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Studies Of Decomposition Of H2O2over Manganese Oxide Octahedral Molecular Sieve Materials

Hua Zhou, Yan-Fei Shen, J. Wang, X. Chen, C. O'young, S. Suib
Published 1998 · Chemistry

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Abstract A series of manganese oxide molecular sieve (OMS) materials has been successfully synthesized. Doping some divalent cations and first row transition metal ions such as Mg 2+ , Ni 2+ , Cu 2+ , Co 2+ , and Fe 3+ into the framework of OMS materials to form [M]-OMS materials was also done. The catalytic activities of [M]-OMS materials and commercial MnO 2 for H 2 O 2 decomposition were studied. The experimental results show an activity order sequence as follows: most of [M]-OMS materials > commercial MnO 2 ; [M]-OMS-2 > [M]-OMS-1; and among [M]-OMS-2 samples, [Ni]-OMS-2 > [Cu]-OMS-2 > [Fe]-OMS-2 > [Co]-OMS-2 > [Mg]-OMS-2. The kinetics and a mechanism of H 2 O 2 catalytic decomposition over [M]-OMS materials were studied and proposed, as well.
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A Green Route to Cyclohexanone: Selective Oxidation of Cyclohexanol Promoted by Non-precious Catalyst of h-WO3 Nanorods
L. Wang (2016)
Efficient hydrogen peroxide decomposition on bimetallic Pt–Pd surfaces
M. Hasnat (2010)
Effect of substrate on the characteristics of manganese(IV) oxide thin films prepared by atomic layer deposition
O. Nilsen (2004)
A Novel Kinetics Study on H2O2 Decomposition inthe Propylene Epoxidation System in a Fixed-Bed Reactor
L. Wang (2013)
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D. J. Davis (2014)
Decomposition of the Methylene Blue Dye Using Layered Manganese Oxide Materials Synthesized by Solid State Reactions
M. E. Becerra (2018)
Efficient degradation of organic pollutants with ferrous hydroxide colloids as heterogeneous Fenton-like activator of hydrogen peroxide.
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The distinct effects of Mn substitution on the reactivity of magnetite in heterogeneous Fenton reaction and Pb(II) adsorption.
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