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DOI: 10.3762/bjoc.15.160

Enantioselective PCCP Brønsted Acid-catalyzed Aza-Piancatelli Rearrangement

Gabrielle R Hammersley, Meghan F Nichol, Helena C Steffens, Jose M Delgado, Gesine K Veits, Javier Read de Alaniz

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An enantioselective aza-Piancatelli rearrangement has been developed using a chiral Brønsted acid based on pentacarboxycyclopentadiene (PCCP). This reaction provides rapid access to valuable chiral 4-amino-2-cyclopentenone building blocks from readily available starting material and is operationally simple.