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Neue Trends In Der Homogenen Übergangsmetallkatalyse

A. Behr, Andreas J. Vorholt
Published 2014 · Chemistry

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Dieser Beitrag gibt eine ausgewahlte Ubersicht uber aktuelle Entwicklungen in der homogenen Ubergangsmetallkatalyse. Im Vordergrund stehen hier vor allem technisch relevante Reaktionen, wie z. B. Hydroformylierung, Carbonylierung, Hydrierung, Oxidation, Aminierung, Metathese und resultierende Tandemreaktionen. Neben dem Einsatz klassischer petrochemischer Grundstoffe wird ebenfalls die Umsetzung nachwachsender Rohstoffe diskutiert. An ausgewahlten Beispielen werden kontinuierlich durchgefuhrte Umsetzungen der Reaktionen in Miniplants gezeigt. This contribution presents an overview of current developments in homogeneous catalysis. In this respect, the focus lies on industrial relevant reactions like hydroformylation, carbonylation, hydrogenation, oxidation, amination and metathesis and resulting tandem reactions. Beyond the classical petrochemical feedstocks, also renewables such as a sustainable feedstock are discussed. Selected examples of homogeneous catalysis in continuously operated miniplants are given.
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