Online citations, reference lists, and bibliographies.
← Back to Search

Clean Alternative For Adipic Acid Synthesis Via Liquid-Phase Oxidation Of Cyclohexanone And Cyclohexanol Over H3−2xCoxPMo12O40 Catalysts With Hydrogen Peroxide

Sihem Benadji, T. Mazari, L. Dermeche, N. Salhi, E. Cadot, C. Rabia
Published 2013 · Chemistry

Save to my Library
Download PDF
Analyze on Scholarcy
Adipic acid (AA) was synthesized from the oxidation of cyclohexanol (-ol), cyclohexanone (-one) and cyclohexanol/cyclohexanone (-ol/-one) mixture over a series of H3−2xCoxPMo12O40 (x: 0.0–1.5) Keggin-type polyoxometalates as catalysts in the presence of hydrogen peroxide (30 %) under mild conditions (90 °C, 20 h) and in solvent free. The heteropolysalts were prepared from H3PMo12O40 and Ba(OH)2 using the cationic exchange method and characterized by Infrared and diffuse reflectance UV–Vis spectroscopies, X-ray diffraction and TG analyses. The catalytic tests showed that salts are more efficient than the corresponding heteropolyacid and among the H3−2xCoxPMo12O40 (x: 0.25–1.5) series, H1Co1PMo12 exhibits the highest AA yield for whole substrates, with ca. 76, 53 and 43 % from oxidation of -one, -ol and -ol/-one, respectively.Graphical Abstract
This paper references
Evidence for the presence of alternative mechanisms in the oxidation of cyclohexanone to adipic acid with oxygen, catalysed by Keggin polyoxometalates
F. Cavani (2010)
Titanium and cerium-containing mesoporous silicate materials as catalysts for oxidative cleavage of cyclohexene with H2O2: A comparative study of catalytic activity and stability
M. Timofeeva (2008)
Direct Conversion of Cyclohexane into Adipic Acid with Molecular Oxygen Catalyzed by N-Hydroxyphthalimide Combined with Mn(acac)2 and Co(OAc)2
T. Iwahama (1998)
Oxidation of cyclohexane, cyclohexanone, and cyclohexanol to adipic acid by a non-HNO3 route over Co/Mn cluster complexes
S. Chavan (2002)
A “one-pot” synthesis of adipic acid from cyclohexene under mild conditions with new bifunctional Ti-AlSBA mesostructured catalysts
G. Lapisardi (2004)
An Industrial Process for Adipic Acid Production by the Liquid-Phase Oxidation of Cyclohexanone with Molecular Oxygen
A. Shimizu (2003)
Innovative direct synthesis of adipic acid by air oxidation of cyclohexane
D. Bonnet (2006)
One-step aerobic oxidation of cyclohexane to adipic acid using an Anderson-type catalyst [(C18H37)2N(CH3)2]6Mo7O24
Hongying Lü (2012)
Preparation and characterization of mixed ammonium salts of Keggin phosphomolybdate
L. Dermeche (2009)
Influence of reaction conditions on product distribution in the green oxidation of cyclohexene to adipic acid with hydrogen peroxide
Peng Jin (2011)
Heterogeneous catalytic decomposition of nitrous oxide
F. Kapteijn (1996)
Synthesis of adipic acid catalyzed by surfactant-type peroxotungstates and peroxomolybdates
Wenshuai Zhu (2008)
Preparation and Characterization of 12-Molybdophosphoric and 12-Molybdosilicic Acids and Their Metal Salts
G. Tsigdinos (1974)
Clean synthesis of adipic acid catalyzed by complexes derived from heteropoly acid and glycine
S. Ren (2009)
Catalysis by heteropolyacid—VII. catalytic oxidation of cyclohexanol by dodecamolybdate
K. Nomiya (1984)
Preparation, characterisation and catalytic activity of new bifunctional Ti–AlSBA15 materials. Application to a “one-pot” green synthesis of adipic acid from cyclohexene and organic hydroperoxides ☆
G. Lapisardi (2005)
Adipic acid yields as a function of the compositon of cyclohexanone/cyclohexanol mixture over Co1PMo12O40 Substrate (-one/-ol
A Castellan (1991)
Oxidation of propane over ammonium-transition metal mixed keggin phosphomolybdate salts
T. Mazari (2010)
Synthesis of adipic acid via nitric acid oxidation of cyclohexanol in a two-step continuous process
A. Castellan (1991)
Synthesis of adipic acid via the nitric acid oxidation of cyclohexanol in a two-step batch process
A. Castellan (1991)
Effective Dawson type polyoxometallate catalysts for methanol oxidation
L. Dermeche (2012)
Main aspects of the selective oxidation of isobutane to methacrylic acid catalyzed by Keggin-type polyoxometalates
F. Cavani (2001)
Oxidation of propane over substituted Keggin phosphomolybdate salts
T. Mazari (2009)
Microporous Mesoporous Mater
G Lapisardi (2005)
Nitric acid oxidation design in the manufacture of adipic acid from cyclohexanol and cyclohexanone
A. Lindsay (1954)
Highly Efficient Utilization of Hydrogen Peroxide for Selective Oxygenation of Alkanes Catalyzed by Diiron-Substituted Polyoxometalate Precursor
N. Mizuno (1998)
Vibrational investigations of polyoxometalates. 2. Evidence for anion-anion interactions in molybdenum(VI) and tungsten(VI) compounds related to the Keggin structure
C. Rocchiccioli-deltcheff (1983)
Nitric acid reaction of cyclohexanol to adipic acid
A. Castellan (1991)

