Online citations, reference lists, and bibliographies.
← Back to Search

Nickel: An Element With Wide Application In Industrial Homogeneous Catalysis

W. Keim
Published 1990 · Chemistry

Save to my Library
Download PDF
Analyze on Scholarcy Visualize in Litmaps
Share
Reduce the time it takes to create your bibliography by a factor of 10 by using the world’s favourite reference manager
Time to take this seriously.
Get Citationsy
The efficiency and future development of the chemical industry are closely linked to catalysis. It has been estimated, for example, that 60 to 70% of all industrial chemicals have involved the use of a catalyst at some point during their manufacture. In the past two decades the share of the market credited to homogeneous transition metal catalysis increasead to 10–15%. Besides cobalt, which is used mainly in hydroformylation reactions, nickel is the most frequently used metal. Many carbon–carbon bond formation reactions can be carried out with high selectivity if catalyzed by organonickel complexes. Such reactions include, inter alia, carbonylation reactions, cyclic and linear oligomerization and polymerization reactions of monoenes and dienes, and hydrocyanation reactions. It was Reppe and Wilke who pioneered and shaped the field of homogeneous nickel catalysis. Great impetus was also given to the development of organonickel chemistry by Wilke and his students. Research in this area has contributed immensely towards an understanding of the reactions involved in catalysis.—This review is primarily concerned with nickel-catalyzed reactions which are of interest both preparatively and industrially; some mechanistic aspects are also dealt with.



