Online citations, reference lists, and bibliographies.
Referencing for people who value simplicity, privacy, and speed.
Get Citationsy
← Back to Search

Efficient Hydrogen Production From Ethanol Steam Reforming Over La-modified Ordered Mesoporous Ni-based Catalysts

H. Ma, L. Zeng, Hao Tian, D. Li, X. Wang, X. Li, Jinlong Gong
Published 2016 · Chemistry

Save to my Library
Download PDF
Analyze on Scholarcy Visualize in Litmaps
Share
Reduce the time it takes to create your bibliography by a factor of 10 by using the world’s favourite reference manager
Time to take this seriously.
Get Citationsy
Abstract This paper describes the synthesis of a group of meso-xLaNiAl catalysts with ordered mesostructure and La promoters, and their catalytic performance for hydrogen production from ethanol steam reforming. For comparison, the conventional 0LaNiAl catalyst was prepared by impregnation with γ-Al2O3. The characterization results exhibited that meso-xLaNiAl materials possessed excellent textural properties, such as high specific surface areas, large pore volumes and uniform pore sizes. The ordered mesostructure was beneficial to obtain and maintain the 4–6 nm Ni nanoparticles, which were smaller than that of the conventional 0LaNiAl catalyst (∼10 nm). Consequently, meso-xLaNiAl catalysts exhibited superior initial activity with respect to the reference 0LaNiAl catalyst, especially at higher temperatures (873 and 973 K). Particularly, the meso-3LaNiAl catalyst gained the highest amount of easily reduced Ni species and then the highest active surface areas. In addition, the highest initial activity at 873 K is exhibited over meso-3LaNiAl catalyst, which is mainly attributed to the highly dispersed nickel nanoparticles and abundant active surface areas. The meso-3LaNiAl catalyst also exhibited excellent long-term stability. Besides the excellent textural properties, the presence of La-modifiers enhanced the basicity of the catalyst, strengthened the metal-support interaction and cleaned the deposited carbon, resulting in the suppression of carbon deposition and the improvement of stability.
This paper references
10.1016/J.IJHYDENE.2015.01.061
H2-production from CO2-assisted ethanol steam reforming: The regeneration of Ni-based catalysts
Lukasz Bednarczuk (2015)
10.1016/0021-9517(80)90316-4
The stoichiometry of hydrogen and carbon monoxide chemisorption on alumina- and silica-supported nickel
C. H. Bartholomew (1980)
10.1016/J.CATCOM.2010.07.015
Acetic acid steam reforming to hydrogen over Co–Ce/Al2O3 and Co–La/Al2O3 catalysts—The promotion effect of Ce and La addition
X. Hu (2010)
10.1039/C2CY20703F
Ethanol steam reforming over Rh and Pt catalysts: effect of temperature and catalyst deactivation
M. Bilal (2013)
10.1016/J.CATCOM.2004.07.015
H2 production for MC fuel cell by steam reforming of ethanol over MgO supported Pd, Rh, Ni and Co catalysts
F. Frusteri (2004)
10.1016/J.APCATB.2013.01.053
CeO2-supported Pt/Ni catalyst for the renewable and clean H2 production via ethanol steam reforming
V. Palma (2014)
10.1021/am302733m
Composition-dependent morphostructural properties of Ni-Cu oxide nanoparticles confined within the channels of ordered mesoporous SBA-15 silica.
Adrian Ungureanu (2013)
10.1016/J.SCRIPTAMAT.2011.09.013
Synthesis of highly thermally stable lanthanum-doped ordered mesoporous alumina
Q. Sun (2011)
10.1007/978-1-4614-0344-9
Catalysis for Alternative Energy Generation
L. Guczi (2012)
10.1016/S0926-3373(97)00083-0
CO2 reforming of methane on Ni catalysts: Effects of the support phase and preparation technique
S. Wang (1998)
10.1016/0920-5861(94)80181-9
Deactivation of supported nickel catalysts during the reforming of methane by carbon dioxide
H. M. Swaan (1994)
10.1016/J.IJHYDENE.2006.10.025
Ethanol steam reforming over Ni/MxOy–Al2O3 (M=Ce, La, Zr and Mg) catalysts: Influence of support on the hydrogen production
M. Sanchez-Sanchez (2007)
Carbon Dioxide Reforming of Methane over Ni/La2O3/Al2O3
Zhong-Wen Liu (2003)
10.1016/J.RENENE.2014.08.048
Syngas production from glycerol-dry(CO2) reforming over La-promoted Ni/Al2O3 catalyst
Kah Weng Siew (2015)
10.1016/S0926-3373(02)00327-2
Production of hydrogen for fuel cells by steam reforming of ethanol over supported noble metal catalysts
D. K. Liguras (2003)
10.1016/S0166-9834(00)81391-3
Temperature-programmed reduction of NiOWO3/Al2O3 Hydrodesulphurization catalysts
B. Scheffer (1989)
10.1039/b910071g
Steam reforming of methane over ordered mesoporous Ni-Mg-Al oxides.
