Please confirm you are human (Sign Up for free to never see this)
← Back to Search
Bending Of Layer-by-Layer Films Driven By An External Magnetic Field
C. Miyazaki, Antonio Riul, D. S. dos Santos, Mariselma Ferreira, C. Constantino, M. A. Pereira-da-Silva, R. Paupitz, D. S. Galvão, O. Oliveira
Published 2013 · Chemistry, Medicine
Save to my Library
Download PDFAnalyze on Scholarcy
We report on optimized architectures containing layer-by-layer (LbL) films of natural rubber latex (NRL), carboxymethyl-chitosan (CMC) and magnetite (Fe3O4) nanoparticles (MNPs) deposited on flexible substrates, which could be easily bent by an external magnetic field. The mechanical response depended on the number of deposited layers and was explained semi-quantitatively with a fully atomistic model, where the LbL film was represented as superposing layers of hexagonal graphene-like atomic arrangements deposited on a stiffer substrate. The bending with no direct current or voltage being applied to a supramolecular structure containing biocompatible and antimicrobial materials represents a proof-of-principle experiment that is promising for tissue engineering applications in biomedicine.
This paper references
Stimuli-responsive LbL capsules and nanoshells for drug delivery.
M. Delcea (2011)
Unusual interactions binding iron tetrasulfonated phthalocyanine and poly(allylamine hydrochloride) in layer-by-layer films
V. Zucolotto (2003)
Mechanical Properties of Robust Ultrathin Silk Fibroin Films
Chaoyang Jiang (2007)
Photocrosslinkable diazoresin/pectin films – Synthesis and application as cell culture supports
A. Plewa (2011)
Catechol biosensing using a nanostructured layer-by-layer film containing Cl-catechol 1,2-dioxygenase.
V. Zucolotto (2006)
Polyelectrolyte films based on polysaccharides of different conformations: effects on multilayer structure and mechanical properties.
Bjoern Schoeler (2006)
Low temperature degradation and characterization of natural rubber
O. Chaikumpollert (2011)
Natural rubber latex LbL films: Characterization and growth of fibroblasts
Christiane P. Davi (2012)
Surface modification of poly(propylene carbonate) by aminolysis and layer-by-layer assembly for enhanced cytocompatibility.
X. Zhong (2012)
Fabrication and hemocompatibility of cell outer membrane mimetic surfaces on chitosan by layer by layer assembly with polyanion bearing phosphorylcholine groups.
M. Gong (2011)
Synthesis and characterization of PEG-graft-quaternized chitosan and cationic polymeric liposomes for drug delivery
Xiaofei Liang (2012)
Polyaniline fibres containing single walled carbon nanotubes: Enhanced performance artificial muscles
V. Mottaghitalab (2006)
Layer-by-layer self-assembly of modified hyaluronic acid/chitosan based on hydrogen bonding.
U. Manna (2009)
Ultrathin cantilevers based on polymer-ceramic nanocomposite assembled through layer-by-layer adsorption
Feng Hua (2004)
Angiogenic properties of natural rubber latex biomembranes and the serum fraction of Hevea brasiliensis
M. Ferreira (2009)
Adjacent assembly of self-assembled monolayers for the construction of selective bio-platforms
A. Ron (2011)
Artificially engineered magnetic nanoparticles for ultra-sensitive molecular imaging
Jaehyun Lee (2007)
Bending LbL Films Containing Magnetic Nanoparticles with an External Field Available online
Polymer artificial muscles
Tissaphern Mirfakhrai (2007)
Modelling Elastic and Thermoelastic Thick Multilayered Composites by a New Constrained Discrete Layer Approach
M. Blanc (2006)
Magnetic fluid hyperthermia (MFH): Cancer treatment with AC magnetic field induced excitation of biocompatible superparamagnetic nanoparticles
A. Jordan (1999)
A novel two-step modifying process for preparation of chitosan-coated Fe 3 O 4 /SiO 2 microspheres
Z Lei (2009)
Use of chitosan membrane associated with polypropylene mesh to prevent peritoneal adhesion in rats.
