Pyrolytic Synthesis And Luminescence Of Porous Lanthanide Eu-MOF.
G. Jin, Zhi-jian Liu, Hongfa Sun, Zhiyong Tian
Published 2016 · Chemistry, Medicine
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A lanthanide metal coordination polymer [Eu2(BDC)3(DMSO)(H2O)] was synthesized by the reaction of europium oxide with benzene-1,3-dicarboxylic acid (H2BDC) in a mixed solution of dimethyl sulfoxide (DMSO) and water under hydrothermal conditions. The crystal structure of Eu2(BDC)3(DMSO)(H2O) was characterized by X-ray diffraction (XRD). Thermo-gravimetric analysis of Eu2(BDC)3(DMSO)(H2O) indicated that coordinated DMSO and H2O molecules could be removed to create Eu2(BDC)3(DMSO)(H2O)-py with permanent microporosity, which was also verified by powder XRD (PXRD) and elemental analysis. Both Eu2(BDC)3(DMSO)(H2O) and Eu2(BDC)3(DMSO)(H2O)-py showed mainly Eu-based luminescence and had characteristic emissions in the range 550-700 nm.
This paper references
Genetic Algorithms, a Nature-Inspired Tool: Survey of Applications in Materials Science and Related Fields
Wojciech Paszkowicz (2009)
Organic Framework Materials as Chemical Sensors
Lauren E. Kreno (2012)
Luminescent Open Metal Sites within a Metal–Organic Framework for Sensing Small Molecules
B. Chen (2007)
A series of three-dimensional lanthanide metal–organic frameworks with biphenylethene-4,4′-dicarboxylic acid: Hydrothermal syntheses and structures
Zhao‐Peng Deng (2010)
Single-crystal structure validation with the program PLATON
A. L. Spek (2003)
Hydrogen storage in metal-organic frameworks.
Leslie J Murray (2009)
Organic, Inorganic, and Hybrid Solar Cells: Principles and Practice
Sudhindra B. Sant (2014)
Gd2O3:Eu Nanophosphors Prepared Via Reverse Micelle Processing: Influence of Eu3+ Content on Photoluminescence Property
Jeyaseelan Chandradass (2012)
The Chemistry and Applications of Metal‐Organic Frameworks
H. Furukawa (2013)
A templated lanthanide metal-organic framework: synthesis, structure, and luminescence of (bpy) [Eu (ip)1.5(H2O)4] (bpy = 4,4′-bipyridine, ip = isophthalate)
Bowei Cai (2012)
A microporous metal-organic framework for gas-chromatographic separation of alkanes.
B. Chen (2006)
Selective turn-on ammonia sensing enabled by high-temperature fluorescence in metal-organic frameworks with open metal sites.
N. Shustova (2013)
A europium(III) based metal–organic framework: bifunctional properties related to sensing and electronic conductivity
Zhaomin Hao (2014)
Metal-organic frameworks with functional pores for recognition of small molecules.
B. Chen (2010)
Synthesis and luminescent properties of LaPO4:Eu3+ microspheres
Yuguo Yang (2013)
Three 3D Lanthanide–Organic Frameworks Based on Novel Flexible Multicarboxylates: From ssa to rtl Topologies
Fangna Dai (2011)
Multipoint interactions enhanced H2 storage and organosulfur removal in a microporous metal–organic framework
Wen-wen He (2013)
Two distinct Dy-isophthalates induced by different solvents
Xin Ying Zhang (2012)
An Open Neodymium−Organic Framework with the NbO Structure Type Based on Binuclear SBU Involved In Situ Generated Formate
Fangna Dai (2010)
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
M. Eddaoudi (2002)
A Series of Cation-Templated, Polycarboxylate-Based Cd(II) or Cd(II)/Li(I) Frameworks with Second-Order Nonlinear Optical and Ferroelectric Properties
Jian-Di Lin (2010)
Luminescent Multifunctional Lanthanides‐Based Metal—Organic Frameworks
J. Rocha (2011)
Postsynthesis modification of a porous coordination polymer by LiCl To enhance H+ transport.
Satoshi Horike (2013)
A microporous luminescent europium metal-organic framework for nitro explosive sensing.
X. Zhou (2013)
Sol–gel synthesis and photoluminescence of CaSiO3:Eu3+ nanophosphors using novel silicate sources
L. Zhou (2008)
Molecular structure, vibrational spectroscopic (FT-IR, FT-Raman), UV-vis spectra, first order hyperpolarizability, NBO analysis, HOMO and LUMO analysis, thermodynamic properties of benzophenone 2,4-dicarboxylic acid by ab initio HF and density functional method.
Kadali Chaitanya (2012)
Hydrogen storage in metal-organic frameworks.
M. P. Suh (2012)
Progress in Adsorption‐Based CO2 Capture by Metal—Organic Frameworks
J. Liu (2012)
Synthesis, crystal structures, and luminescence properties of carboxylate based rare-earth coordination polymers.
R. Decadt (2012)
SYNTHESIS OF CaWO4 AND CaWO4:Eu MICROSPHERES BY PRECIPITATION
Yuguo Yang (2014)
Highly selective luminescent sensing of fluoride and organic small-molecule pollutants based on novel lanthanide metal-organic frameworks.
J. Zhou (2013)
A luminescent mixed-lanthanide metal-organic framework thermometer.
Yuanjing Cui (2012)
Selective gas adsorption and separation in metal-organic frameworks.
J. Li (2009)
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Zirui Wang (2019)
Design of new europium-doped luminescent MOFs for UV radiation dosimetric sensing
Suelle Gisian Farias de Assis (2019)
A New 2D Europium(III) Coordination Polymer Based on 4-Bromoisophthalate Ligand: Synthesis, X-ray Structure, Luminescent and Magnetic Properties
De‐Yun Ma (2017)
An alkaline one-pot reaction to synthesize luminescent Eu-BTC MOF nanorods, highly pure and water-insoluble, under room conditions
D. Y. Medina-Velazquez (2016)
Luminescence properties of mechanochemically synthesized lanthanide containing MIL-78 MOFs.
Tarek Alammar (2018)
Efficient photocatalytic degradation of rhodamine 6G with a quantum dot-metal organic framework nanocomposite.
R. Kaur (2016)