. Israelachvili (1976)
10.1016/J.ADDR.2006.09.020
Thermo- and pH-responsive polymers in drug delivery.
D. Schmaljohann (2006)
10.1039/c2cs35264h
Supramolecular polymeric hydrogels.
E. Appel (2012)
10.1021/JP0028913
Vesicle Gel Formed by a Self-Organization Process
M. Gradzielski (2000)
10.1134/S1061933X14050111
Polyelectrolyte-surfactant association—from fundamentals to applications
B. Lindman (2014)
10.1021/LA000168Y
Effect of Surfactant on the Viscoelastic Behavior of Semidilute Solutions of Multisticker Associating Polyacrylamides
‡. E. Jiménez-Regalado (2000)
10.1007/BF02657771
A comparison of block copolymer surfactant gels
I. R. Schmolka (1991)
10.1007/1-4020-3689-2_20
Rheology of Wormlike Micelles: Equilibrium Properties and Shear Banding Transitions
J. Berret (2006)
10.1021/LA063148Q
Influence of ionic charges on the bilayers of lamellar phases.
Aihua Zou (2007)
10.1021/LA049783I
Network formation of catanionic vesicles and oppositely charged polyelectrolytes. Effect of polymer charge density and hydrophobic modification.
F. Antunes (2004)
10.1002/ANIE.200600324
A new class of biochemically degradable, stimulus-responsive triblock copolymer gelators.
Chengming Li (2006)
10.1021/LA7020353
SANS study of polymer-linked droplets.
S. Maccarrone (2007)
10.1021/LA00021A028
Synthesis, Characterization, and Solution Rheology of Model Hydrophobically-Modified, Water-Soluble Ethoxylated Urethanes
D. J. Lundberg (1994)
10.1021/MA048968T
Structure and Size of Spherical Micelles of Telechelic Polymers
Xiao-xia Meng (2005)
10.1103/PHYSREVLETT.81.5584
Associating Polymers: From ``Flowers'' to Transient Networks
Y. Serero (1998)
10.1021/MA021076D
Association of Adhesive Spheres Formed by Hydrophobically End-Capped PEO. 1. Influence of the Presence of Single End-Capped PEO
Fabrice Laflèche (2003)
10.1021/JP963913H
Novel Gel Phase: A Cubic Phase of Densely Packed Monodisperse, Unilamellar Vesicles
M. Gradzielski (1997)
10.1021/MA990215X
Micellar Solutions of Associative Triblock Copolymers: The Relationship between Structure and Rheology
Q. Pham (1999)
10.1021/MA0013049
Dynamics of Entangled Solutions of Associating Polymers
M. Rubinstein (2001)
10.1122/1.1645517
General nonlinear rheological behavior of associative polymers
L. Pellens (2004)
10.1122/1.1339245
Nonlinear rheology of telechelic polymer networks
J. Berret (2001)
10.1051/JP4:1993107
Hydrophobically cross-linked micellar solutions : microstructure and properties of the solutions
M. Gradzielski (1993)
10.1021/MA0621167
Structure of a New Type of Transient Network: Entangled Wormlike Micelles Bridged by Telechelic Polymers
L. Ramos (2007)
10.1021/MA951174H
Aggregation of hydrophobically end-capped poly(ethylene oxide) in aqueous solutions. Fluorescence and light-scattering studies
E. Alami (1996)
10.1021/LA962054L
Phase Behavior, Microstructure, and Dynamics in a Nonionic Microemulsion on Addition of Hydrophobically End-Capped Poly(ethylene oxide)
H. Bagger-Jörgensen (1997)
10.1007/bf00665638
Microemulsion elastomers
W. Meier (1996)
Associating Polymers: From “Flowers
Y. Séréro (1998)
10.1039/B601435F
pH-Tunable rheological properties of a telechelic cationic polyelectrolyte reversible hydrogel.
F. Bossard (2006)
10.3891/ACTA.CHEM.SCAND.22-3209
Some isotropic mesophases in systems containing amphiphilic components
K. Fontell (1968)
10.1038/nature09963
Optically healable supramolecular polymers
Mark Burnworth (2011)
10.1103/PHYSREVLETT.91.015901
Entropic phase separation in polymer-microemulsion networks.