N. Paulo (2009)
Making carbon nanotubes biocompatible and biodegradable.
A. Bianco (2011)
Iron oxide nanoparticles for sustained delivery of anticancer agents.
Tapan Jain (2005)
Surface functionalization of hyaluronic acid hydrogels by polyelectrolyte multilayer films.
Seda Yamanlar (2011)
Using capacitance measurements as the detection method in antigen-containing layer-by-layer films for biosensing.
V. Zucolotto (2007)
Determination of nanocrystal sizes: a comparison of TEM, SAXS, and XRD studies of highly monodisperse CoPt3 particles.
H. Borchert (2005)
Magnetic nanoparticle-peptide conjugates for in vitro and in vivo targeting and extraction of cancer cells.
K. E. Scarberry (2008)
Carboxymethyl Chitosan - Fe 3 O 4 nanoparticles : Preparation and adsorption behavior toward Zn 2 + Ions
K. E. Scarberry (2006)
Wrinkled polypyrrole electrode for electroactive polymer actuators
Masashi Watanabe (2002)
Raman spectroscopy investigation of magnetite nanoparticles in ferrofluids
L. Slavov (2010)
Biocompatibility of natural latex implanted into dental alveolus of rats.
C. A. C. A. Balabanian (2006)
Bending LbL Films Containing Magnetic Nanoparticles with an External Field
Responsive layer-by-layer materials for drug delivery.
Benjamin M. Wohl (2012)
Counterintuitive effect of molecular strength and role of molecular rigidity on mechanical properties of layer-by-layer assembled nanocomposites.
P. Podsiadlo (2007)
Polyelectrolyte multilayers of diblock copolymer micelles with temperature-responsive cores.
L. Xu (2011)
(Carboxymethyl)chitosan-modified superparamagnetic iron oxide nanoparticles for magnetic resonance imaging of stem cells.
Zhilong Shi (2009)
Chitosan: hydrossoluble derivatives, pharmaceutical applications and recent advances
H.S.R.C. Silva (2006)
WSXM: a software for scanning probe microscopy and a tool for nanotechnology.
I. Horcas (2007)
Dynamic aspects of films prepared by a sequential deposition of species: perspectives for smart and responsive materials.
P. Lavalle (2011)
Natural rubber latexused as drugdelivery system in guidedboneregeneration (GBR). Mater. Res. 2009
R D Herculano
Carboxymethyl Chitosan-Fe3O4 Nanoparticles: Preparation and Adsorption Behavior toward Zn2+ Ions
L. Zhou (2006)
All-atom empirical potential for molecular modeling and dynamics studies of proteins.
Alexander D. MacKerell (1998)
Nanostructured natural-based polyelectrolyte multilayers to agglomerate chitosan particles into scaffolds for tissue engineering.
E. Miranda (2011)
Layer-by-layer assembled stimuli-responsive nanoporous membranes
Younghyun Cho (2012)
On the release of metronidazole from natural rubber latex membranes
R. Herculano (2011)
Immobilization of cholesterol oxidase in LbL films and detection of cholesterol using ac measurements
Marli L. Moraes (2009)
All-nanoparticle thin-film coatings.
D. Lee (2006)
Uso experimental da biomembrana de látex na reconstrução conjuntival
Erika Christina Canarim Martha de Pinho (2004)
Future perspectives and recent advances in stimuli-responsive materials
D. Roy (2010)
Polyelectrolyte/magnetite nanoparticle multilayers: preparation and structure characterization.
D. Grigoriev (2007)
Carboxymethyl Chitosan-Fe 3 O 4 nanoparticles: Preparation and adsorption behavior toward Zn 2+ Ions
L Zhou (2006)
This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license
Preparation and characterization of carboxymethylchitosan
Fernanda Raimunda de Abreu (2005)
Layered polyelectrolyte complexes: physics of formation and molecular properties
M. Schönhoff (2003)
Layer-by-layer self-assembly of composite polyelectrolyte-nafion membranes for direct methanol fuel cells
S. Jiang (2006)
Use of magnetic nanoparticle heating in the treatment of breast cancer.
