Online citations, reference lists, and bibliographies.
Referencing for people who value simplicity, privacy, and speed.
Get Citationsy
← Back to Search

Selection Of Oxygen Reduction Catalysts For Rechargeable Lithium–air Batteries—Metal Or Oxide?

H. Cheng, K. Scott
Published 2011 · Materials Science

Save to my Library
Download PDF
Analyze on Scholarcy Visualize in Litmaps
Share
Reduce the time it takes to create your bibliography by a factor of 10 by using the world’s favourite reference manager
Time to take this seriously.
Get Citationsy
Abstract Carbon-supported Pd and PdO nanocatalysts were synthesised using either chemical reduction or thermal synthesis procedures and were used as model metal and oxide catalysts for oxygen reduction in rechargeable lithium–air batteries. The Pd metal catalyst showed excellent initial performance, e.g. a discharge capacity of 855 mAh (g solids) −1 . However, the PdO catalyst displayed superior capacity retention to the Pd catalyst, producing a discharge capacity of 336 mAh (g solids) −1 after 10 cycles, i.e. the capacity retention was 6% per cycle. The activity and stability of Pd metal and oxide catalysts were found to be closely related to their intrinsic catalytic properties and structural changes during charge/discharge cycles in Li–air batteries. The implication of such a difference is discussed. Model Pd/C and PdO/C catalysts were compared with other widely used carbon-supported metal and oxide catalysts, including Pt/C, Ru/C, RuO 2 /C and MnO 2 /C.
This paper references
10.1016/0378-7753(93)80102-U
Electrochemical study of the passivating layer on lithium intercalated carbon electrodes in nonaqueous solvents
B. Simon (1993)
10.1021/ja2021747
Reactions in the rechargeable lithium-O2 battery with alkyl carbonate electrolytes.
S. Freunberger (2011)
10.1016/J.SSI.2008.01.095
Energy storage beyond the horizon: Rechargeable lithium batteries
P. Bruce (2008)
10.1098/rspa.1961.0122
Electron spin resonance in carbons: the effect of surface oxide formation
H. Harker (1961)
10.1149/1.2220972
An Examination of the Electrochemical Behavior of Palladium Electrodes in Acid
L. D. Burke (1993)
10.1016/J.JPOWSOUR.2009.08.088
Discharge characteristic of a non-aqueous electrolyte Li/O2 battery
S. Zhang (2010)
10.1039/B910217E
Purification of carbon nanotubes by dynamic oxidation in air
N. Dementev (2009)
Chem
T. Ogasawara (2006)
10.1016/J.ELECTACTA.2007.06.056
Effect of synthetic reducing agents on morphology and ORR activity of carbon-supported nano-Pd–Co alloy electrocatalysts
Lei Zhang (2007)
10.1016/0025-5408(83)90138-1
Lithium insertion into manganese spinels
M. M. Thackeray (1983)
10.1016/S0039-6028(00)00599-9
The oxidation of Pd(111)
G. Zheng (2000)
10.1021/JA00020A086
Emission FTIR study of C60 thermal stability and oxidation
A. M. Vassallo (1991)
10.1016/J.CATTOD.2005.07.074
N2O decomposition coupled with ethanol oxidative dehydrogenation reaction on carbon-supported copper catalysts promoted by palladium and cobalt
E. Sales (2005)
10.1016/0013-4686(90)85068-X
"Inner" and "outer" active surface of RuO2 electrodes
S. Ardizzone (1990)
10.1016/S1388-2481(99)00123-X
An electrochemical impedance spectroscopic study of the transport properties of LiNi0.75Co0.25O2
F. Croce (1999)
10.1177/001452469000101110
"J."
G.G. Stokes (1890)
10.1016/S0378-7753(02)00310-5
Two- and three-electrode impedance spectroscopy of lithium-ion batteries
J. Y. Song (2002)
10.1002/anie.201100879
Oxygen reactions in a non-aqueous Li+ electrolyte.