Weihua Shen (2009)
10.1016/J.CATTOD.2013.11.006
Hydrogen production by glycerol steam reforming over SBA-15-supported nickel catalysts: Effect of alkaline earth promoters on activity and stability
J. A. Calles (2014)
10.1016/J.APCATA.2003.09.006
Effects of lanthanum addition on Ni-B/γ-Al2O3 amorphous alloy catalysts used in anthraquinone hydrogenation
Yongjiang Hou (2004)
10.1016/J.APCATA.2007.06.039
The CO2 reforming of CH4 over Ni/La2O3/α-Al2O3 catalysts: The effect of La2O3 contents on the kinetic performance
Yuehua Cui (2007)
10.1006/JCAT.2000.2939
CO2 Reforming of CH4 over Pt/ZrO2 Catalysts Promoted with La and Ce Oxides
S. Stagg-Williams (2000)
10.1016/S0021-9517(02)00130-6
Synthesis of supported catalysts by impregnation and drying using aqueous chelated metal complexes
A. Dillen (2003)
10.1021/CS5020755
Toward Understanding Metal-Catalyzed Ethanol Reforming
D. Zanchet (2015)
10.1021/SC300081Q
Hydrogen Production via Steam Reforming of Ethanol on Phyllosilicate-Derived Ni/SiO2: Enhanced Metal–Support Interaction and Catalytic Stability
Chengxi Zhang (2013)
10.1016/J.IJHYDENE.2012.06.041
Dry reforming of methane to syngas over La-promoted hydrotalcite clay-derived catalysts
A. Serrano-Lotina (2012)
10.1006/JCAT.1996.0225
Characterization of Carbonaceous Species Formed during Reforming of CH4with CO2over Ni/CaO–Al2O3Catalysts Studied by Various Transient Techniques
M. Goula (1996)
10.1016/S1566-7367(02)00118-8
Bio-ethanol catalytic steam reforming over supported metal catalysts
F. Auprêtre (2002)
10.1016/J.JCAT.2007.06.023
Deactivation of Ni catalysts during methane autothermal reforming with CO2 and O2 in a fluidized-bed reactor
Zhaoyin Hou (2007)
10.1016/0021-9517(89)90354-0
Dispersion studies on the system La2O3γ-Al2O3
Max Bettman (1989)
10.1016/S2095-4956(14)60112-1
Characterization of La-promoted Ni/Al2O3 Catalysts for Hydrogen Production from Glycerol Dry Reforming
Kah Weng Siew (2014)
10.1016/J.CATTOD.2008.11.020
Ethanol steam reforming on Mg- and Ca-modified Cu–Ni/SBA-15 catalysts
A. J. Vizcaíno (2009)
10.1016/J.JCAT.2004.04.034
Reaction network of steam reforming of ethanol over Ni-based catalysts
A. Fatsikostas (2004)
10.1039/C1CY00129A
Carbon dioxide reforming of methane over ordered mesoporous NiO–Al2O3 composite oxides
Leilei Xu (2011)
10.1021/CS400159W
Ceria-Doped Ni/SBA-16 Catalysts for Dry Reforming of Methane
Shenghong Zhang (2013)
10.1039/c3cc43699c
A rationally designed CuFe2O4-mesoporous Al2O3 composite towards stable performance of high temperature water-gas shift reaction.
V. Subramanian (2013)
10.1002/cssc.200900243
Renewable H2 from glycerol steam reforming: effect of La2O3 and CeO2 addition to Pt/Al2O3 catalysts.