This paper is referenced by
10.1039/d0sc06471h
Boosting homogeneous chemoselective hydrogenation of olefins mediated by a bis(silylenyl)terphenyl-nickel(0) pre-catalyst†
M. Lücke (2021)
10.1021/jacs.1c01810
Advances in Group 10 Transition-Metal-Catalyzed Arene Alkylation and Alkenylation.
Weihao Zhu (2021)
10.1016/J.CEJ.2021.130342
Bio-inspired Ni dinuclear complexes as heterogeneous catalysts for hydrogen evolution
Alejandro Cabrera-García (2021)
10.1038/s41467-021-22512-6
Olefin oligomerization by main group Ga3+ and Zn2+ single site catalysts on SiO2
Nicole J. Libretto (2021)
10.1039/D1CY00821H
Doubly fused N,N,N-iron ethylene polymerization catalysts appended with fluoride substituents; probing catalytic performance via a combined experimental and MLR study
Qiuyue Zhang (2021)
10.1016/j.poly.2020.114469
Nickel catalyzed oligomerization of internal olefins: Towards lubricant basestocks and high cetane diesel fuels
A. Sattler (2020)
10.3390/catal10020229
Regeneration of Raney®-Nickel Catalyst for the Synthesis of High-Value Amino-Ester Renewable Monomers
Ana Soutelo-Maria (2020)
10.1039/d0nj04003g
2-(N,N-Diethylaminomethyl)-6,7-trihydroquinolinyl-8-ylideneamine-Ni(II) chlorides: application in ethylene dimerization and trimerization
J. Li (2020)
10.1039/d0cs00365d
Synthetic applications of type II intramolecular cycloadditions.
Long Min (2020)
10.21203/rs.3.rs-94946/v1
Olefin Oligomerization by Main Group Ga3+ and Zn2+ Single Site Catalysts
Nicole J. Libretto (2020)
10.1039/c9nj05704h
Catalytic systems based on nickel(II) complexes with bis(3,5-dimethylpyrazol-1-yl)methane – impact of PPh3 on the formation of precatalysts and selective dimerization of ethylene
S. V. Zubkevich (2020)
10.1021/acs.chemrev.0c00076
Nickel Catalyzed Olefin Oligomerization and Dimerization.
H. Olivier-Bourbigou (2020)
10.1039/d0na00669f
Theoretical insights into C–H bond activation of methane by transition metal clusters: the role of anharmonic effects
Preeti Bhumla (2020)
10.1002/EJIC.202000816
Visible‐Light‐Driven CO 2 Reduction Catalyzed by a Dinuclear Nickel Complex
Jia-Wei Wang (2020)
10.1002/aoc.5873
NNNO‐Heteroscorpionate nickel (II) and cobalt (II) complexes for ethylene oligomerization: the unprecedented formation of odd carbon number olefins
S. Zubkevich (2020)
10.1016/J.JECE.2020.104524
Functionalized pineapple aerogels for ethylene gas adsorption and nickel (II) ion removal applications
Zi En Lim (2020)
10.1039/d0cy01186j
Mechanistic Insights into Alkene Chain Growth Reactions Catalyzed by Nickel Active Sites on Ordered Microporous and Mesoporous Supports
R. Joshi (2020)
10.1016/j.molstruc.2020.127692
Molecular structure, magnetic properties and catalytic activity in selective ethylene dimerization of nickel (II) complexes with bis(3,5-dimethylpyrazol-1-yl)methane
S. V. Zubkevich (2020)
10.1016/j.jcou.2019.11.011
Catalytic CO2 absorption in an amine solvent using nickel nanoparticles for post-combustion carbon capture
Seokju Seo (2020)
10.1039/d0dt01139h
Solution XANES and EXAFS analysis of active species of titanium, vanadium complex catalysts in ethylene polymerisation/dimerisation and syndiospecific styrene polymerisation.
J. Yi (2020)
10.1021/acs.organomet.0c00485
Ni(4-tBustb)3: A Robust 16-Electron Ni(0) Olefin Complex for Catalysis
Lukas Nattmann (2020)
10.3390/catal10050498
Ni-Based Complexes in Selective Ethylene Oligomerization Processes
G. Bekmukhamedov (2020)
10.1002/ejoc.202000672
Intramolecular Nickel-Catalyzed Ring-Opening Reactions of Oxabenzonorbornadienes with C1 -Tethered Aryl Halides: An Improvement of Method
S. Koh (2020)
10.1002/cctc.202001121
Steric and Electronic Effects of Phosphane Additives on the Catalytic Performance of Colloidal Palladium Nanoparticles in the Semi‐Hydrogenation of Alkynes
Lena Staiger (2020)
10.1021/acsomega.8b03392
N-(((2-((2-Aminoethyl)amino)ethyl)amino)methyl)-4-sulfamoylbenzamide Impregnated Hydrous Zirconium Oxide as a Novel Adsorbent for Removal of Ni(II) from Aqueous Solutions: Optimization of Variables Using Central Composite Design
N. Rahman (2019)
10.1016/J.JCLEPRO.2019.04.024
Environmentally friendly hydrometallurgical recovery of tin and lead from waste printed circuit boards: Thermodynamic and kinetics studies
Farhad Moosakazemi (2019)
10.1002/AJOC.201900147
A Direct Approach to 3‐Azo‐Substituted 2‐Oxindoles at Room Temperature by Nickel‐Catalyzed Oxidative Coupling Reaction
L. Qing (2019)
10.26850/1678-4618EQJ.V44.1.2019.P11-39
A review on the state-of-the-art advances for CO2 electro-chemical reduction using metal complex molecular catalysts
H. Louis (2019)
10.3390/catal9121016
Solution X-Ray Absorption Spectroscopy (XAS) for Analysis of Catalytically Active Species in Reactions with Ethylene by Homogeneous (Imido)vanadium(V) Complexes—Al Cocatalyst Systems
K. Nomura (2019)
10.1134/S1070427218050026
Selective Hydrogenation of 5-Vinylnorborn-2-ene and Other Methods for the Synthesis of 2-Vinylnorbornane
N. Ushakov (2018)
10.1002/tcr.201800093
Nickel, Cobalt and Palladium Catalysed C-H Functionalization of Un-activated C(sp3 )-H Bond.
A. Mishra (2018)
10.1002/ZAAC.201800122
Structure, Bonding, Reactivity and Spectral Features of Putative NiIII=O Species: A Theoretical Perspective: Structure, Bonding, Reactivity and Spectral Features of Putative NiIII=O Species: A Theoretical Perspective
B. Pandey (2018)
See more
Semantic Scholar Logo Some data provided by SemanticScholar