Zhangquan Peng (2011)
10.1016/0022-4596(71)90045-4
Crystal growth and semiconductivity of palladium oxide
D. B. Rogers (1971)
10.1038/174797A0
Paramagnetic Resonance in Carbonaceous Solids
D. Ingram (1954)
10.1149/1.2048480
Air Electrode: Identification of Intraelectrode Rate Phenomena via AC Impedance
S. Ahn (1995)
10.1021/JA056811Q
Rechargeable LI2O2 electrode for lithium batteries.
Takeshi Ogasawara (2006)
10.1149/1.2048590
Role of Structural and Electronic Properties of Pt and Pt Alloys on Electrocatalysis of Oxygen Reduction An In Situ XANES and EXAFS Investigation
S. Mukerjee (1995)
10.1016/S0926-860X(96)00327-4
Electrochemical investigations on carbon supported palladium catalysts
R. Pattabiraman (1997)
10.1126/SCIENCE.1060928
Carbon Nanotubes--the Route Toward Applications
R. Baughman (2002)
10.1149/1.2044017
Structural and Kinetic Characterization of Lithium Intercalation into Carbon Anodes for Secondary Lithium Batteries
Norio Takami (1995)
10.1016/S0013-4686(98)00123-6
Carbon supported and unsupported Pt–Ru anodes for liquid feed direct methanol fuel cells
L. Liu (1998)
10.1016/S0013-4686(96)00195-8
Kinetics of oxygen reduction at oxide-derived Pd electrodes in alkaline solution
C. Chang (1997)
10.1142/P291
Lithium-ion batteries : solid-electrolyte interphase
P. Balbuena (2004)
10.1016/0378-7753(93)80126-A
The versatility of MnO2 for lithium battery applications
M. Thackeray (1993)
10.1149/1.2086855
Studies of Lithium Intercalation into Carbons Using Nonaqueous Electrochemical Cells
R. Fong (1990)
10.1021/jz200352v
Solvents' Critical Role in Nonaqueous Lithium-Oxygen Battery Electrochemistry.
B. McCloskey (2011)
CRC Handbook of Chemistry and Physics
R. C. Weast (1973)
10.1016/S0009-2614(01)01472-5
Atomistic description of oxide formation on metal surfaces: the example of ruthenium
K. Reuter (2002)
10.1016/J.ELECOM.2005.01.007
Electrocatalytic reactivity for oxygen reduction of palladium-modified carbon nanotubes synthesized in supercritical fluid
Y. Lin (2005)
10.1016/S0254-0584(97)80052-1
An investigation of thermally prepared electrodes for oxygen reduction in alkaline solution
C. Chang (1997)
10.1016/0378-7753(93)80183-P
Inorganic film-forming electrolyte additives improving the cycling behaviour of metallic lithium electrodes and the self-discharge of carbon—lithium electrodes
J. Besenhard (1993)
10.1021/IE101553F
Cyclic Voltammetric Preparation of Palladium Nanoparticles for Ethanol Oxidation Reaction
Keqiang Ding (2010)
10.1016/J.ELECTACTA.2008.04.032
Low temperature preparation of carbon-supported PdCo alloy electrocatalysts for methanol-tolerant oxygen reduction reaction
Xiaowei Li (2008)
10.1016/S0378-7753(97)02708-0
Electrochemical impedance spectra of full cells: Relation to capacity and capacity-rate of rechargeable Li cells using LiCoO2, LiMn2O4, and LiNiO2 cathodes
J. Fan (1998)
10.1016/J.JPOWSOUR.2011.02.060
Investigation of the rechargeability of Li–O2 batteries in non-aqueous electrolyte
J. Xiao (2011)
10.1016/S1388-2481(03)00053-5
Nanoporous amorphous manganese oxide as electrocatalyst for oxygen reduction in alkaline solutions
Jingsi Yang (2003)
10.1149/1.2811864
Comparison Between Electrochemical Properties of Aligned Carbon Nanotube Array and Entangled Carbon Nanotube Electrodes
H. Zhang (2008)
10.1016/S0008-6223(98)00307-8
Air-oxidation and anodization of pitch-based carbon fibers