A. Zilman (2003)
10.1016/J.COCIS.2007.10.006
Recent developments in the characterisation of microemulsions
M. Gradzielski (2008)
10.1002/MACP.200600393
Synthesis and Characterisation of Organogels from ABA Triblock Copolymers
S. Monge (2007)
Surfactant-water liquid crystal
G. Tiddy (1980)
10.1021/LA00016A018
Influence of surfactants on the rheology of associating polymers in solution
T. Annable (1994)
10.1021/la104972r
The use of highly ordered vesicle gels as template for the formation of silica gels.
C. Oppel (2011)
10.1021/MA048504V
Hydrophobically Modified Dimethylacrylamide Synthesis and Rheological Behavior
S. L. Cram (2005)
10.1016/J.COCIS.2010.07.005
The rheology of vesicle and disk systems — Relations between macroscopic behaviour and microstructure
M. Gradzielski (2011)
Liposomes : a practical approach
R. New (1990)
10.1246/BCSJ.80.410
Complex Made from Tetrasodium N,N-Bis(carboxylatomethyl) Glutamate and Sodium Oleate that Forms a Highly Ordered Lamella in Gel Phase
Yeonhwan Jeong (2007)
The Colloidal Domain: Where Physics
F D Evans
10.1021/JP994301A
Sphere-to-Cylinder Transition in Aqueous Micellar Solution of a Dimeric (Gemini) Surfactant
A. Bernheim-Groswasser (2000)
10.1126/science.aag0184
Quantifying the impact of molecular defects on polymer network elasticity
Mingjiang Zhong (2016)
10.1016/0021-9797(84)90115-2
Electron microscopic observation of rod-like micelles of dimethyloleylamine oxide regenerated from its aqueous solutions
T. Imae (1984)
10.1039/C0SM01071E
Wormlike micelles and gels reinforced by hydrogen bonding in aqueous cationic gemini surfactant systems
Xiaomei Pei (2011)
10.1021/CR0302049
Water gelation by small organic molecules.
L. Estroff (2004)
10.1080/00268979100102721
Viscoelastic surfactant solutions: model systems for rheological research
H. Rehage (1991)
10.1038/111825b0
International Union for Pure and Applied Chemistry
J. Zanetti (1923)
10.1021/ja500205v
Tough stimuli-responsive supramolecular hydrogels with hydrogen-bonding network junctions.
Mingyu Guo (2014)
10.1006/JCIS.1998.5690
Formation and Properties of Lamellar Phases in Systems of Cationic Surfactants and Hydroxy-Naphthoate.
Horbaschek (1998)
10.1021/JP014096A
Rheological Properties and Microstructures of Anionic Micellar Solutions in the Presence of Different Inorganic Salts
Jian-Hai Mu (2002)
10.1021/MA201150G
Influence of Surfactants on Hydrophobically End-Capped Poly(ethylene oxide) Self-Assembled Aggregates Studied by SANS
Chantal Rufier (2011)
10.1016/J.IJPHARM.2007.07.026
Injectable block copolymer hydrogels for sustained release of a PEGylated drug.
Lin Yu (2008)
10.1021/bm301143d
Biopolymer-connected liposome networks as injectable biomaterials capable of sustained local drug delivery.
J. Lee (2012)
10.1039/C2SM25107H
The conundrum of gel formation by molecular nanofibers, wormlike micelles, and filamentous proteins: gelation without cross-links?
S. Raghavan (2012)
10.1039/C2SM25505G
Self-assembly of onion-like vesicles induced by charge and rheological properties in anionic–nonionic surfactant solutions
R. Dong (2012)
10.1007/S003960100532
Organogels from ABA triblock copolymers
T. Dürrschmidt (2001)
10.1016/S0966-7822(96)00042-1
Gels from modified hydroxyethyl cellulose and ionic surfactants
H. Hoffmann (1996)
10.1007/S00396-002-0702-3
Gelation of "catanionic" vesicles by hydrophobically modified polyelectrolytes
H. S. Ashbaugh (2002)
10.1021/MA970354J
Association of Hydrophobically End-Capped Poly(ethylene oxide)
C. Chassenieux (1997)
10.1021/la9045308
Thermosensitive aqueous gels with tunable sol-gel transition temperatures from thermo- and pH-responsive hydrophilic ABA triblock copolymer.
