Graphene-Based Nanomaterials As Heterogeneous Acid Catalysts: A Comprehensive Perspective
Bhaskar Garg, Tanuja Bisht, Yong-Chien Ling
Published 2014 · Chemistry, Medicine
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Acid catalysis is quite prevalent and probably one of the most routine operations in both industrial processes and research laboratories worldwide. Recently, “graphene”, a two dimensional single-layer carbon sheet with hexagonal packed lattice structure, imitative of nanomaterials, has shown great potential as alternative and eco-friendly solid carbocatalyst for a variety of acid-catalyzed reactions. Owing to their exceptional physical, chemical, and mechanical properties, graphene-based nanomaterials (G-NMs) offer highly stable Brønsted acidic sites, high mass transfer, relatively large surface areas, water tolerant character, and convenient recoverability as well as recyclability, whilst retaining high activity in acid-catalyzed chemical reactions. This comprehensive review focuses on the chemistry of G-NMs, including their synthesis, characterization, properties, functionalization, and up-to-date applications in heterogeneous acid catalysis. In line with this, in certain instances readers may find herein some criticisms that should be taken as constructive and would be of value in understanding the scope and limitations of current approaches utilizing graphene and its derivatives for the same.
This paper references
Non-covalent functionalization of graphene sheets by sulfonated polyaniline.
Hua Bai (2009)
Inside Cover: Graphene Oxide: A Convenient Carbocatalyst for Facilitating Oxidation and Hydration Reactions (Angew. Chem. Int. Ed. 38/2010)
Daniel R. Dreyer (2010)
On the Atomic Weight of Graphite
Benjamin von Collins Brodie (1859)
Water Soluble Graphene Synthesis
Balaprasad Ankamwar (2012)
Untersuchungen zur Struktur des Graphitoxyds
Alexander Clause (1957)
Efficient synthesis of graphene sheets using pyrrole as a reducing agent
Chellachamy Anbalagan Amarnath (2011)
Sulfonated graphene for persistent aromatic pollutant management.
Guixia Zhao (2011)
This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license
Formation of Sulphamic Acid during the Thermal Decomposition of Ammonium Sulphate
P. Dixon (1944)
Graphene oxide, highly reduced graphene oxide, and graphene: versatile building blocks for carbon-based materials.
Owen C. Compton (2010)
13 C and 1 H MAS NMR studies of graphite oxide and its chemically modified derivatives. Solid State Ion
A Lerf (1997)
The chemistry of graphene oxide.
D. R. Dreyer (2010)
Graphene-based materials for catalysis
Bruno F. Machado (2012)
Graphene oxide: a convenient carbocatalyst for facilitating oxidation and hydration reactions.
Daniel R. Dreyer (2010)
Diazonium functionalization of surfactant-wrapped chemically converted graphene sheets.
Jay R. Lomeda (2008)
Harnessing the chemistry of graphene oxide.
Daniel R. Dreyer (2014)
New insights into the structure and reduction of graphite oxide.
Wenli Gao (2009)
Strategies for chemical modification of graphene and applications of chemically modified graphene
Jingquan Liu (2012)
Chemical conversion of biomass-derived hexose sugars to levulinic acid over sulfonic acid-functionalized graphene oxide catalysts
Pravin P. Upare (2013)
Nomenclature of sp 2 carbon nanoforms
Guest Editorial (2012)
Graphene: Status and Prospects
Andre K. Geim (2009)
Bifunctional Acid–Base Cooperativity in Heterogeneous Catalytic Reactions: Advances in Silica Supported Organic Functional Groups
Sankaranarayanapillai Shylesh (2011)
Graphene Oxide as Catalyst for the Acetalization of Aldehydes at Room Temperature
Amarajothi Dhakshinamoorthy (2012)
13C and 1H MAS NMR studies of graphite oxide and its chemically modified derivatives
Anton Lerf (1997)
A new structure model of graphite oxide
Tsuyoshi Nakajima (1988)
Electric Field Effect in Atomically Thin Carbon Films
K S Novoselov (2004)
Magnetic and fluorescent graphene for dual modal imaging and single light induced photothermal and photodynamic therapy of cancer cells.