T. Montini (2010)
10.1039/c0cp01309a
A facile route to ordered mesoporous-alumina-supported catalysts, and their catalytic activities for CO oxidation.
Z. Li (2011)
10.1016/J.CATTOD.2013.08.013
Synthesis of stable Ni-CeO2 catalysts via ball-milling for ethanol steam reforming
Chengxi Zhang (2014)
10.1016/J.APCATB.2015.02.024
A study of Ni/Al2O3 and Ni–La/Al2O3 catalysts for the steam reforming of ethanol and phenol
G. Garbarino (2015)
10.1016/J.APCATB.2011.10.003
Glycerol steam reforming for hydrogen production: Design of Ni supported catalysts
Valentina Nichele (2012)
10.1016/J.CEJ.2005.12.008
Insight into steam reforming of ethanol to produce hydrogen for fuel cells
P. D. Vaidya (2006)
10.1016/J.CATTOD.2006.10.013
Ethanol steam reforming over Ni/La–Al2O3 catalysts: Influence of lanthanum loading
M. Sanchez-Sanchez (2007)
10.1016/J.JPOWSOUR.2005.02.046
Bio-ethanol steam reforming: Insights on the mechanism for hydrogen production
M. Benito (2005)
10.1016/J.APCATB.2015.07.001
Tuning the metal-support interaction in catalysts for highly efficient methane dry reforming reaction
F. Wang (2016)
10.1002/cctc.201300960
Structure–Activity Relationships of Nickel–Hexaaluminates in Reforming Reactions Part I: Controlling Nickel Nanoparticle Growth and Phase Formation
Thomas Roussière (2014)
10.1016/S0926-860X(97)00298-6
Reduction of impregnated NiO/α-A12O3 association of A13+ ions with NiO
J. Richardson (1998)
10.1016/S0166-9834(00)83033-X
Studies on the promotion of nickel—alumina coprecipitated catalysts: II. Lanthanum oxide
H.G.J. Lansink Rotgerink (1988)
10.1039/c2cc37109j
A Ni@ZrO2 nanocomposite for ethanol steam reforming: enhanced stability via strong metal-oxide interaction.
Shuirong Li (2013)
10.1038/359710A0
Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism
C. Kresge (1992)
10.1016/S0926-860X(00)00440-3
Catalytic steam reforming of bio-oils for the production of hydrogen : effects of catalyst composition
L. García (2000)
10.1016/J.CATTOD.2007.01.062
Carbon formation and its influence on ethanol steam reforming over Ni/Al2O3 catalysts
A. L. Alberton (2007)
10.1081/CR-100101948
CO2 Reforming of CH4
M. Bradford (1999)
10.1021/JP401855X
Inverse NiAl2O4 on LaAlO3–Al2O3: Unique Catalytic Structure for Stable CO2 Reforming of Methane
Yasotha Kathiraser (2013)
10.1351/pac198254112201
Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Provisional)
K. Sing (1982)
10.1016/J.APCATB.2015.04.020
Ceria-promoted Ni/SBA-15 catalysts for ethanol steam reforming with enhanced activity and resistance to deactivation
D. Li (2015)
10.1016/J.CATTOD.2008.03.006
Steam reforming of ethanol over Ni/support catalysts for generation of hydrogen for fuel cell applications
A. Denis (2008)
10.1016/J.APCATA.2004.03.052
Steam reforming of bio-ethanol on alkali-doped Ni/MgO catalysts: hydrogen production for MC fuel cell
F. Frusteri (2004)
10.1039/c4cc01441c
Immobilizing Ni nanoparticles to mesoporous silica with size and location control via a polyol-assisted route for coking- and sintering-resistant dry reforming of methane.
