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Size-fractionated Characterization And Quantification Of Nanoparticle Release Rates From A Consumer Spray Product Containing Engineered Nanoparticles
H. Hagendorfer, Christiane S. Lorenz, R. Kaegi, B. Sinnet, R. Gehrig, N. Goetz, M. Scheringer, C. Ludwig, A. Ulrich
Published 2010 · Materials Science
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This study describes methods developed for reliable quantification of size- and element-specific release of engineered nanoparticles (ENP) from consumer spray products. A modified glove box setup was designed to allow controlled spray experiments in a particle-minimized environment. Time dependence of the particle size distribution in a size range of 10–500 nm and ENP release rates were studied using a scanning mobility particle sizer (SMPS). In parallel, the aerosol was transferred to a size-calibrated electrostatic TEM sampler. The deposited particles were investigated using electron microscopy techniques in combination with image processing software. This approach enables the chemical and morphological characterization as well as quantification of released nanoparticles from a spray product. The differentiation of solid ENP from the released nano-sized droplets was achieved by applying a thermo-desorbing unit. After optimization, the setup was applied to investigate different spray situations using both pump and gas propellant spray dispensers for a commercially available water-based nano-silver spray. The pump spray situation showed no measurable nanoparticle release, whereas in the case of the gas spray, a significant release was observed. From the results it can be assumed that the homogeneously distributed ENP from the original dispersion grow in size and change morphology during and after the spray process but still exist as nanometer particles of size <100 nm. Furthermore, it seems that the release of ENP correlates with the generated aerosol droplet size distribution produced by the spray vessel type used. This is the first study presenting results concerning the release of ENP from spray products.
This paper references
Exposure of engineered nanoparticles to human lung epithelial cells: influence of chemical composition and catalytic activity on oxidative stress.
Ludwig K. Limbach (2007)
Particle emissions of a railway line determined by detailed single particle analysis
R. Lorenzo (2006)
Ultrafine (nanometre) particle mediated lung injury
K. Donaldson (1998)
Development of an Electrostatic Precipitator for Off-Line Particle Analysis
J. Dixkens (1999)
Single walled carbon nanotubes (SWCNT) affect cell physiology and cell architecture
J. Kaiser (2008)
In vitro evaluation of possible adverse effects of nanosized materials
P. Wick (2006)
TEM study on volatility and potential presence of solid cores in nucleation mode particles from diesel powered passenger cars
U. Kirchner (2009)
Ultrafine particles: mechanisms of lung injury
K. Donaldson (2000)
Inhalational and dermal exposures during spray application of biocides.
E. Berger-Preiss (2005)
Occupational exposure to permethrin during its use as a public hygiene insecticide.
D. M. Llewellyn (1996)
Philos Trans R Soc A
Nanomaterial cell interactions: how do carbon nanotubes affect cell physiology?
J. Kaiser (2009)
A POINT-TO-PLANE ELECTROSTATIC PRECIPITATOR FOR PARTICLE SIZE SAMPLING.
P. Morrow (1964)
Analysis of additive metals in fuel and emission aerosols of diesel vehicles with and without particle traps
A. Ulrich (2003)
Evaluation of the Measurement Performance of the Scanning Mobility Particle Sizer and Aerodynamic Particle Sizer
C. Sioutas (1999)
Measuring aerosol size distributions with the fast integrated mobility spectrometer
J. Olfert (2008)
Iron, manganese and copper emitted by cargo and passenger trains in Zürich (Switzerland): Size-segregated mass concentrations in ambient air
N. Bukowiecki (2007)
Aircraft disinsection: exposure assessment and evaluation of a new pre-embarkation method.
E. Berger-Preiss (2006)
Continuous flow, single-particle-counting condensation nucleus counter
J. K. Agarwal (1980)
Nanoscience and nanotechnologies: opportunities and uncertainties, vol 1
Electrostatic aerosol sampler for light and electron microscopy.
B. Liu (1967)
Dermal and respiratory exposure to applicators and occupants of residences treated with dichlorvos (DDVP).
R. Gold (1984)
Contribution of railway traffic to local PM10 concentrations in Switzerland
R. Gehrig (2007)
Acute Respiratory Syndrome After Inhalation of Waterproofing Sprays: A Posteriori Exposure-Response Assessment in 102 Cases
D. Vernez (2006)
An improved low-flow thermodenuder
M. Fierz (2007)
Reviewing the environmental and human health knowledge base of carbon nanotubes.
A. Helland (2008)
Evaluation of the ELPI for diesel soot measurements
C. V. Gulijk (2000)
Number size distribution of particulate emissions of heavy-duty engines in real world test cycles
U. Lehmann (2003)
In vitro cytotoxicity of oxide nanoparticles: comparison to asbestos, silica, and the effect of particle solubility.
T. Brunner (2006)
Nanoparticle inhalation augments particle-dependent systemic microvascular dysfunction
T. Nurkiewicz (2007)
The degree and kind of agglomeration affect carbon nanotube cytotoxicity.
P. Wick (2007)
Pyrethroids as household insecticides: analysis, indoor exposure and persistence
T. Class (1991)
J Nanopart Res
Optimal preparation of water samples for the examination of colloidal material by transmission electron microscopy
Charles-Philippe Lienemann (1998)
Source apportionment of particulate matter in Europe: A review of methods and results
M. Viana (2008)
The potential risks of nanomaterials: a review carried out for ECETOC
P. Borm (2006)
In-flight spraying in aircrafts: determination of the exposure scenario.
