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The First Catalytic Mannich‐Type Reaction Of N‐Alkoxycarbonylamino Sulfones With Silyl Enolates

Thierry Ollevier, Etienne Nadeau, Jean-Christophe Eguillon
Published 2006 · Chemistry

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Bismuth triflate was found to be an efficient catalyst in the Mannich-type reaction of silyl enolates with N-alkoxycarbonylamino sulfones. The reaction proceeded smoothly with a low catalyst loading of bismuth triflate (0.5–1.0 mol %) to afford the corresponding protected β-aminocarbonyl compound in very good yields (up to 96 %).
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