Ting Xie (2014)
10.1016/S0926-860X(99)00487-1
Effect of metal particle size on coking during CO2 reforming of CH4 over Ni–alumina aerogel catalysts
Jin-Hong Kim (2000)
10.1016/J.APCATA.2010.01.036
Evaluation of the performance of Ni/La2O3 catalyst prepared from LaNiO3 perovskite-type oxides for the production of hydrogen through steam reforming and oxidative steam reforming of ethanol
S. M. D. Lima (2010)
10.1016/0040-6031(94)02177-P
Temperature-programmed-reduction studies of nickel oxide/alumina catalysts: effects of the preparation method
Chiuping Li (1995)
10.1016/J.IJHYDENE.2013.01.162
Effect of CaO addition on acid properties of Ni–Ca/Al2O3 catalysts applied to ethanol steam reforming
Kariny F.M. Elias (2013)
10.1016/S0926-860X(00)00575-5
High temperature thermal stabilization of alumina modified by lanthanum species
Xiaoyin Chen (2001)
10.1016/J.CATTOD.2011.04.003
Marked role of mesopores for the prevention of sintering and carbon deposition in dry reforming of methane over ordered mesoporous Ni–Mg–Al oxides
Weihua Shen (2011)
10.1002/cssc.201100821
Sustainable production of syngas from biomass-derived glycerol by steam reforming over highly stable Ni/SiC.
S. Kim (2012)
10.1016/J.IJHYDENE.2013.03.089
On the activity of bimetallic catalysts for ethanol steam reforming
V. Palma (2013)
10.1021/ja0764308
Facile synthesis for ordered mesoporous gamma-aluminas with high thermal stability.
Q. Yuan (2008)
10.1006/JCAT.2002.3643
Efficient Production of Hydrogen over Supported Cobalt Catalysts from Ethanol Steam Reforming
J. Llorca (2002)
10.1007/S10562-006-0082-2
Catalyst deactivation and regeneration in low temperature ethanol steam reforming with Rh/CeO2–ZrO2 catalysts
Hyun-Seog Roh (2006)
10.1021/ja806429q
Ordered mesoporous alumina-supported metal oxides.
Stacy M. Morris (2008)
10.1021/CS3001072
One-Pot Synthesis of Ordered Mesoporous NiO-CaO-Al2O3 Composite Oxides for Catalyzing CO2 Reforming of CH4
Leilei Xu (2012)
10.1002/cctc.201300720
One‐pot Synthesis of Ordered Mesoporous NiCeAl Oxide Catalysts and a Study of Their Performance in Methane Dry Reforming
Ning Wang (2014)
10.1021/IE100636F
Steam Reforming of Ethanol over Ni/Al2O3−La2O3 Catalysts Synthesized by Sol−Gel
Raúl Carrera Cerritos (2011)
10.1016/J.APCATA.2004.06.017
CO2 reforming of methane over coprecipitated Ni–Al catalysts modified with lanthanum
R. Martínez (2004)
10.1016/0926-860X(93)80156-K
On the nature of oxidic nickel phases in NiO/γ-Al2O3 catalysts
J. Rynkowski (1993)
10.1016/J.IJHYDENE.2013.08.077
Hydrogen production over Rh/Ce-MCM-41 catalysts via ethanol steam reforming
O. Vargas (2013)
10.1021/CS4003113
Facile Route for Synthesizing Ordered Mesoporous Ni–Ce–Al Oxide Materials and Their Catalytic Performance for Methane Dry Reforming to Hydrogen and Syngas
Ning Wang (2013)
10.1016/J.APCATB.2013.07.028
Glycerol steam reforming over perovskite-derived nickel-based catalysts
G. Wu (2014)
10.1016/J.FUEL.2008.09.030
Ethanol steam reforming reactions over Al2O3 · SiO2-supported Ni–La catalysts
Lifeng Zhang (2009)
10.1021/cr2000114
Production of hydrogen from ethanol: review of reaction mechanism and catalyst deactivation.
L. Mattos (2012)
10.1016/J.APCATB.2012.02.006
Ni/SiO2 and Ni/ZrO2 catalysts for the steam reforming of ethanol
I. Rossetti (2012)
10.1039/c4cs00223g
Strategies for improving the performance and stability of Ni-based catalysts for reforming reactions.