E. Berger-Preiss (2004)
Nanoparticles in the Environment as Revealed by Transmission Electron Microscopy:Detection, Characterisation and Activities
G. G. Leppard (2012)
Aerosol classification by electric mobility: apparatus, theory, and applications
E. Knutson (1975)
Toxicology of nanoparticles: A historical perspective
G. Oberdoerster (2007)
Ultrafine particle-lung interactions: does size matter?
W. Kreyling (2006)
Electrical low pressure impactor
J. Keskinen (1992)
Theoretical and Experimental Evaluation of a Portable Electrostatic TEM Sampler
M. Fierz (2007)
The Behaviour of Pyrethroids Indoors: A Model Study
Edith Berger‐preieß (1997)
Application of the focused ion beam technique in aerosol science: detailed investigation of selected, airborne particles
R. Kaegi (2006)
Chemical characterisation of PM2.5, PM10 and coarse particles at urban, near-city and rural sites in Switzerland
C. Hueglin (2005)
A three-dimensional cellular model of the human respiratory tract to study the interaction with particles.
B. Rothen-Rutishauser (2005)
Results of the first air ion spectrometer calibration and intercomparison workshop
E. Asmi (2008)
Toxic Potential of Materials at the Nanolevel
A. Nel (2006)
Translocation of particles and inflammatory responses after exposure to fine particles and nanoparticles in an epithelial airway model
B. Rothen-Rutishauser (2007)
Nanotoxicology: An Emerging Discipline Evolving from Studies of Ultrafine Particles
G. Oberdörster (2005)
Source apportionment of particulate matter
M Viana (2008)
Trace metals in ambient air: Hourly size-segregated mass concentrations determined by synchrotron-XRF.
N. Bukowiecki (2005)
This paper is referenced by
Fine Particles – Measurements and Exposure in View of Health Effects
T. Kuhlbusch (2013)
Combination of cloud point extraction with single particle inductively coupled plasma mass spectrometry to characterize silver nanoparticles in soil leachates
L. Torrent (2019)
Silver nanoparticles and total aerosols emitted by nanotechnology-related consumer spray products.
M. E. Quadros (2011)
Characterization of water-based paints containing titanium dioxide or carbon black as manufactured nanomaterials before and after atomization
Ornella Fichera (2019)
Methods for the Measurement of Release of MWCNTs from MWCNT-Polymer Composites | NIST
D. L. Kaiser (2014)
The impact of nanomaterial characteristics on inhalation toxicity.
Frank S Bierkandt (2018)
Current trends and challenges in sample preparation for metallic nanoparticles analysis in daily products and environmental samples: A review
I. Calle (2016)
Investigating the immunotoxicology of silver nanoparticles in vitro
A. Hastings (2012)
Influence of spray-coating process parameters on the release of TiO2 particles for the production of antibacterial textile
Simona Ortelli (2020)
Characterization of silver nanoparticle products using asymmetric flow field flow fractionation with a multidetector approach--a comparison to transmission electron microscopy and batch dynamic light scattering.
H. Hagendorfer (2012)
Physical and chemical characterization of fly ashes from Swiss waste incineration plants and determination of the ash fraction in the nanometer range.
J. Buha (2014)
Nanoparticles-containing spray can aerosol: characterization, exposure assessment, and generator design
B. Chen (2010)
A hyphenated SMPS-ICPMS coupling setup: Size-resolved element specific analysis of airborne nanoparticles
Adrian Hess (2015)
Imaging and Characterization of Engineered Nanoparticles in Sunscreens by Electron Microscopy, Under Wet and Dry Conditions
Christiane S. Lorenz (2010)
International Standardization in Particle Characterization for Quality and Safety Assessment in Particle Technology
M. Stintz (2015)
Metody badania pylistości nanomateriałów
E. Jankowska (2016)
Emissions from Consumer Products Containing Engineered Nanomaterials over Their Lifecycle
B. Nowack (2014)
Epoxy-graphene-related material composites: Nanostructure characterization and release quantification
Tobias Hammer (2020)
A review of models for near-field exposure pathways of chemicals in consumer products.
L. Huang (2017)
Hyphenated Analytical Techniques for Studying the Speciation and Fate of Contaminants and Nanoparticles in Waste Treatment and Bioenergy Processes
D. Foppiano (2019)
Characteristics of exposure factors and inhalation exposure to selected spray consumer products in Korean population.
H. Shin (2019)
Measuring air borne nanoparticles for characterizing hyphenated RDD-SMPS-ICPMS instrumentation
A. Hess (2016)
The ecotoxicological and environmental behaviour and transformations of silver nanoparticles
Isabella Romer Roche (2013)
Nanotechnology: A Review of Exposure, Health Risks and Recent Regulatory Developments
C. Green (2011)
Potential for Inhalation Exposure to Engineered Nanoparticles from Nanotechnology-Based Cosmetic Powders
Y. Nazarenko (2012)
Effects of alginate on stability and ecotoxicity of nano-TiO2 in artificial seawater.
Sarah Callegaro (2015)
Environmental and health effects of nanomaterials in nanotextiles and façade coatings.
C. Som (2011)
Potential impacts of silver nanoparticles on bacteria in the aquatic environment.
Zhiya Sheng (2017)
BIOSORPTION OF SILVER NANOPARTICLES USING ASPERGILLUS TERREUS DEAD BIOMASS
Comparative modeling of exposure to airborne nanoparticles released by consumer spray products
C. Riebeling (2016)
Influence of instruments performance and material properties on exposure assessment of airborne engineered nanomaterials
M. Levin (2015)
Quantitative assessment of inhalation exposure and deposited dose of aerosol from nanotechnology-based consumer sprays.
Y. Nazarenko (2014)See more