A. Fukunaga (1999)
10.1016/J.ELECTACTA.2006.05.028
The influence of a new fabrication procedure on the catalytic activity of ruthenium–selenium catalysts
H. Cheng (2006)
10.1016/S0022-0728(01)00749-5
Effect of the protonation level of poly(o-phenylenediamine) (PoPD) on the ac impedance of humidity-sensitive PoPD/poly(vinyl alcohol) composite film
T. Tonosaki (2002)
10.1007/BF01910709
Thermal investigation of active carbons in presence of air
J. Skowroński (1979)
10.1021/LA9807863
Role of hydrous ruthenium oxide in Pt-Ru direct methanol fuel cell anode electrocatalysts: The importance of mixed electron/proton conductivity
D. R. Rolison (1999)
10.1149/1.1393943
AC Impedance Analysis of Bifunctional Air Electrodes for Metal‐Air Batteries
H. Arai (2000)
10.1149/1.1836378
A Polymer Electrolyte‐Based Rechargeable Lithium/Oxygen Battery
K. M. Abraham (1996)
10.1038/451652a
Building better batteries
M. Armand (2008)
Chem
M. S. Wu (2005)
10.5796/ELECTROCHEMISTRY.78.403
Rechargeable Li-Air Batteries with Carbonate-Based Liquid Electrolytes
Fuminori Mizuno (2010)
10.1016/S0013-4686(01)00511-4
Modification of carbon supported catalysts to improve performance in gas diffusion electrodes
N. Jia (2001)
10.1016/J.JPOWSOUR.2010.04.064
Characterizing capacity loss of lithium oxygen batteries by impedance spectroscopy
Mojtaba Mirzaeian (2010)
10.1016/J.JPOWSOUR.2007.06.180
An O2 cathode for rechargeable lithium batteries: The effect of a catalyst
A. Débart (2007)
10.1149/1.2069510
The Impedance of Lithium Electrodes in LiPF6 ‐ Based Electrolytes
Norio Takami (1992)
10.1016/0008-6223(93)90130-3
Effect of surface oxygen groups of carbon supports on the characteristics of Pd/C catalysts
D. J. Suh (1993)
10.1016/J.IJHYDENE.2010.12.098
Synergistic effect of Co alloying and surface oxidation on oxygen reduction reaction performance for
Yuchen Wei (2011)
10.1021/LA0610553
Palladium monolayer and palladium alloy electrocatalysts for oxygen reduction.
M. H. Shao (2006)
10.1021/J150611A029
Role of interfacial phenomena in the behavior of alumina-supported palladium crystallites in oxygen
J. Chen (1981)
10.1038/35035045
Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries
P. Poizot (2000)
10.1007/BF00570517
The semiconductivity and stability of palladium oxide
E. Rey (1978)
10.1016/0022-4596(87)90350-1
Synthesis and characterization of small platinum particles formed by the chemical reduction of chloroplatinic acid
P. V. Rheenen (1987)
10.1016/J.CATCOM.2008.08.016
Methane combustion activity of unsupported PdO–ZrO2 binary oxides
Samed Ahmed Jalal (2008)
10.1149/1.1393616
Novel Microporous Poly(vinylidene fluoride) Blend Electrolytes for Lithium‐Ion Batteries
Hongpeng Wang (2000)
10.1016/J.CEJ.2010.08.065
Pd–Cu/AC and Pt–Cu/AC catalysts for nitrate reduction with hydrogen: Influence of calcination and reduction temperatures
Olívia S.G.P. Soares (2010)
10.1149/1.3363047
The Influence of Catalysts on Discharge and Charge Voltages of Rechargeable Li–Oxygen Batteries
Y. Lu (2010)
10.1016/J.JPOWSOUR.2009.09.030
Carbon-supported manganese oxide nanocatalysts for rechargeable lithium–air batteries
H. Cheng (2010)
10.1016/S0008-6223(99)00025-1
Formation of oxygen structures by air activation. A study by FT-IR spectroscopy
V. Gómez-Serrano (1999)
10.1016/0039-6028(77)90304-1
Interaction of NO and O2 with Pd(111) surfaces. I.