Ganesh Gollavelli (2014)
Graphene and Its Derivatives: Switching ON and OFF
Yu Chen (2012)
Uber das graphitoxyhydroxyd (graphitoxyd). Monatshefte Chem
G Ruess (1947)
Recyclable Graphite Oxide Catalyzed Friedel—Crafts Addition of Indoles to α,β‐Unsaturated Ketones.
Akkilagunta Vijay Kumar (2012)
Raman scattering from high-frequency phonons in supported n-graphene layer films.
A. Gupta (2006)
Efficient Reduction of Graphite Oxide by Sodium Borohydride and Its Effect on Electrical Conductance
Hyeon-Jin Shin (2009)
Mark A. Ratner (1949)
High Surface Area Nafion Resin/Silica Nanocomposites: A New Class of Solid Acid Catalyst.
Mark Andrew Harmer (1996)
Graphene oxide. Origin of acidity, its instability in water, and a new dynamic structural model.
Ayrat M Dimiev (2013)
Graphene oxide as a facile acid catalyst for the one-pot conversion of carbohydrates into 5-ethoxymethylfurfural
Hong-liang Wang (2013)
The identification of the mechanism function and the kinetic investigation of the energy-storing reaction of ammonium hydrogen sulfate
Jinghua Li (1992)
Formation of sulphamic acid during the decomposition of ammonium sulphate
P. Dixon (1944)
Graphene and its derivatives: Switching
Y. Chen (2012)
Enhanced acidity and pH-dependent surface charge characterization of successively oxidized graphite oxides
T. Szabó (2006)
Sulfonated graphene as water-tolerant solid acid catalyst
Junyi Ji (2011)
One‐pot Green Synthesis of Azides from Alcohols Using Brønsted Acidic Ionic Liquid [HMIM][BF4] as Solvent and Catalyst
Bhaskar Garg (2014)
High-yield, large-scale production of few-layer graphene flakes within seconds: using chlorosulfonic acid and H2O2 as exfoliating agents
Wenbo Lu (2012)
Industrial Processes using Solid Acid Catalysts
Mark Andrew Harmer (2007)
Untersuchungen am Graphitoxid. VI. Betrachtungen zur Struktur des Graphitoxids
W. Scholz (1969)
Direct reduction of graphene oxide films into highly conductive and flexible graphene films by hydrohalic acids
Songfeng Pei (2010)
Synthesis and anion binding of 2-arylazo-meso-octamethylcalixpyrroles
Shive M. S. Chauhan (2009)
Thermal decomposition of ammonium sulphate
W. Halstead (2007)
Optimization of calibration data with the dynamic genetic algorithm
T. Li (1992)
Graphene-based photothermal agent for rapid and effective killing of bacteria.
Meng-Chin Wu (2013)
Amberlyst-15 in organic synthesis
Rammohan Pal (2012)
Lithium Aluminum Hydride as Reducing Agent for Chemically Reduced Graphene Oxides
Adriano Ambrosi (2012)
Betrachtungen zür Struktur des Graphitoxids
W Scholz (1969)
Raman spectra of graphite oxide and functionalized graphene sheets.
K. Kudin (2008)
Focusing on energy and optoelectronic applications: a journey for graphene and graphene oxide at large scale.
Xiangjian Wan (2012)
Determination of the local chemical structure of graphene oxide and reduced graphene oxide.
Kris Erickson (2010)
Graphene oxide as an acid catalyst for the room temperature ring opening of epoxides.
Amarajothi Dhakshinamoorthy (2012)
Spontaneous high-concentration dispersions and liquid crystals of graphene.
Natnael Behabtu (2010)
Untersuchungen am Graphitoxid
W. Scholz (1969)
Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide
S. Stankovich (2007)
Xiao Huang (2012)
Use of Graphite Oxide and Graphene Oxide as Catalysts in the Synthesis of Dipyrromethane and Calixpyrrole
Shive Murat Singh Chauhan (2011)
J. Chromatogr. A
Facile Synthesis of Smart Magnetic Graphene for Safe Drinking Water: Heavy Metal Removal and Disinfection Control
Ganesh Gollavelli (2013)
Sulfur species in graphene oxide.
