Online citations, reference lists, and bibliographies.

Phosphotungstic Acid Encapsulated In Metal-organic Framework As Catalysts For Carbohydrate Dehydration To 5-hydroxymethylfurfural.

Yanmei Zhang, Volkan Degirmenci, Can Li, Emiel J M Hensen
Published 2011 · Medicine, Chemistry
Cite This
Download PDF
Analyze on Scholarcy
Share
MIL-101, a chromium-based metal-organic framework, is known for its very large pore size, large surface area and good stability. However, applications of this material in catalysis are still limited. 5-Hydroxymethylfurfural (HMF) has been considered a renewable chemical platform for the production of liquid fuels and fine chemicals. Phosphotungstic acid, H₃PW₁₂O₄₀ (PTA), encapsulated in MIL-101 is evaluated as a potential catalyst for the selective dehydration of fructose and glucose to 5-hydroxymethylfurfural. The results demonstrate that PTA/MIL-101 is effective for HMF production from fructose in DMSO and can be reused. This is the first example of the application of a metal-organic framework in carbohydrate dehydration.



This paper is referenced by
10.1016/J.APCATA.2018.04.038
Synthesis of cinnamyl benzoate over novel heteropoly acid encapsulated ZIF-8
Radhika S. Malkar (2018)
10.1039/c8dt00572a
H5PV2Mo10O40 encapsulated in MIL-101(Cr): facile synthesis and characterization of rationally designed composite materials for efficient decontamination of sulfur mustard.
Yanqin Li (2018)
10.1016/j.jece.2019.103601
Efficient tetracycline hydrochloride removal by encapsulated phosphotungstic acid (PTA) in MIL–53 (Fe): optimizing the content of PTA and recycling study
Sara Masoumi (2020)
10.1016/j.fuproc.2019.106272
A bifunctional recoverable catalyst based on phosphotungstic acid for cellulose hydrolysis to fermentable sugars
Haonan Qu (2020)
10.1016/j.biortech.2013.09.016
Catalytic conversion of carbohydrates into 5-hydroxymethylfurfural over cellulose-derived carbonaceous catalyst in ionic liquid.
Lei Hu (2013)
10.1016/j.ces.2020.115818
In situ bridging encapsulation of a carboxyl-functionalized phosphotungstic acid ionic liquid in UiO-66: A remarkable catalyst for oxidative desulfurization
Zhaoyang Qi (2020)
10.1039/C7GC00992E
Heterogeneous Diels–Alder catalysis for biomass-derived aromatic compounds
Amy E Settle (2017)
10.3390/molecules17043690
Coupling of Nanoporous Chromium, Aluminium-Containing Silicates with an Ionic Liquid for the Transformation of Glucose into 5-(Hydroxymethyl)-2-furaldehyde
Margarida M Antunes (2012)
10.1038/srep12821
Glucose recovery from aqueous solutions by adsorption in metal–organic framework MIL-101: a molecular simulation study
Krishna M. Gupta (2015)
10.1016/j.biombioe.2017.12.007
Catalytic conversion of glucose to 5-hydroxymethyfural over Fe/β zeolites with extra-framework isolated Fe species in a biphasic reaction system
Haian Xia (2018)
10.1039/c9cc05364f
A hydrothermally stable ytterbium metal-organic framework as a bifunctional solid-acid catalyst for glucose conversion.
David L Burnett (2019)
10.1080/01614940.2016.1128193
Acid-base properties and catalytic activity of metal-organic frameworks: A view from spectroscopic and semiempirical methods
Valentina N. Panchenko (2016)
10.20381/ruor-4031
Microwave-assisted Dehydration of Fructose into 5-Hydroxymethylfurfural (5-HMF) over Acidic Porous Catalysts
Walaa S. Baslyman (2015)
10.1039/C8RA06021E
Catalytic conversion of glucose to 5-hydroxymethylfurfural using zirconium-containing metal–organic frameworks using microwave heating
Jue Gong (2018)
10.3390/catal9100812
ZIF-8 metal organic framework for the conversion of glucose to fructose and 5-hydroxymethyl furfural
Ryan Oozeerally (2019)
10.3390/catal10050578
POM@MOF Hybrids: Synthesis and Applications
Jiamin Sun (2020)
10.1007/s13369-020-04386-w
Simultaneous Adsorption of Multi-lanthanides from Aqueous Silica Sand Solution Using Pectin–Activated Carbon Composite
Eny Kusrini (2020)
10.1016/j.ijbiomac.2018.02.023
Polyoxometalate-metal organic framework-lipase: An efficient green catalyst for synthesis of benzyl cinnamate by enzymatic esterification of cinnamic acid.
Narges Nobakht (2018)
10.1039/c9cc07842h
Glucose isomerization in dioxane/water with Sn-β catalyst: improved catalyst stability and use for HMF production.
Qiang Guo (2019)
10.1039/c9ra06170c
Phosphotungstic acid as a novel acidic catalyst for carbohydrate protection and glycosylation
Jyun-Siao Chen (2019)
10.1002/CCTC.201801889
Glucose Isomerization and Epimerization over Metal‐Organic Frameworks with Single‐Site Active Centers
Q. Luo (2019)
10.3390/CATAL9050437
Replacement of chromium by non-toxic metals in lewis-acid MOFs: Assessment of stability as glucose conversion catalysts
Ralentri Pertiwi (2019)
10.1016/j.biortech.2013.06.063
Immobilizing Cr3+ with SO3H-functionalized solid polymeric ionic liquids as efficient and reusable catalysts for selective transformation of carbohydrates into 5-hydroxymethylfurfural.
Hu Li (2013)
10.1002/9781119128113.ch1
Nanoporous Organic Frameworks for Biomass Conversion
Xiang Zhu (2017)
10.1016/j.ccr.2019.213064
Metal-organic frameworks as catalysts for sugar conversion into platform chemicals : state-of-the-art and prospects
Noor Al-Jammal (2019)
10.1016/j.pecs.2016.04.004
Efficient valorization of biomass to biofuels with bifunctional solid catalytic materials
Hu Li (2016)
10.1155/2014/978708
Catalytic Transformation of Fructose and Sucrose to HMF with Proline-Derived Ionic Liquids under Mild Conditions
Hu Li (2014)
10.1016/J.POLYMDEGRADSTAB.2018.12.004
Modification of mesoporous silica with phosphotungstic acid and its effects on the combustion and thermal behavior of polylactic acid composites
Zhengyu Feng (2019)
10.15376/biores.9.1.303-315
Sn-MCM-41 as Efficient Catalyst for the Conversion of Glucose into 5-Hydroxymethylfurfural in Ionic Liquids
Qing Xu (2013)
10.1016/B978-0-444-64127-4.00008-2
On the R&D Landscape Evolution in Catalytic Upgrading of Biomass
Atıf Emre Demet (2019)
10.14716/ijtech.v9i7.2531
Improving the quality of pyrolysis oil from co-firing high-density polyethylene plastic waste and palm empty fruit bunches
Eny Kusrini (2018)
10.1039/c9nj05572j
The promotion of proton conductivity by immobilizing molybdovanadophosphoric acids in metal–organic frameworks
Fuli Wang (2020)
See more
Semantic Scholar Logo Some data provided by SemanticScholar