Thomas G. O'lenick (2010)
10.1002/ADFM.200700587
Temperature-Induced Hydrogels Through Self-Assembly of Cholesterol-Substituted Star PEG-b-PLLA Copolymers: An Injectable Scaffold for Tissue Engineering†
K. Nagahama (2008)
Morphological Transitions in Amphiphilic Systems Probed by Small-Angle Scattering Techniques
M. Gradzielski (2003)
10.1021/MA00108A038
Associating polymers: Equilibrium and linear viscoelasticity
A. Semenov (1995)
10.1007/978-3-319-15129-8_2
Colloidal Gels Formed by Dilute Aqueous Dispersions of Surfactant and Fatty Alcohol
F. Grewe (2015)
10.1039/c4sm00501e
Oil-in-water microemulsion droplets of TDMAO/decane interconnected by the telechelic C18-EO150-C18: clustering and network formation.
Paula Malo de Molina (2014)
10.1088/0953-8984/15/19/202
TOPICAL REVIEW: Vesicles and vesicle gels - structure and dynamics of formation
M. Gradzielski (2003)
10.1021/LA0527691
Supramolecular self-assembly of multiblock copolymers in aqueous solution.
Michael Determan (2006)
10.1002/mabi.201100022
A thermoresponsive hydrogel based on telechelic PEG end-capped with hydrophobic dipeptides.
I. Hamley (2011)
10.1016/J.POLYMER.2007.04.069
Synthesis and rheological properties of an associative star polymer in aqueous solutions
S. Hietala (2007)
10.1021/la901513w
Distinct character of surfactant gels: a smooth progression from micelles to fibrillar networks.
S. Raghavan (2009)
10.3139/113.100332
Vesicles and Vesicle Gels – Structure and Solubilisation Properties
A. Hufnagl (2007)
10.1063/1.471031
Small angle neutron scattering near the wetting transition: Discrimination of microemulsions from weakly structured mixtures
M. Gradzielski (1996)
10.1051/JP2:1992102
Linear viscoelasticity of wormlike micelles: a comparison of micellar reaction kinetics
M. S. Turner (1992)
10.1007/BF00398432
Shear orientation of a lamellar lyotropic liquid crystal
Jörg Lauger (1995)
10.1039/C3SM52184B
Light-induced transformation of vesicles to micelles and vesicle-gels to sols
Hyuntaek Oh (2013)
10.1039/C0SM01278E
Investigations of vesicle gels by pulsed and modulated gradient NMR diffusion techniques
S. Lasič (2011)
10.1051/JPHYS:019880049090159300
Dynamics of living polymers and flexible surfactant micelles : scaling laws for dilution
M. Cates (1988)
10.1002/chem.201300132
Multiresponsive viscoelastic vesicle gels of nonionic C₁₂EO₄ and anionic AzoNa.
D. Wang (2013)
10.1021/MA001852M
In-Situ Thermoreversible Gelation of Block and Star Copolymers of Poly(ethylene glycol) and Poly(N-isopropylacrylamide) of Varying Architectures
H. Lin (2001)
10.1016/J.COCIS.2010.07.007
Rheology of associative polymer solutions
C. Chassenieux (2011)
10.1021/MA00060A006
A fluorescent probe study of micelle-like cluster formation in aqueous solutions of hydrophobically modified poly(ethylene oxide)
Ahmad Yekta (1993)
10.1021/JP9833303
STRUCTURAL AND MACROSCOPIC CHARACTERIZATION OF A GEL PHASE OF DENSELY PACKED MONODISPERSE, UNILAMELLAR VESICLES
M. Gradzielski (1999)
10.1021/LA052447X
Lamellar gels and spontaneous vesicles in catanionic surfactant mixtures.