Siegfried Eigler (2013)
Amorphous Carbon with SO3H Groups as a Solid Brønsted Acid Catalyst
Kiyotaka Nakajima (2012)
Aqueous dispersions of TCNQ-anion-stabilized graphene sheets.
Rui Hao (2008)
Synthesis of water soluble graphene.
Yongchao Si (2008)
Graphene synthesis via hydrogen induced low temperature exfoliation of graphite oxide
Adarsh Kaniyoor (2010)
Aqueous dispersions of TCNQanionstabilized graphene sheets
R. Hao (2008)
A comparative study of gas phase esterification on solid acid catalysts
Kaewta Suwannakarn (2007)
Formation process and structure of graphite oxide
Tsuyoshi Nakajima (1994)
Carbocatalysts: graphene oxide and its derivatives.
Chenliang Su (2013)
Chemical reduction of graphene oxide: a synthetic chemistry viewpoint.
Chun Kiang Chua (2014)
Simultaneous sulfonation and reduction of graphene oxide as highly efficient supports for metal nanocatalysts
Daping He (2014)
Investigation of the Kinetics and Mechanism of Decomposition of Ammonium Hydrogen Sulfate
Li Jing-hua (1992)
Synthesis of sulfonated graphene/polyaniline composites with improved electroactivity
Elçin Coşkun (2012)
Carbocatalytic dehydration of xylose to furfural in water
Edmond W.M. Lam (2012)
Graphite oxide as a carbocatalyst for the preparation of fullerene-reinforced polyester and polyamide nanocomposites
Daniel R. Dreyer (2012)
Solid-State NMR Studies of the Structure of Graphite Oxide
Heyong He (1996)
Water-tolerant solid acid catalysts.
T. Okuhara (2002)
Synthesis and characterization of sulfonated single-walled carbon nanotubes and their performance as solid acid catalyst
Hao Yu (2008)
Preparation of a Carbon-Based Solid Acid Catalyst by Sulfonating Activated Carbon in a Chemical Reduction Process
Xiao-yan Liu (2010)
Evolution of Surface Functional Groups in a Series of Progressively Oxidized Graphite Oxides
T. Szab'o (2006)
Functionalized single graphene sheets derived from splitting graphite oxide.
H. Schniepp (2006)
Stable aqueous dispersions of graphitic nanoplatelets via the reduction of exfoliated graphite oxide in the presence of poly(sodium 4-styrenesulfonate)
S. Stankovich (2006)
Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite
Michael J. McAllister (2007)
Über das Graphitoxyhydroxyd (Graphitoxyd)
Gerhard Ruess (1947)
Green chemistry: Biodiesel made with sugar catalyst
Masakazu Toda (2005)
Raman spectroscopy of graphene on different substrates and influence of defects
Anindya Das (2007)
Rapid identification of trimethyl and triethyl amines using sulphonic acidic ionic liquids: A time-of-flight secondary ion mass spectrometry study of fragmentation reactions.
Bhaskar Garg (2012)
The reduction of graphene oxide
Songfeng Pei (2012)
2,2′-Diaminoazo-benzene, a potential scaffold for the synthesis of bis-ureas and thioureas: Solution phase anion sensing and binding studies
Bhaskar Garg (2012)
Graphene oxide: an efficient and reusable carbocatalyst for aza-Michael addition of amines to activated alkenes.
Sanny Verma (2011)
Sulfated graphene as an efficient solid catalyst for acid-catalyzed liquid reactions
Fujian Liu (2012)
Sulfated Graphene Oxide as a Hole-Extraction Layer in High-Performance Polymer Solar Cells.
J. Liu (2012)
Improved synthesis of graphene oxide.