This paper is referenced by
Recent Progress in Adipic Acid Synthesis Over Heterogeneous Catalysts
W. Yan (2020)
Triphenylamine-based porous organic polymers: Synthesis and application for supporting phosphomolybdate to fabricate efficient olefin oxidation catalysts
Xiaojing Song (2017)
Green Oxidation of Cyclohexanone to Adipic Acid over Phosphotungstic Acid Encapsulated in UiO-66
Jian Feng (2019)
Polyoxometalates as bifunctional templates: engineering metal oxides with mesopores and reactive surfaces for catalysis
Yan Leng (2019)
Transition metal-substituted Keggin-type polyoxometalates as catalysts for adipic acid production
Sihem Mouanni (2019)
Cyclohexanone Oxidation over H3PMo12O40 Heteropolyacid via Two Activation Modes Microwave Irradiation and Conventional Method
Yasmina Idrissou (2019)
Preparation and characterization of H 3?2( x + y ) Mn x Co y PMo 12 O 40 heteropolysalts. Application to adipic acid green synthesis from cyclohexanone oxidation with hydrogen peroxide
Sihem Mouanni (2019)
Clean Adipic Acid Synthesis from Liquid-Phase Oxidation of Cyclohexanone and Cyclohexanol Using (NH4)xAyPMo12O40 (A: Sb, Sn, Bi) Mixed Heteropolysalts and Hydrogen Peroxide in Free Solvent
L. Mouheb (2017)
Keggin-Type Mixed Polyoxomolybdates Catalyzed Cyclohexanone Oxidation by Hydrogen Peroxide: In Situ IR Pyridine Adsorption
L. Mouheb (2020)
A Green Route to Cyclohexanone: Selective Oxidation of Cyclohexanol Promoted by Non-precious Catalyst of h-WO3 Nanorods
L. Wang (2016)
Single-Atom Mn Active Site in a Triol-Stabilized β-Anderson Manganohexamolybdate for Enhanced Catalytic Activity towards Adipic Acid Production
J. Luo (2018)
Preparation, Characterization and Reactivity of Keggin Type Phosphomolybdates, H3−2xNixPMo12O40 and (NH4)3−2xNixPMo12O40, for Adipic Acid Synthesis
A. Tahar (2014)
Dawson-type polyoxometalates as green catalysts for adipic acid synthesis
M. Moudjahed (2016)
Organic Salts and Merrifield Resin Supported [PM12O40]3− (M = Mo or W) as Catalysts for Adipic Acid Synthesis
Jana Pisk (2019)
Phosphotungstic acid encapsulated in USY zeolite as catalysts for the synthesis of cyclohexylbenzene
Yufei Yang (2020)
Highly dispersed metal incorporated hexagonal mesoporous silicates for catalytic cyclohexanone oxidation to adipic acid
W. Yan (2020)
Kinetic study for the oxidation of cyclohexanol and cyclohexanone with nitric acid to adipic acid
De-Tao Pan (2020)
The primary stages of polyoxomolybdate catalyzed cyclohexanone oxidation by hydrogen peroxide as investigated by in situ NMR. Substrate activation and evolution of the working catalyst
D. Amitouche (2018)
Semantic Scholar Logo Some data provided by SemanticScholar