H. Conrad (1977)
10.1021/JA0579412
Macroporous manganese oxides with regenerative mesopores.
E. Toberer (2006)
Soc
K. M. Abraham (1996)
10.1016/0378-7753(93)80100-4
Some aspects on the preparation, structure and physical and electrochemical properties of LixC6
R. Yazami (1993)
10.1049/EP.1974.0468
Power Sources 4
M. Barak (1974)
10.1007/S10008-006-0122-2
In situ analysis of interfacial reactions between negative MCMB, lithium electrodes, and gel polymer electrolyte
Y. Cheng (2006)
10.1016/J.APCATB.2009.08.005
Catalytic activity and long-term stability of palladium oxide catalysts for natural gas combustion: Pd supported on LaMnO3-ZrO2
S. Specchia (2009)
10.1016/J.ELECOM.2005.12.015
Investigations of carbon-supported CoPd3 catalysts as oxygen cathodes in PEM fuel cells
William E. Mustain (2006)
Angew
F. Raimondi (2005)
10.1016/S0378-7753(03)00823-1
Sonochemical synthesis of amorphous manganese oxide coated on carbon and application to high power battery
H. Kawaoka (2004)
10.1021/JP054740B
Synthesis of manganese oxide electrodes with interconnected nanowire structure as an anode material for rechargeable lithium ion batteries.
Mao-Sung Wu (2005)
10.1016/0378-7753(93)80022-H
Plasticized carbon electrodes of interest for lithium rocking chair batteries
S. Passerini (1993)
10.1149/1.1836375
High performance direct methanol polymer electrolyte fuel cells
Xiaoming Ren (1996)
10.1007/S10008-009-0791-8
The effect of oxygen pressures on the electrochemical profile of lithium/oxygen battery
Xin-hui Yang (2009)
10.1002/ANIE.200460466
Nanoparticles in energy technology: examples from electrochemistry and catalysis.
F. Raimondi (2005)



This paper is referenced by
10.1016/J.MATERRESBULL.2013.04.050
Conducting polymer-doped polyprrrole as an effective cathode catalyst for Li-O2 batteries
J. Zhang (2013)
10.1149/2.033304JES
Investigating the Li-O2 Battery in an Ether-Based Electrolyte Using Differential Electrochemical Mass Spectrometry
Christopher J. Barile (2013)
10.1002/AENM.201200020
Lithium-Air Batteries: Survey on the Current Status and Perspectives Towards Automotive Applications from a Battery Industry Standpoint
Myounggu Park (2012)
10.1016/J.JPOWSOUR.2014.12.078
Review on mechanisms and continuum models of multi-phase transport phenomena in porous structures of non-aqueous Li-Air batteries
J. Yuan (2015)
10.1021/cr400573b
Aprotic and aqueous Li-O₂ batteries.
Jun Lu (2014)
10.1016/J.APENERGY.2017.05.185
Numerical investigation of a non-aqueous lithium-oxygen battery based on lithium superoxide as the discharge product
P. Tan (2017)
10.1016/J.EST.2016.07.001
Modelling of a Na-air battery with porous gas diffusion electrode
Ukrit Sahapatsombut (2016)
10.1201/B15492-8
Nanoengineered Lithium–Air Secondary Batteries: Fundamental Understanding and the Current Status of Development
Junichi Kawamura (2014)
10.1039/C4TB01224K
A porous PdO microrod-based electrochemical sensor for nanomolar-level Cu2+ released from cells.