D. Marcano (2010)
Superior Catalysts for Proton Exchange Membrane Fuel Cells Sulfonation of Carbon-Supported Catalysts Using Sulfate Salts
Zhiqiang Xu (2005)
Sulfonated Ordered Mesoporous Carbon as a Stable and Highly Active Protonic Acid Catalyst
Xiqing Wang (2007)
Über die Säurenatur und die Methylierung von Graphitoxyd
Ulrich Hofmann (1939)
Synthesis and characterization of sulfonated graphene as a highly active solid acid catalyst for the ester-exchange reaction
Lin Wang (2013)
Selective hydrolysis of cellulose into glucose over solid acid catalysts
Ayumu Onda (2008)
Stability of sulfated zirconia and the nature of the catalytically active species in the transesterification of triglycerides
Kaewta Suwannakarn (2008)
Solid acid catalysis using ion-exchange resins
Mark Andrew Harmer (2001)
1-Arylazo-5,5-dimethyl dipyrromethanes: Versatile chromogenic probes for anions
Shive M. S. Chauhan (2009)
RGO LBL modified biomimetic electrochemical sensor for detection of Sildenafil in herbal sexual health products.
Yun Li (2013)
RGD-peptide functionalized graphene biomimetic live-cell sensor for real-time detection of nitric oxide molecules.
Chun Xian Guo (2012)
Highly efficient synthesis of N-confused meso-tetraspirocyclohexyl calixpyrrole using Brønsted acidic ionic liquids as catalysts
Bhaskar Garg (2012)
Pristine graphite oxide.
Ayrat M Dimiev (2012)
Decorating Graphene Sheets with Gold Nanoparticles
Ryan Muszynski (2008)
Flexible graphene films via the filtration of water-soluble noncovalent functionalized graphene sheets.
Y. Xu (2008)
Syntheses of calixpyrroles by amberlyst-15 catalyzed cyclocondensations of pyrrole with selected ketones.
Shive Murat Singh Chauhan (2007)
The synthesis of xanthenes and benzoxanthenes on graphene oxide and sulfated graphene nanosheets in water
Ahmad Shaabani (2013)
Chlorosulfonic Acid-based Room Temperature Chemical Expansion Route for the Bulk Production of Graphite Nanoplatelets
İbrahim Mutlay (2013)
Controlled synthesis of large-area and patterned electrochemically reduced graphene oxide films.
Ming Zhou (2009)
Carbocatalysis by graphene-based materials.
Sergio Navalón (2014)
Verfahren zur Darstellung der Graphitsäure
L. Staudenmaier (1898)
Preparation of Graphitic Oxide
W. S. Hummers (1958)
Carbon nanomaterials for advanced energy conversion and storage.
L. Dai (2012)
Synthesis of nitrogen-doped graphene by pyrolysis of ionic-liquid-functionalized graphene
Jen-Yu Liu (2013)
Nomenclature of sp2 carbon nanoforms
Irene Suarez-Martinez (2012)
Synthesis and anion binding properties of novel 3,12- and 3,7-bis(4′-nitrophenyl)-azo-calixpyrrole receptors
Bhaskar Garg (2010)
Ethylene glycol reduced graphene oxide/polypyrrole composite for supercapacitor
Yan Liu (2013)
Evaluation of sulfonated graphene sheets as sorbent for micro-solid-phase extraction combined with gas chromatography-mass spectrometry.
H. Zhang (2012)
Sulfonated graphene oxide as effective catalyst for conversion of 5-(hydroxymethyl)-2-furfural into biofuels.
Margarida M Antunes (2014)
Mechanism, Kinetics, and Equilibrium of Thermal Decomposition of Ammonium Sulfate
R. Kiyoura (1970)
Sulfonated carbon nanotubes as a strong protonic acid catalyst
Feng Peng (2005)
Rapid identification of trimethyl and triethyl amines using sulfonic acidic ionic liquids: A TOF-SIMS study of fragmentation reactions
B. Garg (2012)
Versatilities of graphene-based catalysts in organic transformations
Bhaskar Garg (2013)
Spatially resolved Raman spectroscopy of single- and few-layer graphene.
D. Graf (2006)
Structure of Graphite Oxide Revisited
A. Lerf (1998)
This paper is referenced by
Advances in carbon based nanomaterials for bio-medical applications.