Shuirong Li (2014)
10.1002/ER.3073
Hydrogen production from ethanol steam reforming over Ni/SiO2 catalysts: A comparative study of traditional preparation and microwave modification methods
L. Liu (2014)
10.1016/J.APCATB.2012.01.005
Low-temperature conversion of phenol into CO, CO2 and H2 by steam reforming over La-containing supported Rh catalysts
Domna A. Constantinou (2012)
10.1016/S0920-5861(98)00401-5
Catalysts for the control of coking during steam reforming
D. Trimm (1999)
10.1021/EF0500538
Current status of hydrogen production techniques by steam reforming of ethanol : A review
A. Haryanto (2005)
10.1016/J.JPOWSOUR.2008.12.104
Hydrogen production by steam reforming of ethanol over Ni-based catalysts promoted with noble metals
Luciene P.R. Profeti (2009)
10.1016/J.APCATB.2011.08.028
Carbon dioxide reforming of methane over ordered mesoporous NiO–MgO–Al2O3 composite oxides
Leilei Xu (2011)
10.1016/J.CCLET.2014.06.016
Rh doping effect on coking resistance of Ni/SBA-15 catalysts in dry reforming of methane
Wenjia Cai (2014)
10.1016/J.CATCOM.2013.01.004
A unique method to fabricate NixMg1 − xO (111) nano-platelet solid solution catalyst for CH4-CO2 dry reforming
H. Xiao (2013)
10.1007/S11244-008-9060-9
Hydrogen Production from Glycerol Over Nickel Catalysts Supported on Al2O3 Modified by Mg, Zr, Ce or La
A. Iriondo (2008)
10.1039/C3CY01037F
Significant roles of mesostructure and basic modifier for ordered mesoporous Ni/CaO–Al2O3 catalyst towards CO2 reforming of CH4
Leilei Xu (2014)



This paper is referenced by
10.1016/J.IJHYDENE.2019.04.289
Sorption-enhanced ethanol steam reforming on Ce-Ni/MCM-41 with simultaneous CO2 adsorption over Na- and Zr- promoted CaO based sorbent
Lida Rahmanzadeh (2019)
10.1021/acsami.6b15507
One-Pot Synthesis of Mesoporous Ni-Ti-Al Ternary Oxides: Highly Active and Selective Catalysts for Steam Reforming of Ethanol.
Alexandre A S Gonçalves (2017)
The role of Mg-Al hydrotalcite derived mixed oxides as catalytic support materials : Applications in the transesterification of vegetable oils for biodiesel production and in the steam reforming of glycerol for hydrogen production
Eliane Dahdah (2018)
10.1021/ACS.CHEMREV.6B00099
Catalytic Reforming of Oxygenates: State of the Art and Future Prospects.
D. Li (2016)
10.3390/catal9121013
Hydrogen Production from Steam Reforming of Acetic Acid as a Model Compound of the Aqueous Fraction of Microalgae HTL Using Co-M/SBA-15 (M: Cu, Ag, Ce, Cr) Catalysts
P. J. Megía (2019)
10.1016/j.jece.2020.104228
Effect of La promotion on Ni/Mg-Al hydrotalcite derived catalysts for glycerol steam reforming
Eliane Dahdah (2020)
10.1016/J.APCATA.2018.12.025
Constructing a high-efficiency iron-based catalyst for carbon dioxide oxidative dehydrogenation of 1-butene: The role of oxygen mobility and proposed reaction mechanism
B. Yan (2019)
Hydrogen Production by Steam Reforming of Ethanol over Mesoporous Nickel-Alumina-Zirconia Catalysts
한승주 (2017)
10.1016/J.IJHYDENE.2018.07.136
Bi-reforming of methane on Ni/SBA-15 catalyst for syngas production: Influence of feed composition
Sharanjit Singh (2018)
10.1016/J.JCAT.2016.01.023
CO methanation on ordered mesoporous Ni–Cr–Al catalysts: Effects of the catalyst structure and Cr promoter on the catalytic properties
Q. Liu (2016)
10.1039/C5RA28057E
Anti-sintering ZrO2-modified Ni/α-Al2O3 catalyst for CO methanation
Q. Liu (2016)
10.1016/J.IJHYDENE.2019.01.251
Renewable hydrogen production over Pt/Al₂O₃ nano-catalysts: Effect of M-promoting (M=Pd, Rh, Re, Ru, Ir, Cr)
Afsanehsadat Larimi (2019)
10.1016/J.FUEL.2017.12.114
Steam reforming of acetic acid over Ni/Al2O3 catalysts: Correlation of nickel loading with properties and catalytic behaviors of the catalysts
