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The Morphology Of Crystalline Synthetic Polymers

F. Khoury, E. Passaglia
Published 1976 · Materials Science

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Crystalline organic high polymers in their solid state have very complex morphologies. This is due to the chainlike nature of their constituent molecules, which leads to crystallization behavior and morphologies that are in most aspects only rarely encountered in more traditional “small molecule” solids, and in other aspects are unique to polymers. Moreover, this chainlike nature leads to a wealth of phenomena and a rich diversity of morphological behavior that is, on the one hand, a boon to the experimentalist, for it provides an almost endless source of study, and, on the other hand, a source of despair for those who, like ourselves, attempt to summarize the behavior of these materials. There is a real danger that too great a preoccupation with the details of the morphology of one or two individual polymers will both obscure important aspects of behavior common to all polymers and also mislead the reader into perceiving a simplicity that in fact does not exist.
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