X. Cao (2014)
10.1039/C6TA00331A
Mesoporous Cr2O3 nanotubes as an efficient catalyst for Li–O2 batteries with low charge potential and enhanced cyclic performance
Xinzhen Zhang (2016)
The Material Design of Stable Cathodes in Li-Oxygen Batteries and Beyond
Xiahui Yao (2017)
10.4028/www.scientific.net/AMR.906.51
Rechargeable Alkali and Alkaline Earth Metal-Air Batteries – Potential and Challenges
H. Cheng (2014)
10.3762/bjnano.6.105
From lithium to sodium: cell chemistry of room temperature sodium–air and sodium–sulfur batteries
P. Adelhelm (2015)
10.1002/ENTE.201600115
Study on Electrolyte Stability and Oxygen Reduction Reaction Mechanisms in the Presence of Manganese Oxide Catalysts for Aprotic Lithium–Oxygen Batteries
Matthias Augustin (2016)
10.1002/ADFM.201200688
Making Li‐Air Batteries Rechargeable: Material Challenges
Yuyan Shao (2013)
10.1002/9781118615515.CH11
Kinetics of the Oxygen Electrode in Lithium–Air Cells
M. Piana (2013)
10.1002/ER.3230
Prospects, challenges, and latest developments in lithium–air batteries
Naveed Akhtar (2015)
10.1016/J.JPOWSOUR.2017.08.007
A combination of CoO and Co nanoparticles supported on electrospun carbon nanofibers as highly stable air electrodes
C. Alegre (2017)
10.1016/B978-1-78242-090-3.00006-7
Electrochemistry of rechargeable lithium–air batteries
Junbo Hou (2015)
Rechargeable lithium-air batteries using mathematical modelling
Ukrit Sahapatsombut (2014)
10.1149/2.012310JSS
Carbon-Based Electrodes for Lithium Air Batteries: Scientific and Technological Challenges from a Modeling Perspective
A. Franco (2013)
10.1016/J.ELECTACTA.2019.04.126
Exploring oxygen electrocatalytic activity and pseudocapacitive behavior of Co3O4 nanoplates in alkaline solutions
P. Tan (2019)
10.1021/ja3042993
Fe/N/C composite in Li-O2 battery: studies of catalytic structure and activity toward oxygen evolution reaction.
Jianglan Shui (2012)
10.1016/j.watres.2012.08.005
A novel structure of scalable air-cathode without Nafion and Pt by rolling activated carbon and PTFE as catalyst layer in microbial fuel cells.
H. Dong (2012)
10.1016/J.ELECTACTA.2015.03.103
Enhancement of stability for lithium oxygen batteries by employing electrolytes gelled by poly(vinylidene fluoride-co-hexafluoropropylene) and tetraethylene glycol dimethyl ether
J. Zhang (2015)
10.1039/C5TA01887K
Ruthenium nanoparticles mounted on multielement co-doped graphene: an ultra-high-efficiency cathode catalyst for Li–O2 batteries
Xiaoyuan Zeng (2015)
10.3724/sp.j.1077.2012.12111
Research Progress of Lithium-air Battery
Liang Chun (2012)
10.1039/C5TA01601K
Performance improvement of air electrode for Li/air batteries by hydrophobicity adjustment
Mei Chen (2015)
10.1016/B978-0-12-801417-2.00006-2
Chapter 6 – Perspectives in Lithium Batteries
P. Poizot (2015)
10.1007/s10800-013-0620-8
A review of high energy density lithium–air battery technology
M. A. Rahman (2013)
10.6000/1929-6002.2013.02.04.1
Review on air cathode in Li-air batteries
WQ Han (2013)
10.1039/C2EE23475K
α-MnO2 nanorods grown in situ on graphene as catalysts for Li–O2 batteries with excellent electrochemical performance
Y. Cao (2012)
See more
Semantic Scholar Logo Some data provided by SemanticScholar