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Immobilization Of Perylene-3,4,9,10-Tetracarboxylic Dianhydride On Hollow Polysulfone Fibers: Primary Amine Coupling And Fluorescence Reporting.

Laura Favaretto, Francesco Manoli, Massimo Zambianchi, Letizia Bocchi, Barbara Ventura, Ilse Manet, Manuela Melucci
Published 2019 · Medicine, Chemistry
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The fluorescent dye perylene-3,4,9,10-tetracarboxylic dianhydride (PBA) was immobilized onto polysulfone hollow fibers by means of a wet coating procedure. After immobilization, PBA was able to react with primary amines through a double anhydride ring opening reaction. The in situ amine coupling was further revealed by fluorescence analysis. Both emission (534 nm →538 nm) and fluorescence lifetime changes (2.7 ns →3.3 ns) of the dye are a useful tool to detect and visualize the occurrence of the reaction. The successful implementation of amine coupling with a reporting function on polysulfone fibers holds great interest for biomedical applications.
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