Online citations, reference lists, and bibliographies.
← Back to Search

Bis(benzotriazol-1-yl) Methylimine As A Novel Cyanating Agent For Labile β-diketonates

S. Thambidurai, K. Jeyasubramanian, S. K. Ramalingam
Published 1996 · Chemistry

Cite This
Download PDF
Analyze on Scholarcy
Share
Abstract Bis(benzotriazol-l-yl) methylimine was used as a novel electrophilic cyanating agent for labile β-diketonates (M = Cu II , Ni II , Co II , Zn II and Cd II ). The actual cyanating species was 1 -cyanobenzotriazole formed in situ with the elimination of benzotriazole. The labile metal-oxygen bond in the chelates possibly induced debenzotriazolation. The inert and less labile β-diketonates did not undergo this reaction. The final product of the reaction, however, was the mixed-ligand complex of cyano-β-diketone and benzotriazole, identified by spectral and analytical methods. Copyright © 1996 Elsevier Science Ltd
This paper references



This paper is referenced by
Semantic Scholar Logo Some data provided by SemanticScholar