I. Hilger (2005)
Carbon nanotube actuators
Evaluation of the biocompatibility of a new biomembrane
F. Mrué (2004)
Quitosana: derivados hidrossolúveis, aplicações farmacêuticas e avanços
H. R. S. Silva (2006)
Polymer artificial muscles. Mater. Today
T Mirfakhrai (2007)
A convergent adaptive wavelet-Rothe method for elastoplastic hardening
G. Naldi (2004)
Fast parallel algorithms for short-range molecular dynamics
S. Plimpton (1993)
Functionalization and peptide-based delivery of magnetic nanoparticles as an intracellular MRI contrast agent
N. Nitin (2004)
Surface nanostructure of Hevea brasiliensis natural rubber latex particles
K. Nawamawat (2011)
Biomedical Applications of Layer‐by‐Layer Assembly: From Biomimetics to Tissue Engineering
Z. Tang (2006)
Chitosan in nanostructured thin films.
F. Pavinatto (2010)
Tissue integration of growth factor-eluting layer-by-layer polyelectrolyte multilayer coated implants.
Mara L Macdonald (2011)
Polyelectrolyte Multilayer Assemblies on Materials Surfaces: From Cell Adhesion to Tissue Engineering.
V. Gribova (2012)
Chitosan scaffolds for osteochondral tissue regeneration.
A. Abarrategi (2010)
Influence of the conductor network composites on the electromechanical performance of ionic polymer conductor network composite actuators
S. Liu (2010)
VIBRATIONAL SPECTRA OF CIS-1,4-POLYISOPRENE
P. Nallasamy (2004)
Compliant, Robust, and Truly Nanoscale Free‐Standing Multilayer Films Fabricated Using Spin‐Assisted Layer‐by‐Layer Assembly
C. Jiang (2004)
Magnetic micelles as a potential platform for dual targeted drug delivery in cancer therapy.
C. Huang (2012)
Emerging applications of stimuli-responsive polymer materials.
M. C. Stuart (2010)
Natural rubber latexused as drugdelivery system in guidedboneregeneration (GBR)
R. D. Herculano (2009)
Increased vascular permeability, angiogenesis and wound healing induced by the serum of natural latex of the rubber tree Hevea brasiliensis
Ricardo José Mendonça (2010)
Natural Rubber Latex Used as Drug Delivery System in Guided Bone Regeneration (GBR)
R. Herculano (2009)
A novel two-step modifying process for preparation of chitosan-coated Fe3O4/SiO2 microspheres
Z. Lei (2009)
Ultrathin film actuators fabricated by layer-by-layer molecular self-assembly
T. Zeng (2001)
This paper is referenced by
Fabrication of High Performance Magnetic Rubber from NBR and Fe3O4 via in Situ Compatibilization with Zinc Dimethacrylate
Y. Chen (2017)
Combining electrochemically reduced graphene oxide and Layer-by-Layer films of magnetite nanoparticles for carbofuran detection
C. Miyazaki (2020)
Layer-by-layer thin films of polyaniline alternated with natural rubber and their potential application as a chemical sensor
C. Cena (2016)
Enhanced electrical and mechanical properties of rubber/graphene film through layer-by-layer electrostatic assembly
L. Wang (2016)
Energy levels of metal porphyrins upon molecular alignment during layer-by-layer electrostatic assembly: scanning tunneling spectroscopy vis-à-vis optical spectroscopy
Biswajit Kundu (2016)
Layer-by-Layer nanostructured films of magnetite nanoparticles and polypyrrole towards synergistic effect on methylparaben electrochemical detection
L. F. D. Lima (2020)
An investigation of the synergistic effect between magnetite nanoparticles and polypyrrole in nanostructured layer‐by‐layer films
L. F. D. Lima (2021)
High-performance magnetic poly (arylene ether nitrile) nanocomposites: Co-modification of Fe 3 O 4 via mussel inspired poly(dopamine) and amino functionalized silane KH550
Xinyi Wan (2017)