Zhanming Zhang (2018)
10.1016/j.jechem.2020.02.053
Balancing free and confined metallic Ni for an active and stable catalyst—A case study of CO methanation over Ni/Ni–Al2O3
Xiao Yong-shan (2020)
10.3390/CATAL8090372
Hydrogen Production from Chemical Looping Steam Reforming of Ethanol over Perovskite-Type Oxygen Carriers with Bimetallic Co and Ni B-Site Substitution
L. Li (2018)
10.1016/j.apcatb.2019.118448
Dry reforming of methane over La2O2CO3-modified Ni/Al2O3 catalysts with moderate metal support interaction
K. Li (2020)
10.1016/J.IJHYDENE.2016.08.128
Carbon intermediates during CO2 reforming of methane over NiCaOZrO2 catalysts: A temperature-programmed surface reaction study
Changzhen Wang (2016)
10.1016/J.APCATB.2019.118019
The importance of inner cavity space within Ni@SiO2 nanocapsule catalysts for excellent coking resistance in the high-space-velocity dry reforming of methane
Changzhen Wang (2019)
10.1016/j.crcon.2020.12.001
Preparation of Highly Dispersed Supported Ni-Based Catalysts and Their Catalytic Performance in Low Temperature for CO Methanation
Yongbin Yao (2020)
10.1039/C8CY01158C
Geometric design of a Ni@silica nano-capsule catalyst with superb methane dry reforming stability: enhanced confinement effect over the nickel site anchoring inside a capsule shell with an appropriate inner cavity
Changzhen Wang (2018)
10.1007/s10853-020-05222-0
Solution-combusted nanosized Ni–Al2O3 catalyst for slurry CO methanation: effects of alkali/alkaline earth metal chlorides
Yuan Gao (2020)
10.1039/C6TA03657K
Kerf loss silicon as a cost-effective, high-efficiency, and convenient energy carrier: additive-mediated rapid hydrogen production and integrated systems for electricity generation and hydrogen storage
Tzu-Lun Kao (2016)
10.1016/J.FUPROC.2017.10.003
Optimum operating conditions in ethanol steam reforming over a Ni/La2O3- αAl2O3 catalyst in a fluidized bed reactor
C. Montero (2018)
10.1002/slct.201904701
Enhanced Coke Resistance and Antioxidation Stability of γ‐Alumina‐Supported Nickel‐Based Catalysts via Decoration with Lanthanum for Propane Pre‐Reforming
Mingwu Tan (2020)
10.3390/CATAL8080319
Investigation of Ni/SiO2 Fiber Catalysts Prepared by Different Methods on Hydrogen production from Ethanol Steam Reforming
Sareena Mhadmhan (2018)
10.1016/J.RENENE.2017.05.072
Synergies between Ni, Co, and Mn ions in trimetallic Ni1-xCoxMnO4 catalysts for effective hydrogen production from propane steam reforming
Seung Won Jo (2017)
10.22104/IJHFC.2015.265
Effect of Sorbitol/Oxidizer Ratio on Microwave Assisted Solution Combustion Synthesis of Copper Based Nanocatalyst for Fuel Cell Grade Hydrogen Production
Hossein Ajamein (2015)
10.1002/ER.4399
A high‐performance CeO2@Pt‐Beta yolk‐shell catalyst used in low‐temperature ethanol steam reforming for high‐purity hydrogen production
Rong Dai (2019)
10.1016/J.IJHYDENE.2016.03.125
Activity and stability performance of multifunctional catalyst (Ni/CaO and Ni/Ca12Al14O33CaO) for bio-hydrogen production from sorption enhanced biogas steam reforming
Janewit Phromprasit (2016)
10.1016/J.APPLTHERMALENG.2016.08.041
Highly dispersed Ni/montmorillonite catalyst for glycerol steam reforming: Effect of Ni loading and calcination temperature
B. Jiang (2016)
10.1016/J.IJHYDENE.2018.08.048
Hydrogen production via steam reforming of acetic acid over biochar-supported nickel catalysts
J. Chen (2018)
10.1016/J.IJHYDENE.2018.06.081
Enhanced hydrogen production through co-cultivation of Chlamydomonas reinhardtii CC-503 and a facultative autotrophic sulfide-oxidizing bacterium under sulfurated conditions
Jiayi He (2018)
See more
Semantic Scholar Logo Some data provided by SemanticScholar