B. Coldren (2006)
10.1016/0014-5793(81)80071-3
The Hydrophobic Effect: Formation of Micelles and Biological Membranes
C. Walker (1981)
10.1016/J.COLSURFA.2007.03.045
How does a non-ionic hydrophobically modified telechelic polymer interact with a non-ionic vesicle? Rheological aspects
T. Santos (2008)
10.1039/C0SM00395F
A gel state from densely packed multilamellar vesicles in the crystalline state
Panfeng Long (2010)
10.1021/MA990350+
Interactions between Catanionic Vesicles and Oppositely Charged PolyelectrolytesPhase Behavior and Phase Structure
E. Marques (1999)
10.1021/LA7028559
Wormlike micelles of a C22-tailed zwitterionic betaine surfactant: from viscoelastic solutions to elastic gels.
R. Kumar (2007)
10.1021/la801452z
Control of phase behavior and properties of vesicle gels by admixing ionic surfactants to the nonionic surfactant Brij 30.
S. Kinzel (2008)
10.1002/asia.201300134
Interconvertible self-assembly and rheological properties of planar bilayers and vesicle gels in anionic/nonionic (CF/CH) surfactant solutions.
R. Dong (2013)
10.1126/SCIENCE.2781283
Spontaneous vesicle formation in aqueous mixtures of single-tailed surfactants.
E. Kaler (1989)
10.1515/arh-2001-0032
The Colloidal Domain – where physics, chemistry, biology and technology meet
W. Richtering (2001)
10.1122/1.2828645
Linear viscoelasticity of entangled wormlike micelles bridged by telechelic polymers: An experimental model for a double transient network
K. Nakaya (2007)
10.1021/LA020912+
Rheology of mixed solutions of an associating polymer with a surfactant. Why are different surfactants different
L. Piculell (2003)
10.1201/9780203911518.ch10
VISCOELASTIC SURFACTANT SOLUTIONS
H. Hoffmann (1997)
Surfactant gels
H. Hoffmann (1996)
10.1021/BM049331K
Synthesis and characterization of biocompatible thermo-responsive gelators based on ABA triblock copolymers.
Chengming Li (2005)
Applications of thermo-reversible pluronic F-127 gels in pharmaceutical formulations.
José Juan Escobar-Chávez (2006)
10.1021/MA990999E
Viscoelastic Behavior of Semidilute Solutions of Multisticker Polymer Chains
Enrique Javier Jiménez Regalado (1999)
10.1016/j.jcis.2015.03.058
How hydrophobically modified chitosans are stabilized by biocompatible lipid aggregates.
N. Ruocco (2015)
10.1021/MA00010A026
COLLOIDAL NATURE OF STAR POLYMER DILUTE AND SEMIDILUTE SOLUTIONS
W. Dozier (1991)
10.1021/acs.langmuir.5b03267
Biological Hydrogels Formed by Swollen Multilamellar Liposomes.
Chih-Yang Cheng (2015)
10.1021/la404434q
Origins of microstructural transformations in charged vesicle suspensions: the crowding hypothesis.
Mansi Seth (2014)
10.1007/BF01425040
Electron microscope study of viscoelastic cationic surfactant systems
Y. Sakaiguchi (1987)
10.1021/MA100464Z
Hydrogels from ABA and ABC Triblock Polymers
Rajiv Taribagil (2010)
10.1021/JP983480D
BEHAVIOR OF IONICALLY CHARGED LAMELLAR SYSTEMS UNDER THE INFLUENCE OF A SHEAR FIELD
M. Bergmeier (1999)
10.1201/9781420007121
Giant micelles : properties and applications
R. Zana (2007)
10.1007/BF02462022
Complex fluids with a yield value; their microstructures and rheological properties
H. Hoffmann (1994)
10.1103/PHYSREVLETT.68.2340
Inverse melting transition and evidence of three-dimensional cubatic structure in a block-copolymer micellar system.
Mortensen (1992)
10.1039/c6cs00130k
Supramolecular polymer networks: hydrogels and bulk materials.
Lenny Voorhaar (2016)



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