Tejendra K. Gupta (2018)
Graphene oxide nanofibers: A nanocarbon material with tuneable electrochemical properties
David Torres (2020)
A comparative study of water-immiscible organic solvents in the production of furfural from xylose and birch hydrolysate
Gerardo Gómez Millán (2019)
Synthesis, Characterization, and Bactericidal Evaluation of Chitosan/Guanidine Functionalized Graphene Oxide Composites
Ping Li (2016)
Graphene-based catalysis for biomass conversion
Shanhui Zhu (2015)
Selectivity matters: Graphene oxide-mediated oxidative coupling of benzylamine to N‑benzylidine-1-phenylmethanamine under microwave irradiation
José Maŕıa Ancochea Bermúdez (2015)
Carbocatalysis in Liquid-Phase Reactions.
Dang Sheng Su (2017)
Emerging Trends in the Syntheses of Heterocycles Using Graphene-based Carbocatalysts: An Update
Sharoni Gupta (2019)
Sol-Gel-Assisted Microwave-Derived Synthesis of Anatase Ag/TiO2/GO Nanohybrids toward Efficient Visible Light Phenol Degradation
Edreese Alsharaeh (2017)
Graphene Based 1-D Photonic Crystal Waveguide for Delay Tuning
Ashina Garg (2016)
Catalytic and mechanistic insights into the production of ethyl levulinate from biorenewable feedstocks
E. Ahmad (2016)
31 P Solid-State NMR Spectroscopy of Adsorbed Phosphorous Probe Molecules: Acidity Characterization of Solid Acid Carbonaceous Materials for Catalytic Applications
Bhaskar Garg (2018)
The designing strategies of graphene-based peroxidase mimetic materials
Yanjie Wen (2017)
One-step solvothermal synthesis of TiO2-reduced graphene oxide nanocomposites with enhanced visible light photoreduction of Cr(VI)
Aasiya Shaikh (2017)
Effect of hybrid filling with short glass fibers and expanded graphite on structure, rheological and mechanical properties of poly(ethylene terephthalate)
V. V. Dubrovsky (2018)
Aldehyde-conjugated chitosan-graphene oxide glucodynamers: Ternary cooperative assembly and controlled chemical release.
Jamal Chabbi (2020)
Piperazine-Grafted Magnetic Reduced Graphene Oxide (Fe3O4@rGO-NH) as a Reusable Heterogeneous Catalyst for Gewald Three-Component Reaction
Esmail Rezaei-Seresht (2020)
Handbook of Materials Characterization
Surender Kumar Sharma (2018)
Carbon Nanodots as Peroxidase Nanozymes for Biosensing
Bhaskar Garg (2016)
Introducing sulphur surface groups in microporous carbons: A mechanistic study on carbide derived carbons
Johannes Landwehr (2018)
Revolution of Graphene for different applications: State-of-the-art
Nabil A. Abdel Ghany (2017)
Raman spectroscopy of biomedical polyethylenes.
Giuseppe Pezzotti (2017)
Magnetic Graphene Nanocomposites for Multifunctional Applications
Bhaskar Garg (2017)
Hydrogen Generation from the Hydrolysis of Ammonia Borane Using Transition Metal Nanoparticles as Catalyst
Serdar Akbayrak (2017)
Effect of the Oxide–Carbon Heterointerface on the Activity of Co3O4/NRGO Nanocomposites toward ORR and OER
Kavita Kumar (2016)
Nanodiamond-Gold Nanocomposites with the Peroxidase-Like Oxidative Catalytic Activity.
Min Chul Kim (2016)
Preparation of highly functionalized carbon nanoparticles using a one-step acid dehydration of glycerol
Christopher S. Estes (2019)
Graphene-Based Nanomaterials as Efficient Peroxidase Mimetic Catalysts for Biosensing Applications: An Overview
Bhaskar Garg (2015)
Graphene-Based Metal/Acid Bifunctional Catalyst for the Conversion of Levulinic Acid to γ-Valerolactone
Yong Wang (2017)
Spectral, Thermal and Morphological Characterization of Biodegradable Graphene Oxide-Chitosan Nanocomposites
Ragupathy Baby Suneetha (2018)
Pyridine-grafted graphene oxide: a reusable acid–base bifunctional catalyst for the one-pot synthesis of β-phosphonomalonates via a cascade Knoevenagel–phospha Michael addition reaction in water
Sara Sobhani (2015)
A facile route for the preparation of silver nanoparticles-graphene oxide nanocomposites and their interactions with pyronin Y dye molecules
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