Online citations, reference lists, and bibliographies.
← Back to Search

D-band Broadening Of Noble-metal Particles

E. Anno
Published 1992 · Chemistry

Save to my Library
Download PDF
Analyze on Scholarcy
Share
Abstract For Cu particles embedded in a SiO 2 matrix, the size-dependent change in the width of the d-band has been investigated in the size region from about 35 to 160 A in diameter by measuring the energy position of the interband-transition absorption of Cu island films in the photon-energy region from 1.5 to 6.5 eV. This position gives the energy spacing which reflects the width of the d-band. Below about 100 A in diameter, the energy spacing increased with decreasing particle size. This increase supports the d-band broadening due to lattice contractions.
This paper references
10.1103/PHYSREVB.30.672
Extended x-ray-absorption fine-structure study of Ag particles isolated in solid argon
P. Montano (1984)
10.1088/0305-4608/7/4/013
Theory of energy bands and related properties of 4d transition metals. I. Band parameters and their volume dependence
D. G. Pettifor (1977)
10.1103/PHYSREVLETT.43.165
Extended X-Ray-Absorption Fine Structure of Small Cu and Ni Clusters: Binding-Energy and Bond-Length Changes with Cluster Size
G. Apai (1979)
10.1103/PHYSREVB.27.3176
Photoemission from surface-atom core levels, surface densities of states, and metal-atom clusters: A unified picture
P. Citrin (1983)
10.1002/PSSB.2221010236
Equation d'état et structure de bandes d'énergie de l'argent métallique
F. Perrot (1980)
10.1103/PHYSREVB.21.2201
Self-consistent local-orbital method for calculating surface electronic structure: Application to Cu (100)
Joshua R. Smith (1980)
10.1103/PHYSREVB.33.5384
Noble- and transition-metal clusters: The d bands of silver and palladium.
Wertheim (1986)
10.1103/PHYSREVB.6.4370
Optical Constants of the Noble Metals
P. Johnson (1972)
10.1103/PHYSREVLETT.56.2076
Structure of copper microclusters isolated in solid argon.
Montaño (1986)
10.1103/PHYSREVB.24.1895
Empirical band calculations of the optical properties of d -band metals. I. Cu, Ag, and Au
R. Lässer (1981)
10.1103/PHYSREVB.32.2126
Optical properties of well-defined granular metal systems.
Yamaguchi (1985)
10.1103/PHYSREVB.15.1613
Renormalized atoms: Cohesion in transition metals
C. D. Gelatt (1977)
10.1143/JPSJ.50.1209
Influence of Lattice Defects on the Width of Plasma Resonance Absorption of Silver Island Films
E. Anno (1981)
10.1103/PHYSREVB.18.674
Optical properties of discontinuous gold films
S. Norrman (1978)
10.1103/PHYSREVB.29.5458
Pressure dependence of the d -band to Fermi-level excitation threshold in silver
H. Tups (1984)
10.1103/PHYSREVB.36.6336
Surface effects in metal microclusters.
Jiang (1987)



This paper is referenced by
10.1063/1.369207
Optical study of continuous thin films and island films of Ir: Interband absorption and localization of conduction electrons of Ir
E. Anno (1999)
10.1103/PHYSREVB.66.165442
Size-dependent change in interband absorption of Pb particles: Effects of surface atoms
E. Anno (2002)
10.1063/1.2033151
Size-dependent change in interband absorption and broadening of optical plasma-resonance absorption of indium particles
E. Anno (2005)
10.1016/0039-6028(93)91495-B
Effects of surface charge on the second harmonic generation from a Cu electrode
T. D. Hewitt (1993)
10.1063/1.3496682
Broad energy-bands of continuous-network-structure molybdenum films
E. Anno (2010)
10.1016/0167-2584(92)90216-R
Electronic structure of palladium deposits on alumina
P. Légaré (1992)
10.1063/1.2963710
Interband absorption of vanadium studied by probing the size-dependent change in energy bands of vanadium particles
E. Anno (2008)
10.1016/S0167-5729(00)00010-8
The metallicity of thin films and overlayers
P. Dowben (2000)
10.1109/ICMULT.2010.5629860
Parallel Video Image Deblurring Computation on a Dual Core Cluster
Shufang Zou (2010)
10.1016/0039-6028(95)01211-7
Electronic structure of Pd clusters in the tight-binding approximation: influence of spd-hybridization
C. Mottet (1996)
Dynamique de la réponse optique non-linéaire ultra-rapide d'una assemblée de nanoparticules d'or
Y. Guillet (2007)
10.1016/0039-6028(92)90956-7
s-d hybridization enhancement of noble metal particles
E. Anno (1992)
Modélisation par la méthode FDTD des plasmons de surface localisés
M. Hamidi (2012)
Semantic Scholar Logo Some data provided by SemanticScholar